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Acta Phys. -Chim. Sin.  2016, Vol. 32 Issue (2): 399-404    DOI: 10.3866/PKU.WHXB201511272
REVIEW     
The Solid-State Photo-CIDNP Effect
Xiao-Jie WANG1,*(),Smitha Surendran THAMARATH2,3,A. ALIA2,3,4,E. BODE Bela5,Jörg MATYSIK2,3,*()
1 Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, P. R. China
2 Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Gemany
3 Leiden Institute of Chemistry, Einsteinweg 55, 2300 RA Leiden, The Netherlands
4 Institute of Medical Physics and Biophysics, University of Leipzig, D-04107 Leipzig, Germany
5 EaStCHEM School of Chemistry and Biomedical Sciences Research Complex, University of St Andrews, St Andrews, KY16 9ST, Scotland
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Abstract  

Photochemically induced dynamic nuclear polarization (photo-CIDNP) is an effect that produces non-Boltzmann nuclear spin polarization, which can be observed as a modification of signal intensity in nuclear magnetic resonance (NMR) spectroscopy. The effect is well known in liquid-state NMR, where it is explained most generally by the classical radical pair mechanism (RPM). In the solid-state, additional mechanisms are operative in the spin-dynamics of radical pairs, such as three-spin mixing (TSM), differential decay (DD) and differential relaxation (DR). The observed solid-state photo-CIDNP effect is strongly magnetic field dependent, and this field-dependence is well distinguished for the various nuclei. Here, we provide an account of the phenomenology, theory and properties of the magnetic field dependence of the solid-state photo-CIDNP effect.



Key wordsPhoto-CIDNP      Magic angle spinning      Nuclear magnetic resonance      Radical pair      Spin chemistry     
Received: 21 September 2015      Published: 27 November 2015
O646.8  
Fund:  the Netherlands Organization for Scientific Research (NWO)(713.012.001)
Corresponding Authors: Xiao-Jie WANG,Jörg MATYSIK     E-mail: yj605@126.com;joerg.matysik@uni-leipzig.de
Cite this article:

Xiao-Jie WANG,Smitha Surendran THAMARATH,A. ALIA,E. BODE Bela,Jörg MATYSIK. The Solid-State Photo-CIDNP Effect. Acta Phys. -Chim. Sin., 2016, 32(2): 399-404.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB201511272     OR     http://www.whxb.pku.edu.cn/Y2016/V32/I2/399

 
 
 
 
 
 
 
 
 
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