氨蒸发诱导法制备纳米结构LiNi1/3Co1/3Mn1/3O2及其作为高功率型锂离子电池正极材料的性能

doi:10.3866/PKU.WHXB201405303

Acta Phys. -Chim. Sin. ›› 2014, Vol. 30 ›› Issue (8): 1481-1486.doi: 10.3866/PKU.WHXB201405303

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Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

HUA Wei-Bo¹, ZHENG Zhuo¹, LI Long-Yan¹, GUO Xiao-Dong¹, LIU Heng², SHEN Chong-Heng³, WU Zhen-Guo^1,3, ZHONG Ben-He¹, HUANG Ling³

1. Phosphorus Resources Comprehensive Utilization & Clean Processing Center of Ministry of Education, School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2. School of Materials Science and Engineering, Sichuan University, Chengdu 610065, P. R. China;
3. State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received:2014-04-23 Revised:2014-05-29 Published:2014-07-18
Contact: GUO Xiao-Dong E-mail:xiaodong2009@scu.edu.cn
Supported by:
The project was supported by the Sichuan University Funds for Young Scientists, China (2011SCU11081) and Research Fund for the Doctoral Program of Higher Education, the Ministry of Education, China (20120181120103).

Abstract

Abstract:

We report on an ammonia-evaporation-induced synthetic method for nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ cathode material. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high- resolution transmission electron microscopy (HRTEM), energy- dispersive X- ray spectroscopy (EDS), Brunauer-Emmett-Teller nitrogen sorption, and galvanostatic charge-discharge tests were applied to analyze the crystal structure, micromorphology, and electrochemical properties of nanostructured LiNi_1/3Co_1/3Mn_1/3O₂. The results show that it has a well-ordered layered α-NaFeO₂ with little cation mixing. Awalnutkernel- like morphology is formed by nanosheets, leading to a nanoporous material. The lateral plane of nanosheets are {010}-faceted, which could provide multiple channels for Li⁺-ion migration. The electrochemical properties of the lithium cells used this material as cathode are excellent: the specific discharge capacity at 0.5C,1C, 3C, 5C and 10C is, respectively, up to 172.90, 153.95, 147.09, 142.16, and 131.23 mAh·g^-1 between 3.0 and 4.6 V at room temperature. These excellent features will make the nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ become a positive electrode material of potential interest for useful applications, such as in electric vehicles and hybrid electric vehicles.

Key words: Lithium-ion battery, Cathode material, LiNi_1/3Co_1/3Mn_1/3O₂, Nanostructure, Ammonia-evaporation-induced synthetic method, Electrochemical property

MSC2000:

O646

HUA Wei-Bo, ZHENG Zhuo, LI Long-Yan, GUO Xiao-Dong, LIU Heng, SHEN Chong-Heng, WU Zhen-Guo, ZHONG Ben-He, HUANG Ling. Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery[J].Acta Phys. -Chim. Sin., 2014, 30(8): 1481-1486.

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Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

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Synthesis of Nanostructured LiNi1/3Co1/3Mn1/3O2 by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery

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Synthesis of Nanostructured LiNi_1/3Co_1/3Mn_1/3O₂ by Ammonia-Evaporation-Induced Synthesis and Its Electrochemical Properties as a Cathode Material for a High-Power Li-Ion Battery