热剥离法制备石墨烯纳米片对Pb2+和Cd2+的吸附

doi:10.3866/PKU.WHXB201602182

Abstract

Abstract:

Graphene nanosheets (GNSs) were prepared using oxidation of graphite powder followed by rapid thermal exfoliation under a nitrogen atmosphere. The as-prepared samples were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), Raman spectroscopy, and Fourier transform infrared (FT-IR) spectroscopy. The specific surface area was determined using the nitrogen adsorption and desorption method. These analytic techniques revealed that the samples possessed a curled morphology consisting of a thin paper-like structure, which was made of a few graphite layers (approximately four layers) and a large specific surface area (628.5 m²·g^-1). The effects of pH, adsorption time, temperature and initial concentration of Pb²⁺ and Cd²⁺ on adsorption onto the GNSs were investigated. The maximum adsorption capacities of GNSs for Pb²⁺ and Cd²⁺ ions were approximately 460.20 and 72.39 mg·g^-1, respectively. These results indicate that the resulting high-quality GNSs can be used as an attractive adsorptive material for removing Pb²⁺ and Cd²⁺ from water.

Key words: Graphene, Thermal exfoliation, Characterization, Adsorption, Heavy metal ion

MSC2000:

O643

Bao-Qing LI,Wen-Hui YUAN,Li LI. Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation[J].Acta Phys. -Chim. Sin., 2016, 32(4): 997-1004.

References

1	Gaur V. K. ; Gupta S. K. ; Pandey S. D. ; Gopal K. ; Misra V. Environ. Monit. Assess 2005, 102, 419.
2	Wu G. ; Li L. Y. J. Contam. Hydrol 1998, 33, 313.
3	Kikuchi Y. ; Qian Q. ; Machida M. ; Tatsumoto H. Carbon 2006, 44 (195)
4	Gardea-Torresdey J. ; Hejazi M. ; Tiemann K. ; Parsons J. G. ; Duarte-Gardea M. ; Henning J. J. Hazard. Mater. B 2002, 91, 95.
5	Dabrowski A. Adv. Colloid Interface 2001, 93 (135)
6	Lagadic I. L. ; Mitchell M. K. ; Payne B. D. Environ. Sci. Technol 2001, 35, 984.
7	Machida M. ; Yamazaki R. ; Aikawa M. ; Tatsumoto H. Sep. Purif. Technol 2005, 46, 88.
8	Machida M. ; Mochimaru T. ; Tatsumoto H. Carbon 2006,, 44, 2681.
9	Chae H. K. ; Siberio-Pérez D. Y. ; Kim J. Nature 2004, 427, 523.
10	Yang Z. ; Xia Y. ; Mokaya R. J. Am. Chem. Soc 2007, 129, 1673.
11	Wu W. Q. ; Yang Y. ; Zhou H. H. ; Ye T. T. ; Huang Z. Y. ; Liu R. ; Kuang Y. F. Water Air Soil Pollut 2013, 224, 1372.
12	Shim J.W. ; Park S. J. ; Ryu S. K. Carbon 2001, 39, 1635.
13	Machida M. ; Aikawa M. ; Tatsumoto H. J. Hazard. Mater. B 2005, 120, 271.
14	Mohan D. ; Singh K. P. Water Res 2002, 36, 2304.
15	Leyva-Ramos R. ; Bernal-Jacome L. A. ; Acosta-Rodriguez I. Sep. Purif. Technol 2005, 45, 41.
16	Li Y. H. ; Ding J. ; Luan Z. ; Di Z. ; Zhu Y. ; Xu C. ; Wu D. ; Wei B. Carbon 2003, 41, 2787.
17	Allen M. J. ; Tung V. C. ; Kaner R. B. Chem. Rev 2010, 110, 132.
18	Sridhar V. ; Jeon J. H. ; Oh I. K. Carbon 2010, 48 (2953)
19	Novoselov K. S. ; Geim A. K. Morozov S. V. Science 2004, 306, 666.
20	Liang M. ; Zhi L. J. Mater. Chem 2009, 19, 5871.
21	Madadrang C. J. ; Kim H. Y. ; Gao G. H. ; Wang N. ; Zhu J. ; Feng H. ; Matthew Gorring M. ; Kasner M. L. ; Hou S. F. ACS Appl. Mater. Interfaces 2012, 4, 1186.
22	Yang S. ; Li L. Y. ; Pei Z. G. ; Li C. M. ; Shan X. Q. ; Wen B. ; Zhang S. Z. ; Zheng L. R. ; Zhang J. ; Xie Y. N. ; Huang R. X. Carbon 2014, 75, 227.
23	Tan P. ; Sun J. ; Hu Y. Y. ; Fang Z. ; Bi Q. ; Chen Y. C. ; Cheng J. H. J. Hazard. Mater 2015, 297, 251.
24	Schniepp H. C. ; Li J. L. ; McAllister M. J. ; Sai H. ; Herrera-Alonso M. ; Adamson D. H. ; Prud' homme R. K. ; Car R. ; Saville D. A. ; Aksay I. A. J. Phys. Chem. B 2006, 110, 8535.
25	Hummers W. S. ; Offeman R. E. J. Am. Chem. Soc 1958, 80, 1339.
26	Wu Z. S. ; Ren W. ; Gao L. ; Liu B. ; Jiang C. ; Cheng H. M. Carbon 2009, 47 (493)
27	Yuan W. H. ; Li B. Q. ; Li L. Acta Phys. -Chim. Sin 2011, 27, 2244.
27	袁文辉; 李保庆; 李莉. 物理化学学报, 2011, 27, 2244.
28	Yuan W. H. ; Li B. Q. ; Li L. Appl. Surf. Sci 2011, 257, 10183.
29	Qian J. S. ; Jin H. Y. ; Chen B. L. ; Lin M. ; Lu W. ; Tang W. M. ; Xiong W. ; Chan H. L.W. ; Lau S. P. ; Yuan J. K. Angew. Chem. Int. Edit 2015, 54, 6800.
30	Moreno-Castilla C. ; López-Ramón M. V. ; Carrasco-Marín F. Carbon 2000, ,38 (1995)
31	Scherrer P. Göttinger Nachrichten 1918, 2, 98.
32	Pan D. ; Wang S. ; Zhao B. ; Wu M. ; Zhang H. ; Wang Y. ; Jiao Z. Chem. Mater 2009, 21, 3136.
33	Szabó T. ; Berkesi O. ; Dékány I. Carbon 2005, 43, 3186.
34	Wang G. X. ; Yang J. ; Park J. ; Gou X. L. ; Wang B. ; Liu H. ; Yao J. J. Phys. Chem. C 2008, 112 (8192)
35	Guo P. ; Song H. ; Chen X. Electrochem. Commun 2009, 11, 1320.
36	Paek S. M. ; Yoo E. J. ; Honma I. Nano Lett 2009, 9, 72.
37	Meyer J. C. ; Geim A. K. ; Katsnelson M. I. ; Novoselov K. S. ; Booth T. J. ; Roth S. Nature 2007, 446, 60.
38	Jung I. ; Pelton M. ; Piner R. ; Dikin D. A. ; Stankovich S. ; Watcharotone S. Nano Lett 2007, 7, 3569.
39	Pimenta M. A. ; Dresselhaus G. ; Dresselhaus M. S. ; Cançado L. G. ; Jorio A. ; Saito R. Phys. Chem. Chem. Phys 2007, 9, 1276.
40	Liu M. X. ; Gan L. H. ; Xiong W. ; Zhao F. Q. ; Fan X. Z. ; Zhu D. Z. ; Xu Z. J. ; Hao Z. X. ; Chen L. W. Energy Fuel 2013, 27, 1168.
41	Liu M. X. ; Gan L. H. ; Xiong W. ; Xu Z. J. ; Zhu D. Z. ; Chen L.W. J. Mater. Chem. A 2014, 2 (2555)
42	Stankovich S. ; Dikin D. A. ; Piner R. D. ; Kohlhaas K. A. ; Kleinhammes A. ; Jia Y. ; Wu Y. ; Nguyen S. T. ; Ruoff R. S. Carbon 2007, 45, 1558.
43	Stafiej A. ; Pyrzynska K. Sep. Purif. Technol 2007, 58, 49.
44	Deng X. J. ; Lv L. L. ; Li H.W. ; Luo F. J. Hazard. Mater 2010, 183, 923.
45	Kabbashi N. A. ; Atieh M. A. ; Al-Mamun A. ; Mirghami M. E. ; Alam M. D. Z. ; Yahya N. J. Environ. Sci 2009, 21, 539.
46	Li Y. H. ; Ding J. ; Luan Z. ; Di Z. ; Zhu Y. ; Xu C. ; Wu D. ; Wei B. Carbon 2003, 41 (2787)
47	Wang H. J. ; Zhou A. L. ; Peng F. ; Yu H. ; Chen L. F. Mater. Sci. Eng. A 2007, 466, 201.
48	Li Y. H. ; Wang S. ; Luan Z. ; Ding J. ; Xu C. ; Wu D. Carbon 2003, 41, 1057.
49	Wang J. ; Chen B. L. Chem. Eng. J 2015, 281, 379.
50	Sanchez-Polo M. ; Rivera-Utrilla J. Environ. Sci. Technol 2002, 36, 3850.
51	Rivera-Utrilla J. ; Sanchez-Polo M. Water. Res 2003, 37, 3335.
52	Yushin G. ; Dash R. ; Jagiello J. ; Fischer J. E. ; Gogotsi Y. Adv. Funct. Mater 2006, 16, 2288.

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Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation

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Adsorption of Pb²⁺ and Cd²⁺ on Graphene Nanosheets Prepared Using Thermal Exfoliation