互通多孔碳/二氧化锰纳米复合材料的原位水热合成及电化学性能

doi:10.3866/PKU.WHXB201403061

Abstract

Abstract:

This article describes the electrochemical performance of a novel interconnected porous carbon/ MnO₂ (IPC/MnO₂) composite prepared by in situ self-limiting deposition under hydrothermal condition. The morphology and structure were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA), and the electrochemical behavior was investigated using cyclic voltammetry (CV), charge-discharge tests, electrochemical impedance spectroscopy (EIS), and cycle life tests. The results showed that MnO₂ grew homogeneously on the IPC surface, forming a hierarchical microstructure. The MnO₂ had a typical K-Birnessite-type crystal structure and the MnO₂ content was about 34%(w). At high synthetic temperatures, the MnO₂ particles on the IPC surface were smaller. The prepared electrode material exhibited a good electrochemical capacitance performance. As the reaction temperature increased, the specific capacitance of the IPC/MnO₂ composite first increased and then remained constant. The IPC/MnO₂ composite synthesized at 100 ℃ had the maximum specific capacitance, 411 F·g^-1, in a three-electrode system. An asymmetric supercapacitor was constructed with the IPC/MnO₂ composite as the positive electrode and activated carbon (AC) as the negative electrode, in a 1 mol·L^-1 Na₂SO₄ electrolyte. The results showed that the corresponding potential window increased from 1 to 1.8 V. The maximum specific capacitance of the asymmetric supercapacitor was 86 F·g^-1 and a good rate capability was achieved.

Key words: Manganese oxide, Interconnected porous carbon, Supercapacitor, Composite electrode material

MSC2000:

O646

ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long. Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO₂ Composites[J].Acta Phys. -Chim. Sin., 2014, 30(5): 881-890.

References

(1) El-Kady, M. F.; Strong, V.; Dubin, S.; Kaner, R. B. Science 2012, 335, 1326. doi: 10.1126/science.1216744
(2) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7, 845. doi: 10.1038/nmat2297
(3) Wen, C. M.; Wen, Z. Y.; You, Z.; Wang, X. F. Chin. J. Chem. Phys. 2012, 25, 209. doi: 10.1088/1674-0068/25/02/209-213
(4) Wang, X. F.; You, Z.; Ruan, D. B. Chin. J. Chem. Phys. 2005, 18, 635.
(5) Kim, I. H.; Kim, K. B. J. Electrochem. Soc. 2006, 153, A383.
(6) Nagarajan, N.; Cheong, M.; Zhitomirsky, I. Mater. Chem. Phys. 2007, 103 (1), 47. doi: 10.1016/j.matchemphys.2007.01.005
(7) Yu, H. M.; Zheng, W.; Cao, G. S.; Zhao, X. B. Acta Phys. -Chim. Sin. 2009, 25 (11), 2186. [余红明, 郑威, 曹高劭, 赵新兵. 物理化学学报, 2009, 25 (11), 2186.] doi: 10.3866/PKU.WHXB20091113
(8) Fischer, A. E.; Pettigrew, K. A.; Rolison, D. R.; Stroud, R. M.; Long, J.W. Nano Lett. 2007, 7 (2), 281.
(9) Sharma, R. K.; Oh, H. S.; Shul, Y. G.; Kim, H. J. Power Sources 2007, 173, 1024. doi: 10.1016/j.jpowsour.2007.08.076
(10) Huang, H. J.; Wang, X. Nanoscale 2011, 3, 3185. doi: 10.1039/c1nr10229j
(11) Wang, H. L.; Casalongue, H. S.; Liang, Y. Y.; Dai, H. J. J. Am. Chem. Soc. 2010, 132, 7472. doi: 10.1021/ja102267j
(12) Sawangphruk, M.; Srimuk, P.; Chiochan, P.; Krittayavathananon, A.; Luanwuthi, S.; Limtrakul, J. Carbon 2013, 60, 109. doi: 10.1016/j.carbon.2013.03.062
(13) Yan, J.; Fan, Z. J.; Wei, T.; Qian, W. Z.; Zhang, M. L.; Wei, F. Carbon 2010, 48, 3825.
(14) Song, M. K.; Cheng, S.; Chen, H. Y.; Qin, W. T.; Nam, K.W.; Xu, S. C.; Yang, X. Q.; Bongiorno, A.; Lee, J.; Bai, J. M.; Tyson, T. A.; Cho, J.; Liu, M. L. Nano Lett. 2012, 12, 3483. doi: 10.1021/nl300984y
(15) Bordjiba, T.; Belanger, D. J. Electrochem. Soc. 2009, 156, A378.
(16) Hu, L. B.; Pasta, M.; La Mantia, F.; Cui, L. F.; Jeong, S.; Deshazer, H. D.; Choi, J.W.; Han, S. M.; Cui, Y. Nano Lett. 2010, 10, 708.
(17) Chen, W.; Xie, X.; Liu, N.; Yang, Y.; Wu, H.; Yao, Y.; Pasta, M.; Alshareef, H. N.; Cui, Y. ACS Nano 2011, 5, 8904. doi: 10.1021/nn203085j
(18) Prasad, K. R.; Miura, N. J. Power Sources 2004, 135, 354. doi: 10.1016/j.jpowsour.2004.04.005
(19) Yan, J.; Fan, Z.; Wei, T.; Qian, W.; Zhang, M.; Wei, F. Carbon 2009, 47, 3371. doi: 10.1016/j.carbon.2009.08.001
(20) Yang, Y. J.; Liu, E. H.; Li, L. M.; Huang, Z. Z.; Shen, H. J.; Xiang, X. X. J. Alloy. Compd. 2009, 487, 564.
(21) Yan, J.; Fan, Z.; Wei, T.; Qie, Z.; Wang, S.; Zhang, M. Mater. Sci. Eng. B 2008, 151, 174. doi: 10.1016/j.mseb.2008.05.018
(22) Chen, S.; Zhu, J.; Wu, X.; Han, Q.; Wang, X. ACS Nano 2010, 4, 2822. doi: 10.1021/nn901311t
(23) Zhang, J.; Jiang, J.; Zhao, X. S. J. Phys. Chem. C 2011, 115, 6448. doi: 10.1021/jp200724h
(24) Jin, X. B.; Zhou, W. Z.; Zhang, S.W.; Chen, G. Z. Small 2007, 3, 1513.
(25) Tan, Y. T.; Ran, F.; Kong, L. B.; Liu, J.; Kang, L. Synthetic Metals 2012, 162, 114. doi: 10.1016/j.synthmet.2011.11.020
(26) Liu, M. C.; Kong, L. B.; Lu, C.; Li, X. M.; Luo, Y. C.; Kang, L.; Li, X. H.; Walsh, F. C. J. Electrochem. Soc. 2012, 159, A1.
(27) Li, L.; He, Y. Q.; Chu, X. F.; Li, Y. M.; Sun, F. F.; Huang, H. Z. Acta Phys. -Chim. Sin. 2013, 29, 1681. [李乐, 贺蕴秋, 储晓菲, 李一鸣, 孙芳芳, 黄河洲. 物理化学学报, 2013, 29, 1681.] doi: 10.3866/PKU.WHXB201305223
(28) Khomenko, V.; Raymundo-Pinero, E.; Beguin, F. J. Power Sources 2006, 153, 183. doi: 10.1016/j.jpowsour.2005.03.192
(29) Wang, X.; Li, Y. D. Chem. Eur. J. 2003, 9, 300.
(30) Song, X. C.; Zhao, Y.; Zheng, Y. F. Cryst. Growth Des. 2007, 7, 159. doi: 10.1021/cg060536h
(31) Ma, R.; Bando, Y.; Zhang, L.; Sasaki, T. Adv. Mater. 2004, 16, 918.
(32) Toupin, M.; Brousse, T.; Bélanger, D. Chem. Mater. 2004, 16, 3184. doi: 10.1021/cm049649j
(33) Zolfaghari, A.; Naderi, H. R.; Mortaheb, H. R. J. Electroanal. Chem. 2013, 697, 60.
(34) Izadi-Najafabadi, A.; Yasuda, S.; Kobashi, K.; Yamada, T.; Futaba, D. N.; Hatori, H.; Yumura, M.; Iijima, S.; Hata, K. Adv. Mater. 2010, 22, E235.
(35) Qu, Q. T.; Zhang, P.; Wang, B.; Chen, Y. H.; Tian, S.; Wu, Y. P.; Holze, R. J. Phys. Chem. C 2009, 113, 14020.

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Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO₂ Composites

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Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO₂ Composites