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Acta Phys. -Chim. Sin.  2012, Vol. 28 Issue (12): 2767-2773    DOI: 10.3866/PKU.WHXB201209052
THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY     
Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles
LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun
State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
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Abstract  

Surface-enhanced Raman spectroscopy (SERS) on silver nanoparticles is highly sensitive because of surface plasmon resonance. We have studied the structures and photoinduced chemical reactions of p-chloronitrobenzene (PCNB) molecules adsorbed on silver nanoparticles using a combination of SERS and density functional theory (DFT) calculations. When the PCNB molecules are adsorbed to the surface of silver nanoparticles in alkaline solution, the SERS spectra are very different from the normal Raman spectra of PCNB. Comparison of the DFT simulated Raman spectra of PCNB and p,p'-dichloroazobenzene (DCAB) indicates that the new peaks in the SERS spectrum of PCNB adsorbed on silver nanoparticles arise from the azo (C-N=N-C) group of DCAB.



Key wordsSurface-enhanced Raman spectroscopy      Density functional theory      p-Chloronitrobenzene      p,p'-Dichloroazobenzene      Silver nanoparticle     
Received: 25 July 2012      Published: 05 September 2012
MSC2000:  O646  
Fund:  

The project was supported by the National Natural Science Foundation of China (20973143, 91027009, 21021002), National Key Basic Research Program of China (973) (2009CB930703), and Xiamen University, China (2010121020).

Cite this article:

LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun. Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles. Acta Phys. -Chim. Sin., 2012, 28(12): 2767-2773.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201209052     OR     http://www.whxb.pku.edu.cn/Y2012/V28/I12/2767

(1) Jeanmaire, D. L.; Van Duyne, R. P. J. Electroanal. Chem. 1977,84 (1), 1. doi: 10.1016/S0022-0728(77)80224-6
(2) Futamata, M. J. Phys. Chem. 1995, 99, 11901. doi: 10.1021/j100031a018
(3) Sakamoto, K.; Mizutani, G.; Ushioda, S. Phys. Rev. B 1993, 48 (12), 8993.
(4) Gao, P.; Gosztola, D.;Weaver, M. J. J. Phys. Chem. 1988, 92,7122. doi: 10.1021/j100336a018
(5) Osawa, M.; Matsuda, N.; Yoshii, K.; Uchida, I. J. Phys. Chem.1994, 98, 12702. doi: 10.1021/j100099a038
(6) Wu, D. Y.; Liu, X. M.; Huang, Y. F.; Ren, B.; Xu, X.; Tian, Z. Q.J. Phys. Chem. C 2009, 113, 18212. doi: 10.1021/jp9050929
(7) Huang, Y. F.; Zhu, H. P.; Liu, G. K.;Wu, D. Y.; Ren, B.; Tian, Z.Q. J. Am. Chem. Soc. 2010, 132 (27), 9244.
(8) Fang, Y. R.; Li, Y. Z.; Xu, H. X.; Sun, M. T. Langmuir 2010, 26 (11), 7737.
(9) Canpean, V.; Losin, M.; Astilean, S. Chem. Phys. Lett. 2010,500 (4-6), 277.
(10) Arjunan, V.; Raj, A.; Sakiladevi, S.; Carthigayan, K.; Mohan, S.J. Mol. Struct. 2012, 1007 (11), 122.
(11) Griffiths, P.; Thompson, H. Proc. Roy. Soc. London A Math. Phys. Sci. 1967, 298 (1452), 51.
(12) Green, J.; Kynaston,W.; Lindsey, A. Spectrochim. Acta 1961,17, 486. doi: 10.1016/0371-1951(61)80103-3
(13) Medhi, K. C. Indian Journal of Physics 1965, 39 (8), 390.
(14) Green, J.; Harrison, D. Spectrochimica Acta Part A: Molecular Spectroscopy 1970, 26, 1925. doi: 10.1016/0584-8539(70)80130-1
(15) Meriles, C.; Schneider, J.; Nunes, L. A. O.; Brunetti, A. J. Phys. Soc. Jpn. 1998, 67, 1296. doi: 10.1143/JPSJ.67.1296
(16) Matsuda, N.; Sawaguchi, T.; Osawa, M.; Uchida, I. Chem. Lett.1995, 145. doi: 10.12461/cl.1995.437
(17) Kuhn, A.; Eschwege, K. G.; Conradie, J. J. Phys. Org. Chem.2012, 25, 58. doi: 10.1002/poc.v25.1
(18) Matsuda, N.; Yoshii, K.; Ataka, K. I.; Osawa, M.; Matsue, T.;Uchida, I. Chem. Lett. 1992, 1385. doi: 10.1246/cl.1992.1385
(19) Khurana, J. M.; Ray, A. Bull. Chem. Soc. Jpn. 1996, 69, 407.doi: 10.1246/bcsj.69.407
(20) Moglie, Y.; Vitale, C.; Radivoy, G. Tetrahedron Lett. 2008, 49,1828. doi: 10.1016/j.tetlet.2008.01.053
(21) Han, S.W.; Lee, I.; Kim, K. Langmuir 2002, 18, 182. doi: 10.1021/la0115684
(22) Dong, B.; Fang, Y.; Chen, X.; Xu, H.; Sun, M. Langmuir 2011,27, 10677. doi: 10.1021/la2018538
(23) Shin, K. S.; Lee, H. S.; Joo, S.W.; Kim, K. J. Phys. Chem. C.2007, 111, 15223. doi: 10.1021/jp073053c
(24) Tao, A.; Sinsermsuksakul, P.; Yang, P. Angew. Chem. Int. Edit.2006, 45, 4597.
(25) Mammone, J.; Sharma, S.; Nicol, M. J. Phys. Chem. 1980, 84,3130. doi: 10.1021/j100460a032
(26) Schweinsberg, D.; Hope, G.; Trueman, A.; Otieno-Alego, V.Corrosion Sci. 1996, 38, 587. doi: 10.1016/0010-938X(95)00148-D
(27) Whiffen, D. H. J. Chem. Soc. 1956, 1350.
(28) Moskovits, M.; DiLella, D.; Maynard, K. Langmuir 1988, 4, 67.doi: 10.1021/la00079a012
(29) Kyziol, J. B.; Frej, H. Chemical Papers 1988, 42 (6), 781.
(30) Stammreich, H. Experientia 1950, 6, 225.
(31) Wu, D. Y.; Cao, Z. B.; Ren, B.; Xu, X.; Tian, Z. Q. J. Light Scattering 2002, 13, 199. [吴德印, 曹志霁, 任斌, 徐昕,田中群. 光散射学报, 2002, 13, 199.]
(32) Wu, D. Y.; Hayashi, M.; Lin, S. H.; Tian, Z. Q. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2004,60, 137. doi: 10.1016/S1386-1425(03)00190-2
(33) Wu, D. Y.; Liu, X. M.; Xu, Y. C.; Duan, S.; Ren, B.; Tian, Z. Q.J. Light Scattering 2006, 18, 323. [吴德印, 刘秀敏, 徐咏春,段赛, 任斌, 田中群. 光散射学报, 2006, 18, 323.]
(34) Bauernschmitt, R.; Ahlrichs, R. Chem. Phys. Lett. 1996, 256,454. doi: 10.1016/0009-2614(96)00440-X
(35) Badger, G. M.; Lewis, G. E. J. Chem. Soc. 1953, 2147.
(36) Moskovits, M. J. Chem. Phys. 1982, 77, 4408. doi: 10.1063/1.444442

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