石墨烯的纳米摩擦与磨损性质

doi:10.3866/PKU.WHXB201305031

Abstract

Abstract:

We prepared few-layer graphene samples by liquid-phase exfoliation in ethanol. By controlling the solvent temperature, sonication time and power, and centrifugation speed and time, we fabricated several-layer graphene from highly oriented pyrolytic graphite (HOPG). The obtained supernatant was added dropwise onto freshly cleaved mica surfaces. Nanotribological study of the samples under high vacuum by atomic force microscope (AFM) showed that frictional force decreased as the number of monolayers (ML) of graphene increased, and their frictional coefficient remained constant when the sample was thicker than about 4 ML. When the coverage reached 7 ML, the frictional coefficient was close to zero. In wear experiments, 2-ML graphene exhibited better wear resistance than the 4-ML sample and had no dependence on directional friction. We also measured the adhesion force of samples containing different numbers of layers of graphene and the mica surface, and found that substrate adhesion is not the main reason for the wear resistance properties of 2-ML graphene. Compared with single-layer graphene, the low friction coefficient of few-layer graphene makes it promising for application in areas such as data storage devices, nanoelectromechanical systems, and anti-wear coatings.

Key words: Highly oriented pyrolytic graphite, Graphene, Nanotribology, Atomic force microscope, Wear

MSC2000:

O647

ZHU Qi-Rong, LI Hui-Qin, LI Ning, CHAI Jing, GAO Run-Gang, LIANG Qi. Nanotribological and Wear Properties of Graphene[J].Acta Phys. -Chim. Sin., 2013, 29(07): 1582-1587.

References

(1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
(2) Castro Neto, A. H.; Guinea, F.; Peres, N. M. R.; Novoselov, K.S.; Geim, A. K. Rev. Mod. Phys. 2009, 81, 109. doi: 10.1103/RevModPhys.81.109
(3) Balandin, A. A.; Ghosh, S.; Bao,W. Z.; Calizo, I.; Teweldebrhan,D.; Miao, F.; Lau, C. N. Nano Lett. 2008, 8 (3), 902.doi: 10.1021/nl0731872
(4) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.doi: 10.1038/nmat1849
(5) Geim, A. K. Science 2009, 324, 1530. doi: 10.1126/science.1158877
(6) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A.A. Nature 2005, 438, 197. doi: 10.1038/nature04233
(7) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80 (6), 1339. doi: 10.1021/ja01539a017
(8) Hamilton, C. E.; Lomeda, J. R.; Sun, Z.; Tour, J. M.; Barron, A.R. Nano Lett. 2009, 9 (10), 3460. doi: 10.1021/nl9016623
(9) Renia, A.; Jia, X. T.; Ho, J.; Nezich, D.; Son, H.; Bulovic, V.;Dresselhaus, M. S.; Kong, J. Nano Lett. 2009, 9 (1), 30.doi: 10.1021/nl801827v
(10) Obraztsov, A. N. Nat. Nanotechnol. 2009, 4, 212. doi: 10.1038/nnano.2009.67
(11) Berger, C.; Song, Z.; Li, X.;Wu, X.; Brown, N.; Naud, C.;Mayou, D.; Li, T.; Hass, J.; Marchenkov, A. N.; Conrad, E. H.;First, P. N.; de Heer,W. A. Science 2006, 312, 1191.doi: 10.1126/science.1125925
(12) Donnet, C., Erdemir, A. Surf. Coat. Tech. 2004, 180-181, 76.
(13) Lee, C.; Li, Q.; Kalb,W.; Liu, X. Z.; Berger, H.; Carpick, R.W.;Hone, J. Science 2010, 328, 76. doi: 10.1126/science.1184167
(14) Filleter, T.; McChesney, J. L.; Bostwick, A.; Rotenberg, E.;Emtsev, K. V.; Seyller, T.; Horn, K.; Bennewitz, R. Phys. Rev. Lett. 2009, 102, 086102. doi: 10.1103/PhysRevLett.102.086102
(15) Kim, K. S.; Lee, H. J.; Lee, C.; Lee, S. K.; Jang, H.; Ahn, J. H.;Kim, J. H.; Lee, H. J. ACS Nano 2011, 5, 5107. doi: 10.1021/nn2011865
(16) Shin, Y. J.; Stromberg, R.; Nay, R.; Huang, H.;Wee, A. T. S.;Yang, H.; Bhatia, C. S. Carbon 2011, 49, 4070. doi: 10.1016/j.carbon.2011.05.046
(17) Lin, L. Y.; Kim, D. E.; Kim,W. K.; Jun, S. C. Surf. Coat. Tech.2011, 205, 4864. doi: 10.1016/j.surfcoat.2011.04.092
(18) Sandoz-Rosado, E. J.; Tertuliano, O. A.; Terrell, E. J. Carbon2012, 50, 4078. doi: 10.1016/j.carbon.2012.04.055
(19) Marchetto, D.; Held, C.; Hausen, F.;Wählisch, F.; Dienwiebel,M.; Bennewitz, R. Tribol. Lett. 2012, 48, 77. doi: 10.1007/s11249-012-9945-4
(20) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri,M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth,S.; Geim, A. K. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
(21) Lui, C. H.; Liu, L.; Mak, K. F.; Flynn, G.W.; Heinz, T. F.Nature 2009, 462, 339. doi: 10.1038/nature08569
(22) Li, Q. Y.; Lee, C. G.; Carpick, R.W.; Hone, J. Phys. Status Solidi B 2010, 247, 2909. doi: 10.1002/pssb.v247.11/12
(23) Du, X. Q.; Li, H. Q.; Zhu, Q. R.; Zou, Z. Q.; Liang, Q. Acta Phys. -Chim. Sin. 2011, 27 (10), 2457. [杜晓青, 李慧琴,朱齐荣, 邹志强, 梁齐. 物理化学学报, 2011, 27 (10), 2457.]doi: 10.3866/PKU.WHXB20111010
(24) Liang, Q.; Li, H. N.; Xu, Y. B.; Xiao, X. D. J. Phys. Chem. B2006, 110, 403. doi: 10.1021/jp054939o
(25) Shin, Y. J.;Wang, Y.; Huang, H.; Kalon, G.;Wee, A. T. S.; Shen,Z. X.; Bhatia, C. S.; Yang, H. Langmuir 2010, 26 (6), 3798.doi: 10.1021/la100231u

[1]	Jiali FANG, Xin CHEN, Chang LI, Yulian WU. Observation of the Gold Nanorods/Graphene Composite Formation and Motion with in situ Liquid Cell Transmission Electron Microscopy [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 808-815.
[2]	Zhe JIANG,Fei YU,Jie MA. Design of Graphene-based Adsorbents and Its Removal of Antibiotics in Aqueous Solution [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 709-724.
[3]	Kang YANG,Xiaorui SHUAI,Huachao YANG,Jianhua YAN,Kefa CEN. Electrochemical Performance of Activated Graphene Powder Supercapacitors Using a Room Temperature Ionic Liquid Electrolyte [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 755-765.
[4]	Peng PENG,Hongtao LIU,Bin WU,Qingxin TANG,Yunqi LIU. Nitrogen Doped Graphene with a p-Type Field-Effect and Its Fine Modulation [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1282-1290.
[5]	Kexin WANG,Liurong SHI,Mingzhan WANG,Hao YANG,Zhongfan LIU,Hailin PENG. Biomass Hydroxyapatite-templated Synthesis of 3D Graphene [J]. Acta Physico-Chimica Sinica, 2019, 35(10): 1112-1118.
[6]	Nanshu LIU,Si ZHOU,Jijun ZHAO. Electrical Conductance of Graphene with Point Defects [J]. Acta Physico-Chimica Sinica, 2019, 35(10): 1142-1149.
[7]	Yangheng XIONG,Hao WU,Jianshu GAO,Wen CHEN,Jingchao ZHANG,Yanan YUE. Toward Improved Thermal Conductance of Graphene-Polyethylene Composites via Surface Defect Engineering: a Molecular Dynamics Study [J]. Acta Physico-Chimica Sinica, 2019, 35(10): 1150-1156.
[8]	Qi HU,Chuanhong JIN. In Situ TEM Observation of Radiolysis and Condensation of Water via Graphene Liquid Cell [J]. Acta Phys. -Chim. Sin., 2019, 35(1): 101-107.
[9]	Ke CHEN,Zhenhua SUN,Ruopian FANG,Feng LI,Huiming CHENG. Development of Graphene-based Materials for Lithium-Sulfur Batteries [J]. Acta Phys. -Chim. Sin., 2018, 34(4): 377-390.
[10]	Chengzhen SUN,Bofeng BAI. Selective Permeation of Gas Molecules through a Two-Dimensional Graphene Nanopore [J]. Acta Phys. -Chim. Sin., 2018, 34(10): 1136-1143.
[11]	Hai-Yan WANG,Gao-Quan SHI. Layered Double Hydroxide/Graphene Composites and Their Applications for Energy Storage and Conversion [J]. Acta Phys. -Chim. Sin., 2018, 34(1): 22-35.
[12]	Hui-Hui QIAN,Xiao HAN,Yan ZHAO,Yu-Qin SU. Flexible Pd@PANI/rGO Paper Anode for Methanol Fuel Cells [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1822-1827.
[13]	Wei-Shi DU,Yao-Kang LÜ,Zhi-Wei CAI,Cheng ZHANG. Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1828-1837.
[14]	Ai-Hua TIAN,Wei WEI,Peng QU,Qiu-Ping XIA,Qi SHEN. One-Step Synthesis of SnS₂ Nanoflower/Graphene Nanocomposites with Enhanced Lithium Ion Storage Performance [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1621-1627.
[15]	Yi YANG,Lai-Ming LUO,Di CHEN,Hong-Ming LIU,Rong-Hua ZHANG,Zhong-Xu DAI,Xin-Wen ZHOU. Synthesis and Electrocatalytic Properties of PtPd Nanocatalysts Supported on Graphene for Methanol Oxidation [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1628-1634.

Nanotribological and Wear Properties of Graphene

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10