Acta Phys. -Chim. Sin. ›› 2013, Vol. 29 ›› Issue (01): 11-16.doi: 10.3866/PKU.WHXB201210262

• THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY • Previous Articles     Next Articles

Vapor-Liquid Equilibrium Data for Carbon Dioxide+Dimethyl Carbonate Binary System

CHEN Li, ZHU Rong-Jiao, YUAN Ping-Fang, CAO Li-Qian, TIAN Yi-Ling   

  1. Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, P. R. China
  • Received:2012-07-16 Revised:2012-10-25 Published:2012-12-14

Abstract:

High pressure vapor-liquid equilibrium data for the carbon dioxide + dimethyl carbonate (DMC) binary system were measured at four temperatures in the 333.0 to 393.0 K range and under pressures ranging from 3.98 to 13.75 MPa. The experimental data were correlated with the Peng-Robison (PR) cubic equation of state and the van der Waals-1 mixing rule. The binary interaction parameters were also obtained. The agreement between experimental results and calculations was good.

Key words: Vapor-liquid equilibrium, High pressure, Binary system, Carbon dioxide, Dimethyl carbonate

MSC2000: 

  • O642