Ni/NiCo2O4电极的制备及其析氧反应性能

doi:10.3866/PKU.WHXB201303071

Abstract

Abstract:

Spinel-type NiCo₂O₄ powders were prepared by a sol-gel method, and Ni/NiCo₂O₄ electrode was prepared through composite sol method combined with sintering. The composition and structure of Ni/ NiCo₂O₄ were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), and energydispersive X-ray spectroscopy (EDS). Electrocatalytic properties of the Ni/NiCo₂O₄ electrode in the oxygen evolution reaction (OER) were studied in 5 mol·L^-1 KOH solution, using cyclic voltammertry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS), chronoamperometry, and extended duration constant potential electrolysis. The Ni/NiCo₂O₄ electrode exhibited a lower OER overpotential, higher specific surface area, and better stability than a porous Ni electrode. The specific surface area of the Ni/NiCo₂O₄ electrode was 28.69 times greater than that of the porous Ni electrode, and its apparent activation energies decrease 166.78 and 162.15 kJ·mol^-1 at different overpotentials, respectively.

Key words: Sol-gel, NiCo₂O₄, Porous nickel, Oxygen evolution reaction, Electrocatalysis

MSC2000:

O646

WANG Sen-Lin, WANG Li-Pin, ZHANG Zhen-Hong. Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode[J].Acta Phys. -Chim. Sin., 2013, 29(05): 981-988.

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Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode

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Preparation and Oxygen Evolution Reaction Performance of Ni/NiCo₂O₄ Electrode