氧化石墨烯/聚电解质层层自组装制备单价离子选择性膜

doi:10.3866/PKU.WHXB201512141

Abstract

Abstract:

Graphene oxide (GO) composite membranes were fabricated via layer-by-layer (LBL) assembling poly(ethylenimine) (PEI) and a mixture of GO and poly(acrylic acid) (PAA) on a poly(acrylonitrile) (PAN) support membrane. The composite membranes and their application performance were characterized and evaluated. The X-ray powder diffraction (XRD) spectrum shows that GO was successfully synthesized by the modified Hummers method, and it was homogenously dispersed in the composite membranes. Scanning electron microscopy (SEM) shows the successful assembly of multiple polyelectrolyte PEI and a mixture of GO and PAA bilayers on the PAN support membrane. The ultraviolet-visible (UV-Vis) spectrum indicates that the uniformity and continuity of the composite membrane were enhanced with the increasing number of assembled layers. The hydrophilic and selectivity tests reveals that the addition of GO decreased the water contact angle and enhanced the selectivity for monovalent cations of the multilayer polyelectrolyte composite membranes. All these advantages combine to fabricate a high-flux, high selectivity, and anti-fouling composite membrane for separation applications and water softening.

Key words: Multilayer structure, Layer-by-layer assembly, Deposition, Graphene oxide, Selectivity

MSC2000:

O647

Sheng-Jun ZHAO,Wei ZHANG,Hui-Ning DENG,Wei LIU. Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation[J].Acta Phys. -Chim. Sin., 2016, 32(3): 723-727.

References

1	Xu Y. X. ; Hong W. J. ; Bai H. ; Li C. ; Shi G. Q. Carbon 2009, 47, 3538.
2	Lee D. C. ; Yang H. N. ; Park S. H. ; Kim W. J. J. Membr. Sci. 2014, 452, 20.
3	Cao C. H. ; Daly M. ; Singh C. V. ; Sun Y. ; Filleter T. Carbon 2015, 81, 497.
4	Liang L. ; Lu Y. ; Yao W. S. ; Zhang X. T. Acta Phys. -Chim. Sin. 2015, 31, 1180.
4	梁祎; 卢赟; 姚维尚; 张学同. 物理化学学报, 2015, 31, 1180.
5	Ji T. H. ; Sun M. ; Zou L. F. ; Ma N. Mater. Lett. 2014, 120, 30.
6	Dreyer D. R. ; Park S. J. ; Bielawski C.W. ; Ruoff R. S. Chem. Soc. Rev. 2010, 39, 228.
7	Nair R. R. ; Wu H. A. ; Jayaram P. N. ; Grigorieva I. V. ; Geim A. K. Science 2012, 335, 442.
8	Mi B. X. Science 2014, 343, 740.
9	Valentini L. Mater. Lett. 2015, 157, 266.
10	Li W. Y. ; He Y. Q. ; Li Y. M. Acta Phys. -Chim. Sin. 2015, 31, 458.
10	李文有; 贺蕴秋; 李一鸣. 物理化学学报, 2015, 31, 458.
11	Dikin D. A. ; Stankovich S. ; Zimney E. J. ; Piner R. D. ; Dommett G. H. B. ; Evmenenko G. ; Nguyen S. T. ; Ruoff R.S. Nature 2007, 448, 458.
12	Rajasekar R. ; Kim N. H. ; Jung D. ; Kuila T. ; Lim J. K. ; Park M. J. ; Lee J. H. Compos. Sci. Technol. 2013, 89, 171.
13	Hu M. ; Mi B. X. J. Membr. Sci. 2014, 469, 80.
14	Hummers W. S. ; Offeman R. E. J. Am. Chem. Soc. 1958, 80, 1339.
15	Wang J. D. ; Peng T. J. ; Xian H. Y. ; Sun H. J. Acta Phys. -Chim. Sin. 2015, 31, 91.
15	汪建德; 彭同江; 鲜海洋; 孙红娟.. 物理化学学报, 2015, 31, 91.
16	Goh K. L. ; Setiawan L. ; Wei L. ; Si R. M. ; Fane A. G. ; Wang R. ; Chen Y. J. Membr. Sci. 2015, 474, 245.
17	Zhou T. N. ; Chen F. ; Tang C. Y. ; Bai H.W. ; Zhang Q. ; Deng H. ; Fu Q. Compos. Sci. Technol. 2011, 71, 1267.
18	Suresh D. ; Udayabhanu; Kumar M. A. P. ; Nagabhushana H. ; Sharma S. C. Mater. Lett. 2015, 151, 93.
19	Zhang G. J. ; Yan H. H. ; Ji S. L. ; Liu Z. Z. J. Membr. Sci. 2007, 292, 2.
20	Wang N. X. ; Ji S. L. ; Zhang G. J. ; Li J. ; Wang L. Chem. Eng. Technol. 2012, 213, 321.
21	Wang X. ; Guo X. Y. ; Shao H. Q. ; Zhou Q. X. ; Hu W. L. ; Song X. J. Prog. Chem. 2015, 27, 1475.
21	王茜; 郭晓燕; 邵怀启; 周启星; 胡万里; 宋晓静. 化学进展, 2015, 27, 1475.
22	Schniepp H. C. ; Li J. L. ; McAllister M. J. ; Sai H. ; Herrera-Alonso M. ; Adamson D. H. ; Prud'homme R. K. ; Car R. ; Saville D. A. ; Aksay I. A. J. Phys. Chem. 2006, 110, 8537.
23	Zhang J. G. ; Xu Z.W. ; Shan M. J. ; Zhou B. M. ; Li Y. L. ; Li B. D. ; Niu J. R. ; Qian X. M. J. Membr. Sci. 2013, 448, 91.
24	Ben Ameur S. ; Barhoumi A. ; Mimouni R. ; Amlouk M. ; Guermazi H. Superlattice. Microst. 2015, 84, 110.
25	Marmur A. Langmuir 2004, 20, 3519.
26	Malaisamy R. ; Talla-Nwafo A. ; Jones K. L. Sep. Purif. Technol. 2011, 77, 370.

[1]	Mengdi ZHAO,Wenjun LU. Alkanes Functionalization via C―H Activation [J]. Acta Physico-Chimica Sinica, 2019, 35(9): 977-988.
[2]	Fang LIU,Lufeng ZHANG,Qian DONG,Zhuo CHEN. Synthesis and Characterization of Small Size Gold-Graphitic Nanocapsules [J]. Acta Physico-Chimica Sinica, 2019, 35(6): 651-656.
[3]	Qin WANG,Minmin XUE,Zhuhua ZHANG. Chemical Synthesis of Borophene: Progress and Prospective [J]. Acta Physico-Chimica Sinica, 2019, 35(6): 565-571.
[4]	Dandan CAO, Rong LÜ, Anchi YU. Preparation and Characterization of Carbon Nitride Film with High Optical Quality [J]. Acta Physico-Chimica Sinica, 2019, 35(4): 442-450.
[5]	Jingjing HUANG, Jinmeng CAI, Kui MA, Tong DING, Ye TIAN, Jing ZHANG, Xingang LI. Ga₂O₃-Modified Cu/SiO₂ Catalysts with Low CO Selectivity for Catalytic Steam Reforming [J]. Acta Physico-Chimica Sinica, 2019, 35(4): 431-441.
[6]	Xiaobing YANG,Lei ZHAO,Xulei SUI,Linghui MENG,Zhenbo WANG. Ultra-High Proton/Vanadium Selectivity of Polybenzimidazole Membrane by Incorporating Phosphotungstic Acid Functionalized Nanofibers for Vanadium Redox Flow Battery [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1372-1381.
[7]	Haipeng WANG,Zichao GUAN,Xia WANG,Piao JIN,Hui XU,Lifang CHEN,Guangling SONG,Ronggui DU. Fabrication of a ZnSe/MoO₃/TiO₂ Composite Film Exhibiting Photocathodic Protection Effect [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1232-1240.
[8]	Peng PENG,Hongtao LIU,Bin WU,Qingxin TANG,Yunqi LIU. Nitrogen Doped Graphene with a p-Type Field-Effect and Its Fine Modulation [J]. Acta Physico-Chimica Sinica, 2019, 35(11): 1282-1290.
[9]	Kexin WANG,Liurong SHI,Mingzhan WANG,Hao YANG,Zhongfan LIU,Hailin PENG. Biomass Hydroxyapatite-templated Synthesis of 3D Graphene [J]. Acta Physico-Chimica Sinica, 2019, 35(10): 1112-1118.
[10]	Shuai CHEN,Junfeng GAO,Bharathi M. SRINIVASAN,Yong-Wei ZHANG. A Kinetic Monte Carlo Study for Mono- and Bi-layer Growth of MoS₂ during Chemical Vapor Deposition [J]. Acta Physico-Chimica Sinica, 2019, 35(10): 1119-1127.
[11]	Hengwei WANG,Junling LU. Atomic Layer Deposition: A Gas Phase Route to Bottom-up Precise Synthesis of Heterogeneous Catalyst [J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1334-1357.
[12]	Chan YAO,Guo-Yan LI,Yan-Hong XU. Carboxyl-Enriched Conjugated Microporous Polymers: Impact of Building Blocks on Porosity and Gas Adsorption [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1898-1904.
[13]	Yi-Ming LI,Xiao CHEN,Xiao-Jun LIU,Wen-You LI,Yun-Qiu HE. Electrochemical Reduction of Graphene Oxide on ZnO Substrate and Its Photoelectric Properties [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 554-562.
[14]	Xiao-Qin ZHOU,Hui ZHANG,Ze ZHANG,Xin CHEN,Chuan-Hong JIN. Characterization of Heterostructural Palladium Deposition on Spherical Gold Nanoparticles by In situ Liquid Cell Transmission Electron Microscopy [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 458-463.
[15]	Pengfei CAO,Yang HU,Youwei ZHANG,Jing PENG,Maolin ZHAI. Radiation Induced Synthesis of Amorphous Molybdenum Sulfide/Reduced Graphene Oxide Nanocomposites for Efficient Hydrogen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2542-2549.

Layer-by-Layer Assembly of Graphene Oxide and Polyelectrolyte Composite Membranes for Monovalent Cation Separation

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10