甲醇选择氧化金属氧化物催化剂的结构与其催化性能的关系

doi:10.3866/PKU.WHXB201209146

Abstract

Abstract:

Methanol is an important platform molecule for the production of energy and chemicals. For its efficient utilization, it is of critical significance to clarify the relationship between the structures of the catalysts and their performance as well as the corresponding reaction mechanisms. In this review, we summarized some recent progress in the understanding of the active structures of several metal oxide-based catalysts and the reaction mechanism, and the consequent tuning of their redox and acid sites for the selective oxidation of methanol. The catalysts included supported molybdenum oxides, supported vanadium oxides, and heteropolyacids with Keggin structures as well as rhenium oxides and ruthenium oxides recently explored for the methanol oxidation. Such progress provides insights into the design of novel catalysts more efficient for the oxidative conversion of methanol towards the targeted products.

Key words: Methanol, Selective oxidation, Redox site, Acid site, Structure-activity relationship

MSC2000:

O643

CHEN Wen-Long, LIU Hai-Chao. Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol[J].Acta Phys. -Chim. Sin., 2012, 28(10): 2315-2326.

References

(1) Olah, G. A.; Molnár, Á. Hydrocarbon Chemistry, 2nd ed.; JohnWiley & Sons: Hoboken, New Jersey, 2003; pp 114-117.
(2) Xu, X. D.; Moulijn, J. A. Energy & Fuels 1996, 10, 305. doi: 10.1021/ef9501511
(3) Hamelinck, C. N.; Faaij, A. P. C. J. Power Sources 2002, 111, 1.doi: 10.1016/S0378-7753(02)00220-3
(4) Olah, G. A.; Goeppert, A.; Prakash, G. K. S. Beyond Oil and Gas: The Methanol Economy;Wiley-VCH:Weinheim, 2009; pp168-173.
(5) Deo, G.;Wachs, I. E. J. Catal. 1994, 146, 323. doi: 10.1006/jcat.1994.1071
(6) Hu, H. C.;Wachs, I. E. J. Phys. Chem. 1995, 99, 10911. doi: 10.1021/j100027a035
(7) Yuan, Y. Z.; Iwasawa, Y. J. Phys. Chem. B 2002, 106, 4441. doi: 10.1021/jp013770l
(8) Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2005, 109, 2155. doi: 10.1021/jp0401980
(9) Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2003, 107, 10840. doi: 10.1021/jp0301554
(10) Tatibouet, J. M. Appl. Catal. A-Gen. 1997, 148, 213. doi: 10.1016/S0926-860X(96)00236-0
(11) Badlani, M.;Wachs, I. E. Catal. Lett. 2001, 75, 137. doi: 10.1023/A:1016715520904
(12) Wachs, I. E. Catal. Today 2005, 100, 79. doi: 10.1016/j.cattod.2004.12.019
(13) Oyama, S. T.; Radhakrishnan, R.; Seman, M.; Kondo, J. N.;Domen, K.; Asakura, K. J. Phys. Chem. B 2003, 107, 1845. doi: 10.1021/jp0220276
(14) Vitry, D.; Morikawa, Y.; Dubois, J. L.; Ueda,W. Appl. Catal. A-Gen. 2003, 251, 411. doi: 10.1016/S0926-860X(03)00381-8
(15) Cavani, F.; Trifiro, F. Catal. Today 1995, 24, 307. doi: 10.1016/0920-5861(95)00051-G
(16) Chen, K. D.; Xie, S. B.; Bell, A. T.; Iglesia, E. J. Catal. 2001,198, 232. doi: 10.1006/jcat.2000.3125
(17) Tsilomelekis, G.; Boghosian, S. J. Phys. Chem. C 2011, 115,2146. doi: 10.1021/jp1098987
(18) Chempath, S.; Zhang, Y. H.; Bell, A. T. J. Phys. Chem. C 2007,111, 1291. doi: 10.1021/jp064741j
(19) Lee, E. L.;Wachs, I. E. J. Phys. Chem. C 2007, 111, 14410. doi: 10.1021/jp0735482
(20) Tsilomelekis, G.; Boghosian, S. Phys. Chem. Chem. Phys. 2012,14, 2216.
(21) Handzlik, J.; Sautet, P. J. Phys. Chem. C 2008, 112, 14456. doi: 10.1021/jp802372e
(22) Liu, H. C.; Cheung, P.; Iglesia, E. J. Catal. 2003, 217, 222.
(23) Christodoulakis, A.; Heracleous, E.; Lemonidou, A. A.;Boghosian, S. J. Catal. 2006, 242, 16. doi: 10.1016/j.jcat.2006.05.024
(24) Li,W. Z.; Huang, H.; Li, H. J.; Zhang,W.; Liu, H. C. Langmuir2008, 24, 8358. doi: 10.1021/la800370r
(25) Hamraoui, K.; Cristol, S.; Payen, E.; Paul, J. F. J. Mol. Struct. - Theochem 2009, 903, 73. doi: 10.1016/j.theochem.2008.09.044
(26) Chen, K. D.; Bell, A. T.; Iglesia, E. J. Catal. 2002, 209, 35. doi: 10.1006/jcat.2002.3620
(27) Liu, H. C.; Cheung, P.; Iglesia, E. J. Phys. Chem. B 2003, 107,4118. doi: 10.1021/jp0221744
(28) Brandhorst, M.; Cristol, S.; Capron, M.; Dujardin, C.; Vezin, H.;Le bourdon, G.; Payen, E. Catal. Today 2006, 113, 34. doi: 10.1016/j.cattod.2005.11.008
(29) Aritani, H.; Fukuda, O.; Miyaji, A.; Hasegawa, S. Appl. Surf. Sci. 2001, 180, 261. doi: 10.1016/S0169-4332(01)00366-X
(30) Tsilomelekis, G.; Christodoulakis, A.; Boghosian, S. Catal. Today 2007, 127, 139. doi: 10.1016/j.cattod.2007.03.026
(31) Zhang, S. H.; Zhang, H. P.; Li,W. Z.; Zhang,W.; Huang, H.;Liu, H. C. Acta Phys. -Chim. Sin. 2010, 26, 1879. [张胜红,张鸿鹏, 李为臻, 张伟, 黄华, 刘海超. 物理化学学报,2010, 26, 1879.] doi: 10.3866/PKU.WHXB20100732
(32) Shannon, I. J.; Maschmeyer, T.; Oldroyd, R. D.; Sankar, G.;Thomas, J. M.; Pernot, H.; Balikdjian, J. P.; Che, M. J. Chem. Soc. Faraday Trans. 1998, 94, 1495. doi: 10.1039/a800054i
(33) Grabowski, R.; Grzybowska, B.; Haber, J.; Sloczynski, J. React. Kinet. Catal. Lett. 1975, 2, 81. doi: 10.1007/BF02060956
(34) Wachs, I. E.; Saleh, R. Y.; Chan, S. S.; Chersich, C. C. Appl. Catal. 1985, 15, 339. doi: 10.1016/S0166-9834(00)81848-5
(35) Blasco, T.; Lopez-Nieto, J. M. Appl. Catal. A-Gen. 1997, 157,117. doi: 10.1016/S0926-860X(97)00029-X
(36) Cavalli, P.; Cavani, F.; Manenti, I.; Trifiro, F. Catal. Today 1987,1, 245. doi: 10.1016/0920-5861(87)80043-3
(37) Kumar, C. P.; Reddy, K. R.; Rao, V. V.; Chary, K. V. R. Green Chem. 2002, 4, 513. doi: 10.1039/b206581a
(38) Olthof, B.; Khodakov, A.; Bell, A. T.; Iglesia, E. J. Phys. Chem. B 2000, 104, 1516. doi: 10.1021/jp9921248
(39) Bronkema, J. L.; Leo, D. C.; Bell, A. T. J. Phys. Chem. C 2007,111, 14530. doi: 10.1021/jp073826x
(40) Bronkema, J. L.; Bell, A. T. J. Phys. Chem. C 2008, 112, 6404.doi: 10.1021/jp7110692
(41) Tanaka, T.; Yamashita, H.; Tsuchitani, R.; Funabiki, T.; Yoshida,S. J. Chem. Soc. Faraday Trans. 1988, 84, 2987. doi: 10.1039/f19888402987
(42) Eckert, H.;Wachs, I. E. J. Phys. Chem. 1989, 93, 6796. doi: 10.1021/j100355a043
(43) Weckhuysen, B. M.; Jehng, J. M.;Wachs, I. E. J. Phys. Chem. B2000, 104, 7382. doi: 10.1021/jp000055n
(44) Busca, G. J. Mol. Catal. 1989, 50, 241.
(45) Gao, X. T.; Bare, S. R.;Weckhuysen, B. M.;Wachs, I. E.J. Phys. Chem. B 1998, 102, 10842. doi: 10.1021/jp9826367
(46) Shapovalov, V.; Metiu, H. J. Phys. Chem. C 2007, 111, 14179.doi: 10.1021/jp074481l
(47) Vining,W. C.; Strunk, J.; Bell, A. T. J. Catal. 2012, 285, 160.doi: 10.1016/j.jcat.2011.09.024
(48) Ganduglia-Pirovano, M. V.; Popa, C.; Sauer, J.; Abbott, H.; Uhl,A.; Baron, M.; Stacchiola, D.; Bondarchuk, O.; Shaikhutdinov,S.; Freund, H. J. J. Am. Chem. Soc. 2010, 132, 2345. doi: 10.1021/ja910574h
(49) Burcham, L. J.;Wachs, I. E. Catal. Today 1999, 49, 467. doi: 10.1016/S0920-5861(98)00442-8
(50) Burcham, L. J.; Badlani, M.;Wachs, I. E. J. Catal. 2001, 203,104. doi: 10.1006/jcat.2001.3312
(51) Bronkema, J. L.; Bell, A. T. J. Phys. Chem. C 2007, 111, 420.doi: 10.1021/jp0653149
(52) Goodrow, A.; Bell, A. T. J. Phys. Chem. C 2007, 111, 14753.doi: 10.1021/jp072627a
(53) Vining,W. C.; Strunk, J.; Bell, A. T. J. Catal. 2011, 281, 222.doi: 10.1016/j.jcat.2011.05.001
(54) Weber, R. S. J. Phys. Chem. 1994, 98, 2999. doi: 10.1021/j100062a042
(55) Kim, H. Y.; Lee, H. M.; Pala, R. G. S.; Metiu, H. J. Phys. Chem. C 2009, 113, 16083. doi: 10.1021/jp903298w
(56) Abbott, H. L.; Uhl, A.; Baron, M.; Lei, Y.; Meyer, R. J.;Stacchiola, D. J.; Bondarchuk, O.; Shaikhutdinov, S.; Freund,H. J. J. Catal. 2010, 272, 82. doi: 10.1016/j.jcat.2010.03.009
(57) Gao, X. T.;Wachs, I. E. Top. Catal. 2002, 18, 243. doi: 10.1023/A:1013842722877
(58) Goodrow, A.; Bell, A. T. J. Phys. Chem. C 2008, 112, 13204.doi: 10.1021/jp801339q
(59) Holstein,W. L.; Machiels, C. J. J. Catal. 1996, 162, 118. doi: 10.1006/jcat.1996.0265
(60) Jackson, S. D.; Hargreaves, J. S. J. Metal Oxide Catalysis;Wiley-VCH:Weinheim, 2009; pp 487-498.
(61) Khaliullin, R. Z.; Bell, A. T. J. Phys. Chem. B 2002, 106, 7832.doi: 10.1021/jp014695h
(62) Dobler, J.; Pritzsche, M.; Sauer, J. J. Am. Chem. Soc. 2005, 127,10861. doi: 10.1021/ja051720e
(63) Gao, X. T.; Bare, S. R.; Fierro, J. L. G.;Wachs, I. E. J. Phys. Chem. B 1999, 103, 618. doi: 10.1021/jp983357m
(64) Gao, X. T.; Fierro, J. L. G.;Wachs, I. E. Langmuir 1999, 15,3169. doi: 10.1021/la981254p
(65) Gao, X. T.;Wachs, I. E. J. Catal. 2000, 192, 18. doi: 10.1006/jcat.2000.2822
(66) Fubini, B.; Bolis, V.; Cavenago, A.; Garrone, E.; Ugliengo, P.Langmuir 1993, 9, 2712. doi: 10.1021/la00034a034
(67) Feng, T.; Vohs, J. M. J. Catal. 2004, 221, 619. doi: 10.1016/j.jcat.2003.10.002
(68) Zhanpeisov, N. U.; Fukumura, H. J. Phys. Chem. C 2007, 111,16941. doi: 10.1021/jp074869g
(69) Eder, D.; Kramer, R. Phys. Chem. Chem. Phys. 2003, 5, 1314.
(70) Strunk, J.; Vining,W. C.; Bell, A. T. J. Phys. Chem. C 2010,114, 16937. doi: 10.1021/jp100104d
(71) Kim, H. Y.; Lee, H. M.; Metiu, H. J. Phys. Chem. C 2010, 114,13736. doi: 10.1021/jp103361v
(72) Vining,W. C.; Goodrow, A.; Strunk, J.; Bell, A. T. J. Catal.2010, 270, 163. doi: 10.1016/j.jcat.2009.12.017
(73) Ross-Medgaarden, E. I.;Wachs, I. E.; Knowles,W. V.; Burrows,A.; Kiely, C. J.;Wong, M. S. J. Am. Chem. Soc. 2009, 131, 680.doi: 10.1021/ja711456c
(74) Masamoto, J.; Iwaisako, T.; Chohno, M.; Kawamura, M.;Ohtake, J.; Matsuzaki, K. J. Appl. Polym. Sci. 1993, 50, 1299.doi: 10.1002/app.1993.070500801
(75) Zhang, Q. D.; Tan, Y. S.; Yang, C. H.; Han, Y. Z. J. Mol. Catal. A-Chem. 2007, 263, 149. doi: 10.1016/j.molcata.2006.08.044
(76) Lambiotte, G. New Process for Continuous Production ofMethylal. CH Patent 688041, 1997.
(77) Satoh, S.; Tanigawa, Y. Process for Producing Methylal. USPatent 6 379 507, 2002.
(78) Yuan, Y. Z.; Liu, H. C.; Imoto, H.; Shido, T.; Iwasawa, Y.J. Catal. 2000, 195, 51. doi: 10.1006/jcat.2000.2990
(79) Yuan, Y. Z.; Shido, T.; Iwasawa, Y. Chem. Commun. 2000, No.15, 1421.
(80) Zhang, Y. H.; Drake, I. J.; Briggs, D. N.; Bell, A. T. J. Catal.2006, 244, 219. doi: 10.1016/j.jcat.2006.09.002
(81) Royer, S.; Secordel, X.; Brandhorst, M.; Dumeignil, F.; Cristol,S.; Dujardin, C.; Capron, M.; Payena, E.; Dubois, J. L. Chem. Commun. 2008, No. 7, 865.
(82) Gornay, J.; Secordel, X.; Tesquet, G.; de Menorval, B.; Cristol,S.; Fongarland, P.; Capron, M.; Duhamel, L.; Payen, E.;Dubois, J. L.; Dumeignil, F. Green Chem. 2010, 12, 1722. doi: 10.1039/c0gc00194e
(83) Fu, Y. C.; Shen, J. Y. Chem. Commun. 2007, No. 21, 2172.
(84) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. J. Catal. 2010,272, 176. doi: 10.1016/j.jcat.2010.02.028
(85) Zhao, H. Y.; Bennici, S.; Cai, J. X.; Shen, J. Y.; Auroux, A.J. Catal. 2010, 274, 259. doi: 10.1016/j.jcat.2010.07.011
(86) Dunn, J. P.; Jehng, J. M.; Kim, D. S.; Briand, L. E.; Stenger, H.G.;Wachs, I. E. J. Phys. Chem. B 1998, 102, 6212. doi: 10.1021/jp9814247
(87) Guo, H. Q.; Li, D. B.; Jiang, D.; Li,W. H.; Sun, Y. H. Catal. Commun. 2010, 11, 396. doi: 10.1016/j.catcom.2009.11.009
(88) Lu, X. L.; Qin, Z. F.; Dong, M.; Zhu, H. Q.;Wang, G. F.;Zhao, Y. B.; Fan,W. B.;Wang, J. G. Fuel 2011, 90, 1335. doi: 10.1016/j.fuel.2011.01.007
(89) Chen, S.;Wang, S. P.; Ma, X. B.; Gong, J. L. Chem. Commun.2011, No. 47, 9345.
(90) Sun, Q.; Liu, J.W.; Cai, J. X.; Fu, Y. C.; Shen, J. Y. Catal. Commun. 2009, 11, 47. doi: 10.1016/j.catcom.2009.08.010
(91) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. Appl. Catal. A-Gen. 2010, 385, 224. doi: 10.1016/j.apcata.2010.07.017
(92) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. J. Therm. Anal. Calorim. 2010, 99, 843. doi: 10.1007/s10973-009-0499-0
(93) Misono, M. Chem. Commun. 2001, No. 13, 1141.
(94) Okuhara, T.; Mizuno, N.; Misono, M. Appl. Catal. A-Gen.2001, 222, 63. doi: 10.1016/S0926-860X(01)00830-4
(95) Damyanova, S.; Cubeiro, M. L.; Fierro, J. L. G. J. Mol. Catal. A-Chem. 1999, 142, 85. doi: 10.1016/S1381-1169(98)00279-9
(96) Liu, H. C.; Bayat, N.; Iglesia, E. Angew. Chem. Int. Edit. 2003,42, 5072. doi: 10.1002/(ISSN)1521-3773
(97) Liu, H. C.; Iglesia, E. J. Catal. 2004, 223, 161.
(98) Guo, H. Q.; Li, D. B.; Xiao, H. C.; Zhang, J. L.; Li,W. H.;Sun, Y. H. Kor. J. Chem. Eng. 2009, 26, 902. doi: 10.1007/s11814-009-0151-5
(99) Nakka, L.; Molinari, J. E.;Wachs, I. E. J. Am. Chem. Soc.2009, 131, 15544. doi: 10.1021/ja904957d
(100) Molinari, J. E.; Nakka, L.; Kim, T.;Wachs, I. E. ACS Catal.2011, 1, 1536. doi: 10.1021/cs2001362
(101) Mol, J. C. Catal. Today 1999, 51, 289. doi: 10.1016/S0920-5861(99)00051-6
(102) Liu, H. C.; Gaigneaux, E. M.; Imoto, H.; Shido, T.; Iwasawa,Y. Appl. Catal. A-Gen. 2000, 202, 251. doi: 10.1016/S0926-860X(00)00539-1
(103) Wachs, I. E.; Deo, G.; Andreini, A.; Vuurman, M. A.; deBoer,M. J. Catal. 1996, 160, 322. doi: 10.1006/jcat.1996.0152
(104) Yuan, Y. Z.; Tsai, K. R.; Liu, H. C.; Iwasawa, Y. Top. Catal.2003, 22, 9. doi: 10.1023/A:1021451309465
(105) Lee, E. L.;Wachs, I. E. J. Phys. Chem. C 2008, 112, 6487. doi: 10.1021/jp076485w
(106) Lacheen, H. S.; Cordeiro, P. J.; Iglesia, E. J. Am. Chem. Soc.2006, 128, 15082. doi: 10.1021/ja065832x
(107) Lacheen, H. S.; Cordeiro, P. J.; Iglesia, E. Chem.-Eur. J. 2007,13, 3048. doi: 10.1002/(ISSN)1521-3765
(108) Nikonova, O. A.; Capron, M.; Fang, G.; Faye, J.; Mamede, A.S.; Jalowiecki-Duhamel, L.; Dumeignil, F.; Seisenbaeva, G. A.J. Catal. 2011, 279, 310. doi: 10.1016/j.jcat.2011.01.028
(109) Tougerti, A.; Cristol, S.; Berrier, E.; Briois, V.; La Fontaine, C.;Villain, F.; Joly, Y. Phys. Rev. B 2012, 85 (12), 125136. doi: 10.1103/PhysRevB.85.125136
(110) Yang, T. J.; Lunsford, J. H. J. Catal. 1987, 103, 55. doi: 10.1016/0021-9517(87)90092-3
(111) Chan, A. S. Y.; Chen,W. H.;Wang, H.; Rowe, J. E.; Madey, T.E. J. Phys. Chem. B 2004, 108, 14643. doi: 10.1021/jp040168x
(112) Liu, J. L.; Zhan, E. S.; Cai,W. J.; Li, J.; Shen,W. J. Catal. Lett.2008, 120, 274. doi: 10.1007/s10562-007-9280-9
(113) Hardcastle, F. D.;Wachs, I. E.; Horsley, J. A.; Via, G. H.J. Mol. Catal. 1988, 46, 15. doi: 10.1016/0304-5102(88)85081-8
(114) Albonetti, S.; Cavani, F.; Trifiro, F. Catal. Rev.-Sci. Eng. 1996,38, 413. doi: 10.1080/01614949608006463
(115) Secordel, X.; Yoboue, A.; Cristol, S.; Lancelot, C.; Capron, M.;Paul, J. F.; Berrier, E. J. Solid State Chem. 2011, 184, 2806.doi: 10.1016/j.jssc.2011.08.002
(116) Zang, L.; Kisch, H. Angew. Chem. Int. Edit. 2000, 39, 3921.doi: 10.1002/(ISSN)1521-3773
(117) Zhan, B. Z.; White, M. A.; Sham, T. K.; Pincock, J. A.; Doucet,R. J.; Rao, K. V. R.; Robertson, K. N.; Cameron, T. S. J. Am. Chem. Soc. 2003, 125, 2195. doi: 10.1021/ja0282691
(118) Zhan, B. Z.; White, M. A.; Pincock, J. A.; Robertson, K. N.;Cameron, T. S.; Sham, T. K. Can. J. Chem. -Rev. Can. Chim.2003, 81, 764. doi: 10.1139/v03-060
(119) Li,W. Z.; Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2006, 110,23337. doi: 10.1021/jp0648689
(120) Lee, J. S.; Kim, J. C.; Kim, Y. G. Appl. Catal. 1990, 57, 1. doi: 10.1016/S0166-9834(00)80720-4
(121) Jenner, G. Appl. Catal. A-Gen. 1995, 121, 25.
(122) Huang, H.; Li,W. Z.; Liu, H. C. Catal. Today 2012, 183, 58.doi: 10.1016/j.cattod.2011.05.021
(123) Lichtenberger, J.; Lee, D.; Iglesia, E. Phys. Chem. Chem. Phys.2007, 9, 4902.
(124) Wittstock, A.; Zielasek, V.; Biener, J.; Friend, C. M.; Baumer,M. Science 2010, 327, 319. doi: 10.1126/science.1183591
(125) Zhan, B. Z.; Iglesia, E. Angew. Chem. Int. Edit. 2007, 46, 3697.doi: 10.1002/(ISSN)1521-3773
(126) Yu, H.; Zeng, K.; Fu, X. B.; Zhang, Y.; Peng, F.;Wang, H. J.;Yang, J. J. Phys. Chem. C 2008, 112, 11875. doi: 10.1021/jp804003g

[1]	Shuyi ZHANG,Jingxian BAO,Bo WU,Liangshu ZHONG,Yuhan SUN. Research Progress on the Photocatalytic Conversion of Methane and Methanol [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 923-939.
[2]	Jincheng GUO,Yanfen LIN,Na TIAN,Shigang SUN. Modification of Tetrahexahedral Pd Nanocrystals with Ru and Their Performance for Methanol Electro-oxidation [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 749-754.
[3]	Yazhi YIN,Bing HU,Guoliang LIU,Xiaohai ZHOU,Xinlin HONG. ZnO@ZIF-8 Core-Shell Structure as Host for Highly Selective and Stable Pd/ZnO Catalysts for Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(3): 327-336.
[4]	Yanfang LIU,Bing HU,Yazhi YIN,Guoliang LIU,Xinlin HONG. One-Pot Surfactant-Free Synthesis of Transition Metal/ZnO Nanocomposites for Catalytic Hydrogenation of CO₂ to Methanol [J]. Acta Phys. -Chim. Sin., 2019, 35(2): 223-229.
[5]	Yanliang ZHAI, Shaolong ZHANG, Luoming ZHANG, Yunshan SHANG, Wenxuan WANG, Yu SONG, Caitong JIANG, Yanjun GONG. Effect of B and Al Distribution in ZSM-5 Zeolite on Methanol to Propylene Reaction Performance [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1248-1258.
[6]	Yanhui YI,Xunxun WANG,Li WANG,Jinhui YAN,Jialiang ZHANG,Hongchen GUO. Plasma-Triggered CH₃OH/NH₃ Coupling Reaction for Synthesis of Nitrile Compounds [J]. Acta Phys. -Chim. Sin., 2018, 34(3): 247-255.
[7]	Hui-Hui QIAN,Xiao HAN,Yan ZHAO,Yu-Qin SU. Flexible Pd@PANI/rGO Paper Anode for Methanol Fuel Cells [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1822-1827.
[8]	Yi YANG,Lai-Ming LUO,Di CHEN,Hong-Ming LIU,Rong-Hua ZHANG,Zhong-Xu DAI,Xin-Wen ZHOU. Synthesis and Electrocatalytic Properties of PtPd Nanocatalysts Supported on Graphene for Methanol Oxidation [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1628-1634.
[9]	Jian-Ping QIU,Yi-Wen TONG,De-Ming ZHAO,Zhi-Qiao HE,Jian-Meng CHEN,Shuang SONG. Electrochemical Reduction of CO₂ to Methanol at TiO₂ Nanotube Electrodes [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1411-1420.
[10]	Hassan GOLMOHAMMADI,Zahra DASHTBOZORGI,Sajad KHOOSHECHIN. Prediction of Blood-to-Brain Barrier Partitioning of Drugs and Organic Compounds Using a QSPR Approach [J]. Acta Phys. -Chim. Sin., 2017, 33(6): 1160-1170.
[11]	Ling-Ling LI,Ren CHEN,Jian DAI,Ye SUN,Zuo-Liang ZHANG,Xiao-Liang LI,Xiao-Wa NIE,Chun-Shan SONG,Xin-Wen GUO. Reaction Mechanism of Benzene Methylation with Methanol over H-ZSM-5 Catalyst [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 769-779.
[12]	Yang LU. Recent Progress in Crystal Facet Effect of TiO₂ Photocatalysts [J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2185-2196.
[13]	Si HU,Qing ZHANG,Yan-Jun GONG,Ying ZHANG,Zhi-Jie WU,Tao DOU. Deactivation and Regeneration of HZSM-5 Zeolite in Methanol-to-Propylene Reaction [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1785-1794.
[14]	Chun-Xia TIAN,Jun-Shuai YANG,Li LI,Xiao-Hua ZHANG,Jin-Hua CHEN. New Methanol-Tolerant Oxygen Reduction Electrocatalyst——Nitrogen-Doped Hollow Carbon Microspheres@Platinum Nanoparticles Hybrids [J]. Acta Phys. -Chim. Sin., 2016, 32(6): 1473-1481.
[15]	Jun-Feng ZHAO,Xiao-Li SUN,Xu-Ri HUANG,Ji-Lai LI. A Theoretical Study on the Reactivity and Charge Effect of PtRu Clusters toward Methanol Activation [J]. Acta Phys. -Chim. Sin., 2016, 32(5): 1175-1182.

Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10