氮掺杂还原氧化石墨烯负载铂催化剂的制备及甲醇电氧化性能

doi:10.3866/PKU.WHXB201405052

Abstract

Abstract:

Nitrogen-doped reduced graphene oxide materials (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites were used as a support for the immobilization of Pt nanoparticles. The morphologies and structures of N-RGO and Pt/N-RGO were comprehensively characterized by transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Raman spectroscopy. The electrocatalytic activities of the as-prepared catalysts for CO stripping and methanol oxidation were investigated by cyclic voltammetry and chronoamperometry. The results showed that GO was reduced to multilayer graphene by thermal annealing accompanied with successful incorporation of N atoms into RGO. Moreover, the presence of the doped N atoms enhanced the surface defects and electrical conductivity of the RGO materials. Pt nanoparticles on N-RGO were more evenly dispersed, had better CO tolerance, and had higher activity/stability for methanol oxidation than those on RGO without N doping.

Key words: Polyaniline, Reduced graphene oxide, Nitrogen-doped, Platinum electrocatalyst, Methanol oxidation

MSC2000:

O646

WANG Li, MA Jun-Hong. Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation[J].Acta Phys. -Chim. Sin., 2014, 30(7): 1267-1273.

References

(1) Wei, D.; Liu, Y.;Wang, Y.; Zhang, H.; Huang, L.; Yu, G. Nano Lett. 2009, 9, 1752. doi: 10.1021/nl803279t
(2) Yang, Z.; Yao, Z.; Li, G.; Fang, G.; Nie, H.; Liu, Z.; Zhou, X.; Chen, X.; Huang, S. ACS Nano 2012, 6, 205. doi: 10.1021/nn203393d
(3) Shao, Y. Y.; Sui, J. H.; Yin, G. P.; Gao, Y. Z. Appl. Catal. B 2008, 79 (1), 89. doi: 10.1016/j.apcatb.2007.09.047
(4) Xiong, B.; Zhou, Y. K.; O′Hayre, R.; Shao, Z. P. Appl. Surf. Sci. 2013, 266, 433. doi: 10.1016/j.apsusc.2012.12.053
(5) Wu, J.; Hu, F.; Hu, X.;Wei, Z. D.; Shen, P. K. Electrochimica Acta 2008, 53 (28), 8341. doi:10.1016/j.electacta.2008.06.051
(6) Zhou, C.W.; Kong, J.; Yenilmez, E.; Dai, H. J. Science 2000, 290, 1552. doi: 10.1126/science.290.5496.1552
(7) He, D. P.; Jiang, Y. L.; Lv, H. F.; Pan, M.; Mu, S. C. Applied Catalysis B: Environmental 2013, 132 -133, 379.
(8) Xiao, X.; Zhou, Y. K.; Lu, J. M.; Tian, X. H.; Zhu, H. X.; Liu, J. G. Electrochimica Acta 2014, 120, 439. doi: 10.1016/j. electacta.2013.12.062
(9) Zhang, L. S.; Liang, X. Q.; Song,W. G.;Wu, Z. Y. Phys. Chem. Chem. Phys. 2010, 12, 12055. doi: 10.1039/c0cp00789g
(10) Sun, L.;Wang, L.; Tian, G. G.; Tan, T. X.; Xie, Y.; Shi, K. Y.; Li, M. T.; Fu, H. G. RSC Adv. 2012, 2, 4498. doi: 10.1039/c2ra01367c
(11) Wang, Y.; Shao, Y. Y.; Matson, D.W.; Li, J. H.; Lin, Y. H. ACS Nano 2010, 4, 1790.
(12) Hassan, F. M.; Chabot, V.; Li, J. D.; Kim, B. K.; Ricardez-Sandoval, L.; Yu, A. P. J. Mater. Chem. A 2013, 1, 2904.
(13) Xu, X.; Zhou, Y. K.; Yuan, T.; Li, Y.W. Electrochimica Acta 2013, 112, 587. doi: 10.1016/j.electacta.2013.09.038
(14) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Adv. Energy Mater. 2012, 2 (7), 884.
(15) Lin, Z.Y.; Song, M. K.; Ding, Y.; Liu, Y.; Liu, M. L.;Wong, C. P. Phys. Chem. Chem. Phys. 2012, 14, 3381. doi: 10.1039/c2cp00032f
(16) Sheng, Z. H.; Shao, L.; Chen, J. J.; Bao,W. J.;Wang, F. B.; Xia, X. H. ACS Nano 2011, 5, 4350. doi: 10.1021/nn103584t
(17) Lin, Z. Y.;Waller, G.; Liu, Y.; Liu, M. L.;Wong, C. P. Nano Energy 2013, 2, 241. doi: 10.1016/j.nanoen.2012.09.002
(18) Lai, L. F.; Potts, J. R.; Zhan, D.;Wang, L.; Poh, C. K.; Tang, C. H.; Gong, H.; Shen, Z. X.; Lin, J. Y.; Rodney, S. R. Energy Environ. Sci. 2012, 5, 7936. doi: 10.1039/c2ee21802j
(19) Wu, G.; Mack, N. H.; Gao,W.; Ma, S. G.; Zhong, R. Q.; Han, J. T.; Baldwin, J. K.; Zelenay, P. ACS Nano 2012, 6 (11), 9764. doi: 10.1021/nn303275d
(20) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339. doi: 10.1021/ja01539a017
(21) Wu, G.; Swaidan, R. J.; Li, D. Y.; Li, N. Electrochimica Acta 2008, 53, 7622. doi: 10.1016/j.electacta.2008.03.082
(22) Stankovicha, S.; Dikina, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y. Y.;Wu, Y.; Nguyen, S. B. T.; Ruoff, R. S. Carbon 2007, 45 (7), 1558. doi: 10.1016/j.carbon.2007.02.034
(23) Liu, S.;Wang, J.; Zeng, J.; Ou, J.; Li, Z.; Liu, X.; Yang, S. G. J. Power Sources 2010, 195 (15), 4628. doi: 10.1016/j. jpowsour.2010.02.024
(24) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; Geim, A. K. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
(25) Kudin, K. N.; Ozbas, B.; Schniepp, H. C.; Prud′homme, R. K.; Aksay, I. A.; Car, R. Nano Lett. 2008, 8, 36. doi: 10.1021/nl071822y
(26) Xin, Y. C.; Liu, J. G.; Zhou, Y.; Liu,W. M.; Gao, J.; Xie, Y.; Yin, Y.; Zou, Z. G. Electrochimica Acta 2012, 60, 354. doi: 10.1016/j.electacta.2011.11.062
(27) Kuo, P. L.; Chen,W. F.; Huang, H. Y.; Chang, I. C.; Dai, S. A. J. Phys. Chem. B 2006, 110, 3071.
(28) Wu, G.; Li, D.; Dai, C.;Wang, D.; Li, N. Langmuir 2008, 24, 3566. doi: 10.1021/la7029278
(29) Groves, M. N.; Chan, A. S.W.; Malardier, J. C.; Jugroot, M. Chem. Phys. Lett. 2009, 481, 214. doi: 10.1016/j.cplett.2009.09.074
(30) Zhou, Y.; Neyerlin, K.; Olson, T. S.; Pylypenko, S.; Bult, J.; Dinh, H. N.; Gennett, T.; Shao, Z. P.; O'Hayre, R. Energy Environ. Sci. 2010, 3 (10), 1437. doi: 10.1039/c003710a
(31) Wang, S. Y.; Jiang, S. P.;Wang, X.; Guo, J. Electrochimica Acta 2011, 56, 1563. doi: 10.1016/j.electacta.2010.10.055
(32) Zheng, S. F.; Hu, J. S.; Zhong, L. S.;Wan, L. J.; Song,W. G. J. Phys. Chem. C 2007, 111, 11174. doi: 10.1021/jp0727042
(33) Zheng, B.; Zheng,W. T.; Zhang, K.;Wen, Q. B.; Zhu, J. Q.; Meng, S. H.; He, X. D.; Han, J. C. Carbon 2006, 44, 962. doi: 10.1016/j.carbon.2005.10.009

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Synthesis and Electrocatalytic Properties of Pt Nanoparticles on Nitrogen-Doped Reduced Graphene Oxide for Methanol Oxidation

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