基于稀土配合物的有机光盲型紫外探测器

doi:10.3866/PKU.WHXB201310301

Abstract

Abstract:

Anew type of organic visible-blind ultraviolet (UV) photodetector based on tri(dibenzoylmethane)(4, 7-biphenyl-1,10-phenanthroline)europium (Ⅲ) [Eu(DBM)₃BPhen] as an electron donor and [6,6]-phenyl-C-61-butyric acid methyl ester ([60]PCBM) as an electron acceptor was fabricated. A peak response of 26 mA·W^-1 and external quantum efficiency of 9.1% were obtained under illumination with 360 nm UV light at 2.1 mW·cm^-2. This was because of the high UV absorption of Eu(DBM)₃BPhen and the long lifetime, 300 μs, of Eu³⁺ ions, resulting in high exciton dissociation efficiency. Distinct photoluminescence quenching and photoconductivity of Eu(DBM)₃BPhen were obtained by doping with [60]PCBM. A strong persistent photoconductivity was observed, which could be attributed to low charge carrier transportation and slow release of trapped exciton states in the blend films after the UV light is turned off.

Key words: Organic visible-blind, Ultraviolet photodetector, Persistent photoconductivity

MSC2000:

O644

LI Ling-Liang, ZHANG Fu-Jun, WANG Zi-Xuan, AN Qiao-Shi, WANG Jian, XU Zheng. Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex[J].Acta Phys. -Chim. Sin., 2013, 29(12): 2624-2629.

References

(1) Forrest, S. R. Nature 2004, 428, 911. doi: 10.1038/nature02498
(2) Gong, X. O.; Tong, M. H.; Park, S. H.; Liu, M.; Jen, A.; Heeger,A. J. Sensors 2010, 10, 6488. doi: 10.3390/s100706488
(3) Wu, S. H.; Li,W. L.; Chu, B.; Lee, C. S.; Su, Z. S.;Wang, J. B.;Ren, Q. J.; Hu, Z. Z.; Zhang, Z. Q. Appl. Phys. Lett. 2010, 97,023306. doi: 10.1063/1.3463483
(4) Zhu, L.; Dai, Q.; Hu, Z. F.; Zhang, X. Q.;Wang, Y. S. Opt. Lett.2011, 36, 1821. doi: 10.1364/OL.36.001821
(5) Zhu, L.;Wang,W. S.; Yao, Z. G.; Zhang, X. Q.;Wang, Y. S.IEEE Trans. Electron Devices 2012, 59, 3583. doi: 10.1109/TED.2012.2219864
(6) Zhang, J. L.; Nan, Y. X.; Li, H. G.; Qiu,W. M.; Yang, X.;Wu,G.; Chen, H. Z.;Wang, M. Sensors and Actuators B: Chemical2012, 162, 321. doi: 10.1016/j.snb.2011.12.088
(7) Kalyani, N. T.; Dhoble, S. J. Renewable & Sustainable Energy Reviews 2012, 16, 2696. doi: 10.1016/j.rser.2012.02.021
(8) Canzler, T.W.; Kido, J. Org. Electron 2006, 7, 29. doi: 10.1016/j.orgel.2005.10.004
(9) Zhang, F. J.; Zhuo, Z. L.; Zhang, J.;Wang, X.; Xu, X.W.;Wang, Z. X.; Xin, Y. S.;Wang, J.;Wang, J.; Tang,W. H.; Xu, Z.;Wang, Y. S. Solar Energy Materials and Solar Cells 2012, 97,71. doi: 10.1016/j.solmat.2011.09.006
(10) Zhang, F. J.; Xu, X.W.; Tang,W. H.; Zhang, J.; Zhuo, Z. L.;Wang, J.;Wang, J.; Xu, Z.;Wang, Y. S. Solar Energy Materials and Solar Cells 2011, 95, 1785. doi: 10.1016/j.solmat.2011.02.002
(11) Zhuo, Z. L.; Zhang, F. J.; Lv, Y. G.; Xu, Z.; Lu, L. F.; Li, J. M.;Wang, Y. S. Phys. Scr. 2010, 82, 055703. doi: 10.1088/0031-8949/82/05/055703
(12) Li, B.; Ma, D. G.; Zhang, H. J.; Zhao, X. J.; Ni, J. Z. Acta Phys. -Chim. Sin. 1998, 14, 305. [李斌, 马东阁, 张洪杰,赵晓江, 倪嘉缵. 物理化学学报, 1998, 14, 305.] doi: 10.3866/PKU.WHXB19980404
(13) Huang, L.; Cheng, L.; Yu, H.; Zhou, L.; Sun, J.; Zhong, H.; Li,X.; Zhang, J.; Tian, Y.; Zheng, Y.; Yu, T.;Wang, J.; Chen, B.Physica B: Condensed Matter 2011, 406, 2745. doi: 10.1016/j.physb.2011.04.019
(14) Huang, L.; Cheng, L.; Yu, H.; Zhang, J.; Zhou, L.; Sun, J.;Zhong, H.; Li, X.; Tian, Y.; Zheng, Y.; Yu, T.; Li, C.; Zhong, H.;Liu,W.; Zhang, L.;Wang, J.; Chen, B. Opt. Commun. 2012,285, 1476. doi: 10.1016/j.optcom.2011.10.006
(15) Zhuo, Z. L.; Zhang, F. J.; Xu, X.W.;Wang, J.; Lu, L. F.; Xu, Z.Acta Phys. -Chim. Sin. 2011, 27, 875. [卓祖亮, 张福俊, 许晓伟, 王健, 卢丽芳, 徐征. 物理化学学报, 2011, 27, 875.]doi: 10.3866/PKU.WHXB20110414
(16) Kajii, H.; Katsura, A.; Ohmori, H.; Sato, Y.; Hamasaki, T.;Ohmori, Y. J. Non-Cryst. Solids 2012, 358, 2504. doi: 10.1016/j.jnoncrysol.2011.12.097
(17) Li, Y. F. Accounts of Chemical Research 2012, 45, 723. doi: 10.1021/ar2002446
(18) Cai, S.; Parish, G.; Dell, J. M.; Nener, B. D. J. Appl. Phys. 2004,96, 1019.
(19) Verbakel, F.; Meskers, S. C. J.; Janssen, R. A. J. Appl. Phys. Lett. 2006, 89, 102103. doi: 10.1063/1.2345612
(20) Reyes, P. I.; Ku, C. J.; Duan, Z. Q.; Xu, Y.; Garfunkel, E.; Lu, Y.C. Appl. Phys. Lett. 2012, 101, 031118. doi: 10.1063/1.4737648
(21) Dasgupta, S.; Knaak, C.; Moser, J.; Bichler, M.; Roth, S. F.;Morral, A. F. I.; Abstreiter, G.; Grayson, M. Appl. Phys. Lett.2007, 91, 142120. doi: 10.1063/1.2794012
(22) Hirsch, M. L. T.;Wolk, J. A.;Walukiewicz,W.; Haller, E. E.Appl. Phys. Lett. 1997, 71, 1098. doi: 10.1063/1.119738
(23) Kim, C. H.; Kisiel, K.; Jung, J.; Ulanski, J.; Tondelier, D.;Geffroy, B.; Bonnassieux, Y.; Horowitz, G. Synth. Met. 2012,162, 460. doi: 10.1016/j.synthmet.2011.12.021
(24) Nardes, A. M.; Ferguson, A. J.; Whitaker, J. B.; Larson, B.W.;Larsen, R. E.; Maturová, K.; Graf, P. A.; Boltalina, O. V.;Strauss, S. H.; Kopidakis, N. Adv. Funct. Mater. 2012, 22,4115. doi: 10.1002/adfm.v22.19
(25) Kim, C. H.; Choi, M. H.; Lee, S. H.; Jang, J.; Kirchmeyer, S.Appl. Phys. Lett. 2010, 96, 123301. doi: 10.1063/1.3372619
(26) Li, L.; Zhang, F.; An, Q.;Wang, Z.;Wang, J.; Tang, A.; Peng,H.; Xu, Z.;Wang, Y. Opt. Lett. 2013, 38, 3823. doi: 10.1364/OL.38.003823

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Organic Visible-Blind Ultraviolet Photodetectors Based on Rare Earth Complex

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