卤代苯溶剂对镓咔咯配合物光物理性质的影响:外重原子效应

doi:10.3866/PKU.WHXB201601043

Acta Phys. -Chim. Sin. ›› 2016, Vol. 32 ›› Issue (3): 771-779.doi: 10.3866/PKU.WHXB201601043

• ARTICLE • Previous Articles Next Articles

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

Xuan ZHAN¹,Fang ZHAO²,Lei ZHANG^2,*(),Biao-Biao LÜ³,Su-Hong PENG¹,Xiao YING³,Hui WANG^2,*(),Hai-Yang LIU^1,^2,*()

¹ Department of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China
² State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, P. R. China
³ Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China

Received:2015-11-03 Published:2016-03-04
Contact: Lei ZHANG,Hui WANG,Hai-Yang LIU E-mail:zhlei28@mail.sysu.edu.cn;stswh@mail.sysu.edu.cn;chhyliu@scut.edu.cn
Supported by:
the National Natural Science Foundation of China(21171057, 21371059);National Key Basic Research Program of China((973)(2013CB922403));Open Fund of State Key Laboratory of Opto-Electronic Material and Technologies of SunYat-Sen University, China(OEMT-2015-KF-05)

Abstract

Abstract:

The photophysical properties of pentafluorophenyl-substituted gallium corroles in halogenated benzenes were investigated using ultraviolet-visible (UV-Vis), steady-state, time-resolved fluorescence, and femtosecond transient absorption spectroscopies. The results showed that the absorption maximum wavelength of the gallium corroles was mainly related to the dispersion force of the halogenated benzene solvents. The external heavy atom effect of halogenated benzenes may markedly lower the fluorescence quantum yield of gallium corrole complexes. Photoinduced electron transfer between the gallium corroles and halogenated benzene solvents was detected by femtosecond transient absorption spectroscopy. The experimental evidence showed that the heavy atom effect of the solvent might lower the charge recombination rate of charge-separated gallium corrole-solvent complexes.

Key words: Corrole, Gallium, Halogenated benzene solvent, External heavy atom effect, Photophysical property

MSC2000:

O641.06

Xuan ZHAN,Fang ZHAO,Lei ZHANG,Biao-Biao LÜ,Su-Hong PENG,Xiao YING,Hui WANG,Hai-Yang LIU. Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect[J].Acta Phys. -Chim. Sin., 2016, 32(3): 771-779.

References

1	Zdilla M. J. ; Abu O. M. Inorg. Chem. 2008, 47 (22), 10718.
2	Flamigni L. ; GryKo D. T. Chem. Soc. Rev. 2009, 38, 1635.
3	Gross Z. ; Galili N. ; Saltsman I. Angew. Chem. Int. Edit. 1999, 38, 1427.
4	Paolesse R. ; Jaquinod L. ; Nurco D. ; Mini S. ; Sagone F. ; Boschi T. ; Smith K. M. Chem. Commun. 1999, 1307.
5	Bose S. ; Pariyar A. ; Biswas A. N. ; Bandyopadhyay P. Catal. Commum. 2011, 12, 1193.
6	Liu H. Y. ; Mahmood M. H. R. ; Qiu S. X. ; Chang C. K. Coord. Chem. Rev. 2013, 25, 1306.
7	Chang C. K. ; Kong P.W. ; Liu H. Y. ; Yeung L. L. ; Koon H.K. ; Mak N. K. Proc. SPIE-Int. Soc. Opt. Eng. 2006, 6139, 613911.
8	Zhang Y. ; Chen H. ; Wen J. Y. ; Wang X. L. ; Wang H. ; Ji L.N. ; Liu H. Y. Chem. J. Chin. Univ. 2013, 34, 2462.
8	张阳; 陈欢; 闻金燕; 王湘利; 王惠; 计亮年; 刘海洋.. 高等化学学报, 2013, 34, 2462.
9	Robert C. ; Ohkawara T. Chem. Eur. J. 2014, 20 (16), 4789.
10	Zou H. B. ; Yang H. ; Liu Z. Y. ; Liu H. Y. Organomeallic 2015, 34 (12), 2791.
11	Barata J. F. B. ; Zamarron A. ; Neves M. ; Graca P. M. S. Eur. J. Med. Chem. 2015, 92, 135.
12	Chun Z. ; Jin X. J. Power Sources 2015, 283, 343.
13	Basumatary B. ; Sekhar A. Inorg. Chem. 2015, 54 (9), 4257.
14	Santtos C. I. M. ; Oliveria E. Inorg. Chim. Acta 2014, 417, 148.
15	Agadjannian H. ; Ma J. ; Rentsendorj A. ; Valluripalli V. ; Hwang J. Y. ; Mahammed A. ; Farkas D. L. ; Gray H. B. ; Gross Z. ; Medina-Kauwe L. K. Proc. Natl. Acad. Sci. U. S. A 2009, 106 (15), 6105.
16	Wang J. Y. ; Lubow I. ; Chu D. ; Hwang J. Y. ; Lubow J. ; Chu D. ; Ma J. ; Agadjanian H. ; Sims J. ; Gray H. B. ; Gross Z. ; Farkas D. L. ; Lali K. ; Medina-Kauwe L. K. Mol. Pharm. 2011, 8, 2233.
17	Lim P. ; Mahammed A. ; OKun Z. ; Saltsman I. ; Gross Z. ; Gray H. B. ; Termini J. Chem. Res. Toxicol. 2012, 25, 400.
18	Peng K. M. ; Shao W. L. ; Wang H. H. ; Ying X. ; Wang H. ; Ji L. N. ; Liu H. Y. Acta Phys. -Chim. Sin. 2011, 27 (1), 199.
18	彭开美; 邵文莉; 汪华华; 应晓; 王惠; 计亮年; 刘海洋. 物理化学学报, 2011, 27 (1), 199.
19	Zhang L. ; Liu Z. Y. ; Zhan X. ; Liu H. Y. Photochem. Photobiol. Sci. 2015, 14, 953.
20	Liu H. Y. ; Lai T. S. ; Yeung L. L. Org. Lett. 2003, 5, 617.
21	Jozefowicz M. ; Bajorek M. ; Heldt J. J. Lumin. 2014, 153, 152.
22	Strat G. ; Strat M. Spectros. Lett. 1994, 27, 177.
23	Liu X. ; Mahammed A. ; Tripathy U. ; Gross Z. ; Steer R. P. Chem. Phys. Lett. 2008, 459, 113.
24	Shao W. L. Photophysical Study on Ultrafast ElectronTransfer in Biomolecular Systems. Sun-Yat Sen University: Guangzhou 2012, 15- 30.
24	邵文莉. 新型光敏剂Corrole的激发态动力学及单线态氧产生过程研究[D].广州:中山大学, 2012, 15- 30.
25	Yang X. ; Pan Z. T. ; Ma Y. J. Analytical. Sci. 2003, 19 (6), 588.
26	Paul G. S. ; Martin G. J. Mol. Spectrosc. 1969, 3, 1.
27	You L. L. ; Shen H. ; Shi L. ; Zhang G. L. ; Liu H. Y. ; Wang H. ; Ji L. N. Scientia Sinica chimica 2010, 40, 224.
27	游丽莉; 沈涵; 史蕾; 张国良; 刘海洋; 王惠; 计亮年.. 中国科学, 2010, 40, 224.
28	Chen P. ; Ge F. Y. Chemistry Online 2014, 77, 243.
28	陈鹏; 葛凤燕.. 化学通报, 2014, 77, 243.
29	Guo C. ; Feng M. B. Chin. J. Lumin. 1987, 8 (2), 92.
29	郭础; 冯梅波. 发光学报, 1987, 8 (2), 92.
30	Shi L. ; Liu H. Y. ; Shen H. J. Porphyr. Phthalocya. 2009, 13, 1221.
31	Ghosh M. ; Mora A. K. ; Sukhendu N. P. ; Kumar P. H. ; Bangal P. R. ; Sinha S. J. Photochem. Photobiol. A 2015, 306, 55.
32	HayesR. T. ; Walsh C. J. ; Wasielewski ; M R. J. Phys. Chem. A 2004, 108, 2375.

[1]	Hua-Bin CHEN,Xiao-Hui ZHANG,Li-Zhen GONG,Jing HE,Xuan XU,Zhi-Guang XU,Hai-Yang LIU. Effect of β-Substituents on the Electronic Absorption Spectra of Manganese(Ⅴ)-oxo Corrole Complexes [J]. Acta Phys. -Chim. Sin., 2016, 32(8): 1983-1989.
[2]	ZHANG Xiao-Hui, XU Zhi-Guang, GONG Li-Zhen, XU Xuan, SHEN Gui-Xian, CHEN Hua-Bin, LIU Hai-Yang. Stability of trans-Dioxo Manganese(V) Corrole Complex [J]. Acta Phys. -Chim. Sin., 2015, 31(6): 1069-1076.
[3]	GONG Li-Zhen, XU Zhi-Guang, XU Xuan, HE Jing, WANG Qi, LIU Hai-Yang. Axial Coordination Behavior of Corrole Mn^Ⅲ and Mn^VO Complexes with N-Based Ligands [J]. Acta Phys. -Chim. Sin., 2014, 30(2): 265-272.
[4]	TANG Peng, XIAO Jian-Jian, ZHENG Chao, WANG Shi, CHEN Run-Feng. Graphene-Like Molybdenum Disulfide and Its Application in Optoelectronic Devices [J]. Acta Phys. -Chim. Sin., 2013, 29(04): 667-677.
[5]	LIU Shu-Juan, MA Ting-Chun, XU Wen-Juan, LIU Xiang-Mei, ZHAO Qiang, HUANG Yan-Qin, HUANG Wei. Optoelectronic Properties for Main Group Element-Bridged Ladder Compounds [J]. Acta Phys. -Chim. Sin., 2012, 28(11): 2597-2604.
[6]	HE Jing, XU Zhi-Guang, ZENG Yun-Xiu, XU Xuan, YU Lan, WANG Qi, LIU Hai-Yang. Effect of Substituents on Mn―O Bond in Oxo-Manganese(V) Corrole Complexes [J]. Acta Phys. -Chim. Sin., 2012, 28(07): 1658-1664.
[7]	SHI Lei, JIANG Huan-Feng, YIN Wei, WANG Hua-Hua, WANG Hui, ZHANG Lei, JI Liang-Nian, LIU Hai-Yang. Synthesis, Fluorescence and DNA Photocleavage Activity of Phenothiazine-Corrole Gallium(III) Complexes [J]. Acta Phys. -Chim. Sin., 2012, 28(02): 465-469.
[8]	PENG Kai-Mei, SHAO Wen-Li, WANG Hua-Hua, YING Xiao, WANG Hui, JI Liang-Nian, LIU Hai-Yang. Effects of Solvents on the Spectral Properties of Gallium Corrole [J]. Acta Phys. -Chim. Sin., 2011, 27(01): 199-206.
[9]	LIU Hai-Yang, LENG Ke, HU Jun, YING Xiao, XU Zhi-Guang, CHANG Chi-Kwong. Effect of Meso-Substituents on β ¹H-NMR of A₃ Type Corrole [J]. Acta Phys. -Chim. Sin., 2009, 25(04): 694-700.
[10]	LIU Hai-Yang; LI Li; YING Xiao; WANG Xiang-Li; XU Zhi-Guang; LIAO Shi-Jun; CHANG Chi-Kwong. DFT Calculations on Manganese(III)5,10,15-Tris(pentafluorophenyl)-Corrole [J]. Acta Phys. -Chim. Sin., 2008, 24(09): 1602-1608.
[11]	JI Yong-Jun; WU Hai-Shun; ZHANG Fu-Qiang; JIA Jian-Feng. Structure and Stability of (MN)_nH_m (M=Ga, In; n=1-4; m=1, 2) Clusters [J]. Acta Phys. -Chim. Sin., 2008, 24(02): 257-262.
[12]	JIN Wei-Hong; NI Jing; LAI Yee-Hing; PEI Jian. Photophysical Properties and Electropolymerization of Regioregular Head-to-Tail Oligothiophenes-Functionalized 9,9'-spirobifluorene Derivatives [J]. Acta Phys. -Chim. Sin., 2007, 23(04): 459-465.
[13]	Yao Guang-Qing;Feng Yan-E;Duan Jie-Fei;Lin Jian-Hua. Synthesis and Luminescence of Gallium Nitride LED Blue Light Conversion Materials [J]. Acta Phys. -Chim. Sin., 2003, 19(03): 226-229.

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 13

Metrics

Comments

Recommended 0