不同模板剂合成具有介微结构的ZSM-5分子筛及其甲醇制丙烯性能

doi:10.3866/PKU.WHXB201509281

Abstract

Abstract:

ZSM-5 zeolites with different pore structures were synthesized using different templates (tetrapropyl ammonium hydroxide (TPAOH), cetyltrimethylammonium bromide (CTAB) and C_18-6-6Br₂). The obtained nanosized (NZ), mesoporous (MZ), and nanosheets (NSZ) ZSM-5 samples were compared with conventional microporous ZSM-5 zeolite (CZ). The physicochemical properties of these samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), N₂ adsorption-desorption, and temperature-programmed desorption of ammonia (NH₃-TPD). The results showed that the mesopore volumes and surface areas of the four samples increased in the order NSZ > MZ > NZ > CZ, and the ratio of strong/weak acidity increased in the order CZ > MZ > NZ > NSZ. In the methanol to propylene (MTP) reaction, the catalyst porosity played an important role on the product selectivity and catalytic stability. The selectivities for propylene and total olefins improved with increasing mesoporosity; NSZ, with the largest mesopore volume, gave the highest propylene selectivity, i.e., 47.5%, and 78.4% total olefins. Meanwhile, the introduction of mesopores into the ZSM-5 zeolite extended the catalytic lifetime. The NZ sample displayed reliable MTP catalytic activity for 200 h, which was predominately attributed to its optimal combination of acidity and porosity.

Key words: ZSM-5 zeolite, Nanometer, Nanosheet, Mesopore, Methanol to propylene

MSC2000:

O643

Lan-Lan. ZHANG,Yu. SONG,Guo-Dong. LI,Shao-Long. ZHANG,Yun-Shan. SHANG,Yan-Jun. GONG. ZSM-5 Zeolite with Micro-Mesoporous Structures Synthesized Using Different Templates for Methanol to Propylene Reaction[J].Acta Phys. -Chim. Sin., 2015, 31(11): 2139-2150.

References

1	Chang C.D. Catal. Rev 1983, 25 (1), 1.
2	Keil F. J. Microporous Mesoporous Mat 1999, 29 (1-2), 49.
3	Chen J. Q. ; Bozzano A. ; Glover B. ; Fuglerud T. ; Kvisle S. Catal. Today 2005, 106 (1-4), 103.
4	Chang C. D. ; Chu C. T. W. ; Socha R. F. J. Catal 1984, 86 (2), 289.
5	Stöcker M. M. Microporous Mesoporous Mat 1999, 29 (1-2), 3.
6	Haw J. F. ; Song W. ; Marcus D. M. ; Nicholas J. B. Accounts Chem. Res 2003, 36 (5), 317.
7	Olson D. H. ; Kokotailo G. T. ; Lawton S. L. ; Meier W. M. J. Phys. Chem 1981, 85 (15), 2238.
8	Dahl I. ; Kolboe S. Catal. Lett 1993, 20 (3-4), 329.
9	Bjø rgen M. ; Svelle S. ; Joensen F. ; Nerlov J. ; Kolboe S. ; Bonino F. ; Palumbo L. ; Bordiga S. ; Olsbye U. J. Catal 2007, 249 (2), 195.
10	Corma A. Chem. Rev 1997, 97 (6), 2373.
11	Yao M. ; Hu S. ; Wang J. ; Dou T. ; Wu Y. P. Acta Phys. -Chim. Sin 2012, 28 (9), 2122.
11	姚敏; 胡思; 王俭; 窦涛; 伍永平. 物理化学学报, 2012, 28 (9), 2122.
12	Rownaghi A. A. ; Rezaei F. ; Hedlund J. Catal. Commun 2011, 14 (1), 37.
13	Khare R. ; Millar D. ; Bhan A. J. Catal 2015, 321, 23.
14	Wen P. Y. ; Mei C. S. ; Liu H. X. ; Yang W. M. ; Chen Q. L. Chem. Rea. Eng. Technol 2007, 23, 481.
14	温鹏宇; 梅长松; 刘红星; 杨为民; 陈庆龄. 化学反应工程与工艺, 2007, 23, 481.
15	Firoozi M. ; Baghalha M. ; Asadi M. Catal. Commun 2009, 10 (12), 1582.
16	Bjørgen M. ; Joensen F. ; Spangsberg Holm M. ; Olsbye U. ; Lillerud K. P. ; Svelle S. Appl. Catal. A 2008, 345 (1), 43.
17	Rownaghi A. A. ; Hedlund J. Ind. Eng. Chem. Res 2011, 50 (21), 11872.
18	Mei C. ; Wen P. ; Liu Z. ; Liu H. ; Wang Y. ; Yang W. ; Xie Z. ; Hua W. ; Gao Z. J. Catal 2008, 258 (1), 243.
19	Serrano D. P. ; Escola J. M. ; Pizarro P. Chem. Soc. Rev 2013, 42 (9), 4004.
20	Perego C. ; Millini R. Chem. Soc. Rev 2013, 42 (9), 3956.
21	Almutairi S. M. T. ; Mezari B. ; Pidko E. A. ; Magusin P. C. M. M. ; Hensen E. J. M. J. Catal 2013, 307, 194.
22	Sazama P. ; Wichterlova B. ; Dedecek J. ; Tvaruzkova Z. ; Musilova Z. ; Palumbo L. ; Sklenak S. ; Gonsiorova O. Microporous Mesoporous Mat 2011, 143 (1), 87.
23	Zhao L. ; Gao J. ; Xu C. ; Shen B. Fuel Process. Technol 2011, 92 (3), 414.
24	Zhang Q. ; Hu S. ; Zhang L. ; Wu Z. ; Gong Y. ; Dou T. Green Chem 2014, 16 (1), 77.
25	Sun C. ; Du J. ; Liu J. ; Yang Y. ; Ren N. ; Shen W. ; Xu H. ; Tang Y. Chem. Commun 2010, 46 (15), 2671.
26	Ahmadpour J. ; Taghizadeh M. J. Nat. Gas. Sci. Eng 2015, 23, 184.
27	Wang Q. ; Xu S. ; Chen J. ; Wei Y. ; Li J. ; Fan D. ; Yu Z. ; Qi Y. ; He Y. ; Xu S. ; Yuan C. ; Zhou Y. ; Wang J. ; Zhang M. ; Su B. ; Liu Z. RSC Adv 2014, 4 (41), 21479.
28	Choi M. ; Na K. ; Kim J. ; Sakamoto Y. ; Terasaki O. ; Ryoo R. Nature 2009, 461 (7261), 246.
29	Hu S. ; Shan J. ; Zhang Q. ; Wang Y. ; Liu Y. ; Gong Y. ; Wu Z. ; Dou T. Appl. Catal. A 2012, 445-446, 215.
30	Zhang S. L. ; Zhang L. L. ; Wang W. G. ; Min Y. Y. ; Ma T. ; Song Y. ; Gong Y. J. ; Dou T. Acta Phys. -Chim. Sin 2014, 30 (3), 535.
30	张少龙; 张兰兰; 王务刚; 闵媛媛; 马通; 宋宇; 巩雁军; 窦涛. 物理化学学报, 2014, 30 (3), 535.
31	Wang W. G. ; Zhang S. L. ; Zhang L. L. ; Wang Y. ; Liu X. L. ; Gong Y. J. ; Dou T. Acta Phys. -Chim. Sin 2013, 29 (9), 2035.
31	王务刚; 张少龙; 张兰兰; 王艳; 刘晓玲; 巩雁军; 窦涛. 物理化学学报, 2013, 29 (9), 2035.
32	Na K. ; Choi M. ; Park W. ; Sakamoto Y. ; Terasaki O. ; Ryoo R. J. Am. Chem. Soc 2010, 132 (12), 4169.
33	Treacy, M. M. J.; Higgins, J. B. MFI—Tetrapropylammonium ZSM-5. In Collection of Simulated XRD Powder Patterns for Zeolites (fifth); Treacy, M. M. J., Higgins, J. B., Eds.; Elsevier Science B.V.: Amsterdam, 2007; p 276.
34	Egeblad K. ; Christensen C. H. ; Kustova M. ; Christensen C. H. Chem. Mater 2008, 20 (3), 946.
35	Sing K. S. ; Williams R. T. Adsorpt. Sci. Technol 2004, 22 (10), 773.
36	Groen J. C. ; Peffer L. A. A. ; Pérez-Ramírez. J. Microporous Mesoporous Mat 2003, 60 (1-3), 1.
37	Olsbye U. ; Svelle S. ; Bjørgen M. ; Beato P. ; Janssens T. V. W. ; Joensen F. ; Bordiga S. ; Lillerud K. P. Angew. Chem. Int. Edit 2012, 51 (24), 5810.
38	Bjørgen M. ; Joensen F. ; Lillerud K. P. ; Olsbye U. ; Svelle S. Catal. Today 2009, 142 (1-2), 90.
39	Svelle S. ; Joensen F. ; Nerlov J. ; Olsbye U. ; Lillerud K. P. ; Kolboe S. ; Bjørgen M. J. Am. Chem. Soc 2006, 128 (46), 14770.
40	Guo Q. S. ; Mao D. S. ; Lao Y. P. ; Lu G. Z. Chin. J. Catal 2009, 30 (12), 1248.
40	郭强胜; 毛东森; 劳嫣萍; 卢冠忠. 催化学报, 2009, 30 (12), 1248.
41	Zhang S. ; Gong Y. ; Zhang L. ; Liu Y. ; Dou T. ; Xu J. ; Deng F. Fuel Process. Technol 2015, 129, 130.
42	Yang Y. ; Sun C. ; Du J. ; Yue Y. ; Hua W. ; Zhang C. ; Shen W. ; Xu H. Catal. Commun 2012, 24, 44.
43	Rostamizadeh M. ; Taeb A. J. Ind. Eng. Chem 2015, 27, 297.
44	Yaripour F. ; Shariatinia Z. ; Sahebdelfar S. ; Irandoukht A. J. Nat. Gas. Sci. Eng 2015, 22, 260.
45	Wei R. ; Li C. ; Yang C. ; Shan H. J. Nat. Gas Chem 2011, 20 (3), 261.
46	Westgård Erichsen M. ; Svelle S. ; Olsbye U. Catal. Today 2013, 215 (216)
47	Wen P. Y. ; Mei C. S. ; Liu H. X. ; Yang W. M. ; Chen Q. L. Acta Petrolei. Sinica (Petroleum Processing Section) 2008, 24 (4), 446.
47	温鹏宇; 梅长松; 刘红星; 杨为民; 陈庆龄. 石油学报(石油加工), 2008, 24 (4), 446.
48	Mores D. ; Kornatowski J. ; Olsbye U. ; Weckhuysen B. M. Chem. Eur. J 2011, 17 (10), 2874.
49	Lee K. Y. ; Kang M. Y. ; Ihm S. K. J. Phys. Chem. Solids 2012, 73 (12), 1542.
50	Schmidt F. ; Hoffmann C. ; Giordanino F. ; Bordiga S. ; Simon P. ; Carrillo-Cabrera W. ; Kaskel S. J. Catal 2013, 307, 238.
51	Kim J. ; Choi M. ; Ryoo R. J. Catal 2010, 269 (1), 219.
52	Bjørgen M. ; Akyalcin S. ; Olsbye U. ; Benard S. ; Kolboe S. ; Svelle S. J. Catal 2010, 275 (1), 170.

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ZSM-5 Zeolite with Micro-Mesoporous Structures Synthesized Using Different Templates for Methanol to Propylene Reaction

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