Ni/NiCo2O4电极的制备及其析氧反应性能

doi:10.3866/PKU.WHXB201303071

Abstract

Abstract:

Spinel-type NiCo₂O₄ powders were prepared by a sol-gel method, and Ni/NiCo₂O₄ electrode was prepared through composite sol method combined with sintering. The composition and structure of Ni/ NiCo₂O₄ were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energydispersive X-ray spectroscopy (EDS). Electrocatalytic properties of the Ni/NiCo₂O₄ electrode in the oxygen evolution reaction (OER) were studied in 5 mol·L^-1 KOH solution, using cyclic voltammertry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), chronoamperometry, and extended duration constant potential electrolysis. The Ni/NiCo₂O₄ electrode exhibited a lower OER overpotential, higher specific surface area, and better stability than a porous Ni electrode. The specific surface area of the Ni/NiCo₂O₄ electrode was 28.69 times greater than that of the porous Ni electrode, and its apparent activation energies decrease 166.78 and 162.15 kJ·mol^-1 at different overpotentials, respectively.

Key words: Sol-gel, NiCo₂O₄, Porous nickel, Oxygen evolution reaction, Electrocatalysis

MSC2000:

O646

WANG Sen-Lin, WANG Li-Pin, ZHANG Zhen-Hong. Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode[J].Acta Phys. -Chim. Sin., 2013, 29(05): 981-988.

References

(1) Liu, S. Y.;Wang, Y. X.; Xu, L. Battery 2006, 36 (2), 153.[刘世永, 王宇新, 许莉. 电池, 2006, 36 (2), 153.]
(2) John, M. B.; Takaaki, O. J. Electrochem. Soc. 1984, 131 (2),290. doi: 10.1149/1.2115565
(3) Huang, Q. H.; Li, Z. Y.;Wang,W. J. Power Sources 2007, 27 (Suppl), 241. [黄庆华, 李振亚, 王为. 电源技术, 2007, 27 (Suppl), 241.]
(4) Lee, C. K.; Striebel, K. A.; Mclarnon, F. R.; Cairns, E. J.J. Electrochem. Soc. 1997, 144 (11), 3801. doi: 10.1149/1.1838095
(5) Kumar, M.; Awasthi, R.; Pramanick, A. K.; Singh, R. N.Int. J. Hydrog. Energy 2011, 36 (20), 12698. doi: 10.1016/j.ijhydene.2011.07.029
(6) Ardizzone, S.; Spinodo, G.; Trasatti, S. Electrochim. Acta 1995,40 (16), 2683. doi: 10.1016/0013-4686(95)00238-A
(7) Bao, J. Z.;Wang, S. L. Acta Phys. -Chim. Sin. 2011, 27 (12),2849. [鲍晋珍, 王森林. 物理化学学报, 2011, 27 (12), 2849.]doi: 10.3866/PKU.WHXB20112849
(8) Gao, Y. Y.; Cao, D. X.;Wang, G. L.; Yin, C. L. ActaPhys. -Chim. Sin. 2010, 26 (1), 29. [高胤义, 曹殿学, 王贵领,尹翠蕾. 物理化学学报, 2010, 26 (1), 29.] doi: 10.3866/PKU.WHXB20100102
(9) Yuan, Z.; Deng, X. Y.; Li, J. B. J. Chem. Engineer 2011, 187 (4),1. [袁珍, 邓湘云, 李建保. 化学工程师, 2011, 187 (4), 1.]
(10) Chi, B.; Li, J. B.; Han, Y. S.; Chen, Y. J. Int. J. Hydrog. Energy2004, 29 (6), 605. doi: 10.1016/S0360-3199(03)00219-2
(11) Ye, Q.W.; Xiang, Y. C.; Ping, T. J.; Qing, Q. Z. Electrochim.Acta 2011, 56 (22), 7517. doi: 10.1016/j.electacta.2011.06.101
(12) Singh, R. N.; Pandey, J. P.; Singh, N. K.; Lal, B.; Chartier, P.;Koening, J. F. Electrochim. Acta 2000, 45 (12), 1911. doi: 10.1016/S0013-4686(99)00413-2
(13) Marco, J. F.; Gancedo, J. R.; Gracia, M.; Gautier, J. L.; Rmos,E.; Berry, F. J. J. Solid State Chem. 2000, 153 (1), 74. doi: 10.1006/jssc.2000.8749
(14) Kim, J. G.; Pugmire, D. L.; Battaglia, D.; Langell, M. A.J. Appl. Surf. Sci. 2000, 165 (1), 70. doi: 10.1016/S0169-4332(00)00378-0
(15) Baydi, M. E.; Tiwari, S. K.; Singh, R. N.; Rehspringer, J. L.;Chartier, P.; Koenig, J. F.; Poillerat, G. J. Solid Chem. 1995, 116 (1), 157. doi: 10.1006/jssc.1995.1197
(16) Barrow, D. A.; Petroff, T. E.; Sayer, M. J. Surface and ComingsTechnology 1995, 76-77 (1), 113.
(17) Rao, A. V. P.; Paik, D. S.; Komarneni, S. J. Electroceramics1998, 2 (3), 157. doi: 10.1023/A:1009918715122
(18) Yang, X. J. Study on the Process and Properties of PerovskiteType Ceramic Coatings Prepared by Sol-Gel Method. MSDissertation, Shandong University, Jinan, 2007. [杨晓洁.溶胶-凝胶法制备钙钛矿型涂层的工艺及性能研究[D]. 济南:山东大学, 2007.]
(19) Wu, A.; Salvado, I. M. M.; Vilarinho, P. M.; Baptista, J. L.Journal of European Ceramic Society 1997, 17 (12), 1443. doi: 10.1016/S0955-2219(97)00027-7
(20) Ramanan, S. R. Thin Solid Films 2001, 389 (1-2), 207. doi: 10.1016/S0040-6090(01)00825-2
(21) Zhang, Y.;Wang, S. L.; Li, C. C. Rare Metal Materials andEngineering 2012, 41 (3), 457. [张艺, 王森林, 李彩彩.稀有金属材料与工程, 2012, 41 (3), 457.]
(22) Wang, S. L.; Zhang, Y. Acta Phys. -Chim. Sin. 2011, 27 (6),1417. [王森林, 张艺. 物理化学学报, 2011, 27 (6), 1417.]doi: 10.3866/PKU.WHXB20110510
(23) Zha, Q. X. An Introduction to Electrode Kinetics, 3rd ed.;Science Press: Beijing, 2002; pp 240-260. [查全性. 电极过程动力学导论. 第三版. 北京: 科学出版社, 2002: 240-260.]
(24) Cao, C. N.; Zhang, J. Q. An Introduction to ElectrochemicalImpedance Spectroscopy; Science Press: Beijing, 2002; pp45-75. [曹楚南, 张鉴清. 电化学阻抗谱导论. 北京:科学出版社, 2002: 45-75.]
(25) Lapham, D. P.; Tseung, A. C. C. J. Mater. Sci. 2004, 39 (1), 251.doi: 10.1023/B:JMSC.0000007751.14703.4b
(26) Lian, K.; Thorpe, S. J.; Kirk, D.W. Electrochim. Acta 1992, 37 (11), 2039.
(27) Baronetto, D.; Kodintsev, I. M.; Trasatti, S. J. Appl.Electrochem. 1994, 24 (3), 190.
(28) Wu, G.; Li, N.; Dai, C. S.; Zhou, D. R. Chin. J. Catal. 2004, 25 (4), 321. [武刚, 李宁, 戴长松, 周德瑞. 催化学报, 2004,25 (4), 321.]

[1]	Xinjiang Cui, Feng Shi. Selective Conversion of CO₂ by Single-Site Catalysts [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2006080-0.
[2]	Yuan Zhou, Na Han, Yanguang Li. Recent Progress on Pd-based Nanomaterials for Electrochemical CO₂ Reduction [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 2001041-0.
[3]	Kunfang Tu, Guang Li, Yanxia Jiang. Effect of Temperature on the Electrocatalytic Oxidation of Ethanol [J]. Acta Phys. -Chim. Sin., 2020, 36(8): 1906026-0.
[4]	Yongli Tong, Meizhen Dai, Lei Xing, Hengqi Liu, Wanting Sun, Xiang Wu. Asymmetric Hybrid Capacitor Based on NiCo₂O₄ Nanosheets Electrode [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1903046-0.
[5]	Xiaolong Tang,Shenghui Zhang,Jing Yu,Chunxiao Lü,Yuqing Chi,Junwei Sun,Yu Song,Ding Yuan,Zhaoli Ma,Lixue Zhang. Preparation of Platinum Catalysts on Porous Titanium Nitride Supports by Atomic Layer Deposition and Their Catalytic Performance for Oxygen Reduction Reaction [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1906070-0.
[6]	Jingxuan Ge, Jun Hu, Yingting Zhu, Zonish Zeb, Dejin Zang, Zhaoxian Qin, Yichao Huang, Jiangwei Zhang, Yongge Wei. Recent Advances in Polyoxometalates for Applications in Electrocatalytic Hydrogen Evolution Reaction [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1906063-0.
[7]	Xiaodong YANG,Chi CHEN,Zhiyou ZHOU,Shigang SUN. Advances in Active Site Structure of Carbon-Based Non-Precious Metal Catalysts for Oxygen Reduction Reaction [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 472-485.
[8]	Zhou LIN,Linfan SHEN,Ximing QU,Junming ZHANG,Yanxia JIANG,Shigang SUN. Molybdenum Carbide Prepared by a Salt Sealing Approach as an Electrocatalyst for Enhanced Hydrogen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 523-530.
[9]	Chufeng ZHANG,Zhewei CHEN,Yuebin LIAN,Yujie CHEN,Qin LI,Yindong GU,Yongtao LU,Zhao DENG,Yang PENG. Copper-based Conductive Metal Organic Framework In-situ Grown on Copper Foam as a Bifunctional Electrocatalyst [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1404-1411.
[10]	Qingqing WANG, Jinling WANG, Shengxiang JIANG, Pingyun LI. Recent Progress in Sol-Gel Method for Designing and Preparing Metallic and Alloy Nanocrystals [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1186-1206.
[11]	Jordan LEE,Yong LI,Jianing TANG,Xiaoli CUI. Synthesis of Hydrogen Substituted Graphyne through Mechanochemistry and Its Electrocatalytic Properties [J]. Acta Phys. -Chim. Sin., 2018, 34(9): 1080-1087.
[12]	Pan LUO,Fang SUN,Ju DENG,Haitao XU,Huijuan ZHANG,Yu WANG. Tree-Like NiS-Ni₃S₂/NF Heterostructure Array and Its Application in Oxygen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1397-1404.
[13]	Hai-Yan WANG, Gao-Quan SHI. Layered Double Hydroxide/Graphene Composites and Their Applications for Energy Storage and Conversion [J]. Acta Physico-Chimica Sinica, 2018, 34(1): 22-35.
[14]	Xiao-Ru ZHANG,Yue-Feng XU,Shou-Yu SHEN,Yuan CHEN,Ling HUANG,Jun-Tao LI,Shi-Gang SUN. Reduced Graphene Oxide-LaFeO₃ Composite Nanomaterials as Bifunctional Catalyst for Rechargeable Lithium-Oxygen Batteries [J]. Acta Phys. -Chim. Sin., 2017, 33(11): 2237-2244.
[15]	Cui-Juan XUAN,Jie WANG,Jing ZHU,De-Li WANG. Recent Progress of Metal Organic Frameworks-Based Nanomaterials for Electrocatalysis [J]. Acta Phys. -Chim. Sin., 2017, 33(1): 149-164.

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo2O4 Electrode

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0

Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode