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Acta Phys. Chim. Sin.  2013, Vol. 29 Issue (12): 2481-2497    DOI: 10.3866/PKU.WHXB201310152
REVIEW     
Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects
ZHANG Hui1,3, YAN Jian-Xin1, WU Shu-Ting2, LI Dan1, WAN Shi-Gang1, DING Lei1, LIN Li-Rong1
1 Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2 Department of Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China;
3 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Struture of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
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Abstract  

In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations.



Key wordsSolid-state chiroptical spectroscopy      Circular dichroism      Method of measurement      Concentration effect      Atropisomerism      Mirror symmetry breaking     
Received: 19 July 2013      Published: 15 October 2013
MSC2000:  O641  
Fund:  

The project was supported by the National Natural Science Foundation of China (21273175, 21271150, 21001026) and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (20110006, 20130008).

Corresponding Authors: ZHANG Hui, WU Shu-Ting     E-mail: huizhang@xmu.edu.cn;shutingwu@fzu.edu.cn
Cite this article:

ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects. Acta Phys. Chim. Sin., 2013, 29(12): 2481-2497.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB201310152     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2013/V29/I12/2481

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