金属衬底上石墨烯的控制生长和微观形貌的STM表征

doi:10.3866/PKU.WHXB201209062

Abstract

Abstract:

Recently, chemical vapor deposition (CVD) has been widely applied to the large-scale synthesis of graphene on various metal substrates. As a powerful and direct imaging method, scanning tunneling microscopy (STM) has been used to study the microscopic morphologies of graphene on metal substrates, for the purpose of further optimizing the growth parameters. This review presents the recent progress in the controlled growth of graphene on Cu foils, Pt foils, and Ni substrates, as well as the research of the microscopic morphologies, defect states, and stacking orders of graphene. Monolayer growth of graphene on Cu and Pt foils follows a surface catalyzed growth mechanism, while bilayer graphene growth follows an epitaxial growth mechanism. After the formation of a bilayer, the corrugated substrate breaks the planar conjugated π bonds of graphene, inducing a binding configuration change from sp² to sp³. Then, pristine wrinkles are introduced by the thermal expansion mismatch between graphene and the metal substrates. Finally, the roughness of graphene on the Pt foils is considerably less than that of graphene on Cu foils, and the multifaceted interweaving Pt substrate has almost no effect on the in-plane continuity of graphene.

Key words: Chemical vapor deposition, Metal substrate, Graphene, Scanning tunneling microscope

MSC2000:

O641-33

ZHANG Yan-Feng, GAO Teng, ZHANG-Yu, LIU Zhong-Fan. Controlled Growth of Graphene on Metal Substrates and STM Characterizations for Microscopic Morphologies[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2456-2464.

References

(1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
(2) Bolotin, K. I.; Sikes, K. J.; Zhang, Z.; Klima, M.; Fudenberg,G.; Hone, J.; Kim, P.; Stormer, H. L. Solid State Commun. 2008,146, 351. doi: 10.1016/j.ssc.2008.02.024
(3) Schwierz, F. Nat. Nanotech. 2010, 5, 487. doi: 10.1038/nnano.2010.89
(4) Lin, Y. M.; Dimitrakopoulos, C.; Jenkins, K. A.; Farmer, D. B.;Chiu, H. Y.; Grill, A.; Avouris, P. Science 2012, 327, 662.
(5) Stankovich, S.; Dikin, D. A.; Dommett, G. H. B.; Kohlhaas, K.M.; Zimney, E. J.; Stach, E. A.; Piner, R. D.; Nguyen, S. T.;Ruoff, R. S. Nature 2006, 442, 282. doi: 10.1038/nature04969
(6) Li, X. L.; Zhang, G. Y.; Bai, X. D.; Sun, X. M.;Wang, X. R.;Wang, E. G.; Dai, H. J. Nat. Nanotech. 2008, 3, 538. doi: 10.1038/nnano.2008.210
(7) Berger, C.; Song, Z. M.; Li, T. B.; Li, X. B.; Ogbazghi, A. Y.;Feng, R.; Dai, Z. T.; Marchenkov, A. N.; Conrad, E. H.; First, P.N.; de Heer,W. A. J. Phys. Chem. B 2004, 108, 19912. doi: 10.1021/jp040650f
(8) Sutter, P.W.; Flege, J. I.; Sutter, E. A. Nat. Mater. 2008, 7, 406.doi: 10.1038/nmat2166
(9) Reina, A.; Jia, X. T.; Ho, J.; Nezich, D.; Son, H.; Bulovic, V.;Dresselhaus, M. S.; Kong, J. Nano Lett. 2009, 9, 30. doi: 10.1021/nl801827v
(10) Li, X. S.; Cai,W.W.; An, J. H.; Kim, S.; Nah, J.; Yang, D. X.;Piner, R.; Velamakanni, A.; Jung, I.; Tutuc, E.; Banerjee, S. K.;Colombo, L.; Ruoff, R. S. Science 2009, 324, 1312. doi: 10.1126/science.1171245
(11) Li, X. S.; Zhu, Y.W.; Cai,W.W.; Borysiak, M.; Han, B. Y.;Chen, D.; Piner, R. D.; Colombo, L.; Ruoff, R. S. Nano Lett.2009, 9, 4359. doi: 10.1021/nl902623y
(12) Gao, L.; Guest, J. R.; Guisinger, N. P. Nano Lett. 2010, 10,3512. doi: 10.1021/nl1016706
(13) Pan, Y.; Zhang, H. G.; Shi, D. X.; Sun, J. T.; Du, S. X.; Liu, F.;Gao, H. J. Adv. Mater. 2009, 21, 2777. doi: 10.1002/adma.200800761
(14) Zhang, Y. F.; Gao, T.; Gao, Y. B.; Xie, S. B.; Ji, Q. Q.; Yan, K.;Peng, H. L.; Liu, Z. F. ACS Nano 2011, 5, 4014. doi: 10.1021/nn200573v
(15) Ishigami, M.; Chen, J. H.; Cullen,W. G.; Fuhrer, M. S.;Williams, E. D. Nano Lett. 2007, 7, 1643. doi: 10.1021/nl070613a
(16) Xu, K.; Cao, P.; Heath, J. R. Nano Lett. 2009, 9, 4446. doi: 10.1021/nl902729p
(17) Yan, K.; Peng, H. L.; Zhou, Y.; Li, H.; Liu, Z. F. Nano Lett.2011, 11, 1106. doi: 10.1021/nl104000b
(18) Gao, T.; Xie, S. B.; Gao, Y. B.; Liu, M. X.; Chen, Y. B.; Zhang,Y. F.; Liu, Z. F. ACS Nano 2011, 11, 9194.
(19) Liu, N.; Fu, L.; Dai, B. Y.; Yan, K.; Liu, X.; Zhao, R. Q.; Zhang,Y. F.; Liu, Z. F. Nano Lett. 2011, 11, 297. doi: 10.1021/nl103962a
(20) Zhang, Y. F.; Gao, T.; Xie, S. B.; Dai, B. Y.; Gao, Y. B.; Chen, Y.B.; Liu, M. X. Nano Res. 2012, 5, 402. doi: 10.1007/s12274-012-0221-6
(21) Zhao, R. Q.; Zhang, Y. F.; Gao, T.; Gao, Y. B.; Liu, N.; Fu, L.;Liu, Z. F. Nano Res. 2011, 4, 712. doi: 10.1007/s12274-011-0127-8
(22) Meng, L.; Zhang, Y. F.; Yan,W.; Feng, L.; He, L. Dou, R. F.;Nie, J. C. Appl. Phys. Lett. 2012, 100, 091601. doi: 10.1063/1.3691952
(23) Li, G. H.; Luican, A.; Lopes dos Santos, J. M. B.; Castro, N. A.H.; Reina, A.; Kong, J.; Andrei, E. Y. Nat. Phys. 2010, 4, 109.
(24) Chen, Z. Y.; Yuan, H. T.; Zhang, Y. F.; Nomura, K.; Gao, T.;Gao, Y. B.; Shimotani, H.; Liu, Z. F.; Iwasa, Y. Nano Lett. 2012,12, 2212. doi: 10.1021/nl204012c
(25) Gao, T.; Gao, Y. B.; Chang, C. Z.; Chen, Y. B.; Liu, M. X.; Xie,S. B.; He, K.; Ma, X. C.; Zhang, Y. F.; Liu, Z. F. ACS Nano2012, 6, 6562. doi: 10.1021/nn302303n

[1]	Ruojuan Liu, Bingzhi Liu, Jingyu Sun, Zhongfan Liu. Gaseous-Promotor-Assisted Direct Growth of Graphene on Insulating Substrates: Progress and Prospects [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2111011-0.
[2]	Wenya He, Huhu Cheng, Liangti Qu. Progress on Carbonene Fibers for Energy Devices [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2203004-.
[3]	Hanqing Liu, Feng Zhou, Xiaoyu Shi, Quan Shi, Zhong-Shuai Wu. Recent Advances and Prospects of Graphene-Based Fibers for Application in Energy Storage Devices [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2204017-.
[4]	Wenqian He, Ya Di, Nan Jiang, Zunfeng Liu, Yongsheng Chen. Graphene-Oxide Seeds Nucleate Strong and Tough Hydrogel-Based Artificial Spider Silk [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2204059-.
[5]	Zhou Xia, Yuanlong Shao. Wet Spinning Assembled Graphene Fiber: Processing, Structure, Property, and Smart Applications [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2103046-.
[6]	Zeyao Zhang, Yixi Yao, Yan Li. Modulating the Diameter of Bulk Single-Walled Carbon Nanotubes Grown by FeCo/MgO Catalyst [J]. Acta Phys. -Chim. Sin., 2022, 38(8): 2101055-.
[7]	Jingsong Peng, Qunfeng Cheng. Nacre-Inspired Graphene-based Multifunctional Nanocomposites [J]. Acta Phys. -Chim. Sin., 2022, 38(5): 2005006-.
[8]	Henan Mao, Xiaogong Wang. Key Factors Affecting Rheological Behavior of High-Concentration Graphene Oxide Dispersions and Population Balance Equation Model Analysis [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2004025-.
[9]	Yishun Yang, Min Zhou, Yanxia Xing. Symmetry-Dependent Transport Properties of γ-Graphyne-based Molecular Magnetic Tunnel Junctions [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2003004-.
[10]	Zheng Bo, Jing Kong, Huachao Yang, Zhouwei Zheng, Pengpeng Chen, Jianhua Yan, Kefa Cen. Ultra-Low-Temperature Supercapacitor Based on Holey Graphene and Mixed-Solvent Organic Electrolyte [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2005054-.
[11]	Shiyi Tang, Gaotian Lu, Yi Su, Guang Wang, Xuanzhang Li, Guangqi Zhang, Yang Wei, Yuegang Zhang. Raman Mapping of Lithiation Process on Graphene [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2001007-.
[12]	Yi Cheng, Kun Wang, Yue Qi, Zhongfan Liu. Chemical Vapor Deposition Method for Graphene Fiber Materials [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2006046-.
[13]	Bei Jiang, Jingyu Sun, Zhongfan Liu. Synthesis of Graphene Wafers: from Lab to Fab [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2007068-.
[14]	Muqiang Jian, Yingying Zhang, Zhongfan Liu. Graphene Fibers: Preparation, Properties, and Applications [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2007093-.
[15]	Meihui Jiang, Lizhi Sheng, Chao Wang, Lili Jiang, Zhuangjun Fan. Graphene Film for Supercapacitors: Preparation, Foundational Unit Structure and Surface Regulation [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2012085-.

Controlled Growth of Graphene on Metal Substrates and STM Characterizations for Microscopic Morphologies

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0