四种深共融溶剂的性质:密度、电导率、动力粘度及折光率

doi:10.3866/PKU.WHXB201506111

Abstract

Abstract:

Four deep eutectic solvents (DESs) were prepared from tetrabutylammonium chloride: tetrabutylammonium chloride:propionic acid [TBAC:2PA], tetrabutylammonium chloride:ethylene glycol [TBAC:2EG], tetrabutylammonium chloride:polyethylene glycol [TBAC:2PEG], and tetrabutylammonium chloride:phenylacetic acid [TBAC:2PAA]. The density, electrical conductivity, dynamic viscosity, and refractive index of the samples were measured at 288.15-338.15 K under atmospheric pressure. The influence of the temperature on the density, electrical conductivity, dynamic viscosity, and refractive index are discussed. The thermal expansion coefficient, molecular volume, standard molar entropy, and lattice energy were determined from the measured values using empirical equations. The temperature dependences on the electrical conductivity and dynamic viscosity of the DESs were fitted by the Vogel-Fulcher-Tamman (VFT) equation. The Arrhenius equation is also discussed for the electrical conductivity and dynamic viscosity. The above study will be of great significance for the industrial and engineering applications of DESs.

Key words: Deep eutectic solvent, Density, Electrical conductivity, Dynamic viscosity, Refractive index

MSC2000:

O642

Click here to download Supporting Info material in PDF type

Hong-Zhen. SU,Jing-Mei. YIN,Qing-Shan. LIU,Chang-Ping. LI. Properties of Four Deep Eutectic Solvents: Density, Electrical Conductivity, Dynamic Viscosity and Refractive Index[J].Acta Phys. -Chim. Sin., 2015, 31(8): 1468-1473.

References

1	Zhang Q. H. ; Vigier K. D. O. ; Royer S. ; Jérôme F. Chem. Soc. Rev. 2012, 41, 7108.
2	Jhong H. R. ; Wong D. S. H. ; Wan C. C. ; Wang Y. Y. ; Wei T. C. Electrochem. Commun. 2009, 11, 209.
3	Singh B. S. ; Lobo H. R. ; Shankarling G. S. Catal. Commun. 2012, 24, 70.
4	Dai, Y.; Sprosen, J. V.; Witkamp, G. J.; Verpoorte, R.; Choi, Y. H. Anal. Chim. Acta 2013, 766, 61. doi: 10.1016/j.aca. 2012.12.019
5	Francisco M. ; Bruinhorst A. V. D. ; Kroon M. C. Angew. Chem. Int. Edit. 2013, 52, 3074.
6	Krystof M. ; Pérez-Sánchez M. ; María P. D. D. ChemSusChem 2013, 6, 630.
7	Maugeri Z. ; María P. D. D. ChemCatChem 2014, 6, 1535.
8	Serrano, M. C.; Gutiérrez, M. C.; Jiménez, R.; Ferrer, M. L.; Monte, F. D. Chem. Commun. 2012, 48, 579. doi: 10.1039/C1CC15284J
9	Zhang Z. H. ; Zhang X. N. ; Mo L. P. ; Li Y. X. ; Ma F. P. Green Chem. 2012, 14, 1502.
10	Carriazo D. ; Gutirrez M. C. ; Pic F. ; Rojo J. M. ; Fierro J. L. G. ; Ferrer M. L. ; Monte F. D. ChemSusChem 2012, 5, 1405.
11	Abbott A. P. ; Ttaib K. E. ; Frisch G. ; Ryder K. S. ; Weston D. Phys. Chem. Chem. Phys. 2012, 14, 2443.
12	Monte F. D. ; Carriazo D. ; Serrano M. C. ; Gutirrez M. C. ; Ferrer M. L. ChemSusChem 2014, 7, 999.
13	Abbott A. P. ; Cullis P. M. ; Gibson M. J. ; Harris R. C. ; Raven E. Green Chem. 2007, 9, 868.
14	Shahbaz K. ; Mjalli F. S. ; Hashim M. A. ; AlNashef I. M. Energy Fuels 2011, 25, 2671.
15	Li C. P. ; Li D. ; Zou S. S. ; Li Z. ; Yin J. M. ; Wang A. L. ; Cui Y. N. ; Yao Z. L. ; Zhao Q. Green Chem. 2013, 15, 2793.
16	Abbott A. P. ; Capper G. ; Davias D. L. ; Rasheed R. K. ; Tambyrajah V. Chem. Commun. 2003, 70, 70.
17	Maugeri Z. ; María P. D. D. RSC Adv. 2012, 2, 421.
18	Ruß, C.; König, B. Green Chem. 2012, 14, 2969. doi: 10.1039/c2gc36005e
19	Bahadori L. ; Manan N. S. ; Chakrabarti M. H. ; Hashim M. A. ; Mjalli F. S. ; AlNashef I. M. ; Hussain M. A. ; Low C. T. J.Phys. Chem. Chem. Phys. 2013, 15, 1707.
20	Liu Q. S. ; Yang M. ; Yan P. F. ; Liu X. M. ; Tan Z. C. ; Welz-Biermann U. J.Chem. Eng. Data 2010, 55, 4928.
21	Liu Q. S. ; Li P. P. ; Welz-Biermann U. ; Chen J. ; Liu X. X. J.Chem. Thermodyn. 2013, 66, 88.
22	Chen Y. ; Zhuo K. ; Chen J. ; Bai G. J.Chem. Thermodyn. 2015, 86, 13.
23	Chen Y. ; Zhang H. ; Li A. ; Zhuo K. Fluid Phase Equilibr. 2015, 388, 78.
24	Tong, J.; Hong, M.; Chen, Y.; Wang, H.; Guan, W.; Yang, J. Z. J. Chem. Thermodyn. 2012, 54, 352. doi: 10.1016/j.jct.2012.05.012
25	Lide, D. R. Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001-2002.
26	Jacquemin J. ; Husson P. ; Padua A. A. H. ; Majer V. Green Chem. 2006, 8, 172.
27	Glasser L. Thermochim. Acta 2004, 421, 87.
28	Vila J. ; Ginés P. ; Pico J. M. ; Franjo C. ; Jiménez E. ; Varela L. M. ; Cabeza O. Fluid Phase Equilibr. 2006, 242, 141.
29	Schreiner C. ; Zugmann S. ; Hartl R. ; Gores H. J. J.Chem. Eng. Data 2010, 55, 1784.
30	Belieres J. P. ; Angell C. A. J.Phys. Chem. B 2007, 111, 4926.

[1]	Xingang Fei, Haiyan Tan, Bei Cheng, Bicheng Zhu, Liuyang Zhang. 2D/2D Black Phosphorus/g-C₃N₄ S-Scheme Heterojunction Photocatalysts for CO₂ Reduction Investigated using DFT Calculations [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2010027-0.
[2]	Dunfeng Gao, Pengfei Wei, Hefei Li, Long Lin, Guoxiong Wang, Xinhe Bao. Designing Electrolyzers for Electrocatalytic CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009021-0.
[3]	Yunfei Wang, Jianhua Liu, Mei Yu, Jinyan Zhong, Qisen Zhou, Junming Qiu, Xiaoliang Zhang. SnO₂ Surface Halogenation to Improve Photovoltaic Performance of Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(3): 2006030-0.
[4]	Dongdong Liu, Chao Chen, Xunhui Xiong. Research Progress on Artificial Protective Films for Lithium Metal Anodes [J]. Acta Phys. -Chim. Sin., 2021, 37(2): 2008078-0.
[5]	Wenyi Liu,Linpo Li,Qiuyue Gui,Bohua Deng,Yuanyuan Li,Jinping Liu. Novel Hybrid Supercapacitors Based on Nanoarray Electrodes [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904049-0.
[6]	Pan Zhao,Bingjun Yang,Jiangtao Chen,Junwei Lang,Tianyun Zhang,Xingbin Yan. A Safe, High-Performance, and Long-Cycle Life Zinc-Ion Hybrid Capacitor Based on Three-Dimensional Porous Activated Carbon [J]. Acta Physico-Chimica Sinica, 2020, 36(2): 1904050-0.
[7]	Xuezhu Xiao, Xiaofang Cao, Dongbo Zhao, Chunying Rong, Shubin Liu. Quantification of Molecular Basicity for Amines: a Combined Conceptual Density Functional Theory and Information-Theoretic Approach Study [J]. Acta Physico-Chimica Sinica, 2020, 36(11): 1906034-0.
[8]	Zhichao Huang,Yazhong Dai,Xiaojie Wen,Dan Liu,Yuxuan Lin,Zhen Xu,Jian Pei,Kai Wu. Conformational Switching of Verdazyl Radicals on Au(111) [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907043-0.
[9]	Qiang CHEN,Li-Xue JIANG,Hai-Fang LI,Jiao-Jiao CHEN,Yan-Xia ZHAO,Sheng-Gui HE. Thermal Activation of Methane by Diatomic Vanadium Boride Cations [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 1014-1020.
[10]	Dan WANG,Xunlei DING,Henglu LIAO,Jiayu DAI. Methane Activation on (Au/Ag)₁-Doped Vanadium Oxide Clusters [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 1005-1013.
[11]	Mengru HAN,Yanan ZHOU,Xuan ZHOU,Wei CHU. Tunable Reactivity of MNi₁₂ (M = Fe, Co, Cu, Zn) Nanoparticles Supported on Graphitic Carbon Nitride in Methanation [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 850-857.
[12]	Yue ZHAO,Jiatong CUI,Jichuang HU,Jiabi MA. Reactivities of VO_1–4⁺ Toward n-C_mH_2m+2 (m = 3, 5, 7) as Functions of Oxygen Content and Carbon Chain Length [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 531-538.
[13]	Yanyan GONG,Haichun LIU,Duo ZHANG,Jing TONG. Thermodynamic Properties of the Ether-Based Functionalized Ionic Liquids [MOEMIm]Cl and [EOEMIm]Cl [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1224-1231.
[14]	Yucui HOU,Congfei YAO,Weize WU. Deep Eutectic Solvents: Green Solvents for Separation Applications [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 873-885.
[15]	Wenjun CHEN,Zhimin XUE,Jinfang WANG,Jingyun JIANG,Xinhui ZHAO,Tiancheng MU. Investigation on the Thermal Stability of Deep Eutectic Solvents [J]. Acta Physico-Chimica Sinica, 2018, 34(8): 904-911.

Properties of Four Deep Eutectic Solvents: Density, Electrical Conductivity, Dynamic Viscosity and Refractive Index

RichHTML

PDF

Like

Knowledge

Abstract

Supporting Info

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0