镁热还原法制备有序介孔Si/C锂离子电池负极材料及其电化学性能

doi:10.3866/PKU.WHXB201605124

Abstract

Abstract:

A highly ordered mesoporous Si/C composite was prepared by magnesiothermic reduction method, using SBA-15 as the precursor at 660 ℃ with subsequent carbon coating. This Si/C composite preserved the ordered honeycomb pore channels of SBA-15 and exhibited a lotus root-like structure with high packing density. A liquid ambient reaction model is proposed to explain the reaction between SBA-15 and magnesium powder at 660 ℃ as well as the mechanism by which the highly ordered mesoporous structure is generated. The phase composition and morphology of this material were analyzed by X-ray diffractometry (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption and Raman spectroscopy. The excellent electrochemical performance of the as-prepared material suggests potential applications as an anode material in second-generation Li-ion batteries.

Key words: Li-ion battery, Mesoporous silicon, Anode material, Nanocomposite, Magnesiothermic reduction method

MSC2000:

O646

Yan-Ping TANG,Sha YUAN,Yu-Zhong GUO,Rui-An HUANG,Jian-Hua WANG,Bin YANG,Yong-Nian DAI. Magnesiothermic Reduction Preparation and Electrochemical Properties of a Highly Ordered Mesoporous Si/C Anode Material for Lithium-Ion Batteries[J].Acta Phys. -Chim. Sin., 2016, 32(9): 2280-2286.

References

1	Ding P. ; Xu Y. L. ; Sun X. F. Acta Phys.-Chim. Sin 2013, 29, 293.
1	丁朋; 徐友龙; 孙孝飞. 物理化学学报, 2013, 29, 293d.
2	Choi N. S. ; Chen Z. ; Freunberger S. A. ; Ji X. ; Sun Y. K. ; Amine K. ; Yushin G. ; Linda F. N. ; Cho J. ; Peter G. B. Angew. Chem. Int. Ed 2012, 51, 9994.
3	Xu J. ; Wang X. F. ; Wang X.W. ; Chen D. ; Chen X. Y. ; Li D.D. ; Shen G. Z. ChemElectroChem 2014, 1, 975.
4	Munao D. ; Valvo M. ; Van Erven J. ; Kelder E. M. ; Hassoun J. ; Panero S. J. Mater. Chem 2012, 22, 1556.
5	Peng K. Q. ; Jie J. S. ; Zhang W. J. ; Lee S. T. Appl. Phys. Lett 2008, 93, 033105.
6	Kim G. ; Jeong S. ; Shin J. ; Cho J. ; Lee H. ACS Nano 2014, 8, 1907.
7	Wu H. ; Cui Y. Nano Today 2012, 7, 414.
8	Cui L. F. ; Ruffo R. ; Chan C. K. ; Peng H. L. ; Cui Y. Nano Lett 2009, 9, 491.
9	Zhou Y. L. ; Jiang X. L. ; Chen L. ; Yue J. ; Xu H. Y. ; Yang J. ; Qian Y. T. Electrochim. Acta 2014, 127, 252.
10	Yao Y. ; McDowell M. T. ; Ryu I. ; Wu H. ; Liu N. ; Hu L. ; Nix W. D. ; Cui Y. Nano Lett 2011, 11, 2949.
11	Datta M. K. ; Maranchi J. ; Chung S. J. ; Epur R. ; Kadakia K. ; Jampani P. ; Kumta P. N. Electrochim. Acta 2011, 56, 4717.
12	Tang Y. Y. ; Xia X. H. ; Yu Y. X. ; Shi S. J. ; Chen J. ; Zhang Y.Q. ; Tu J. P. Electrochim. Acta 2013, 88, 664.
13	Wang J. T. ; Wang Y. ; Huang B. ; Yang J. Y. ; Tan A. ; Lu S. G. Acta Phys.-Chim. Sin 2014, 30, 305.
13	王建涛; 王耀; 黄斌; 杨娟玉; 谭翱; 卢世刚. 物理化学学报, 2014, 30, 305d.
14	Yue L. ; Zhang W. H. ; Yang J. F. ; Zhang L. Z. Electrochim. Acta 2014, 125, 206.
15	Jia H. P. ; Gao P. F. ; Yang J. ; Wang J. L. ; Nuli Y.N. ; Yang Z. Adv. Energy Mater 2011, 1, 1036.
16	Park J. B. ; Lee K. H. ; Jeon Y. J. ; Lim S. H. ; Lee S. M. Electrochim. Acta 2014, 133, 73.
17	Zhang R. Y. ; Du Y. J. ; Li D. ; Shen D. K. ; Yang J. P. ; Guo Z.P. ; Liu H. K. ; Elzatahry A. A. ; Zhao D. Y. Adv. Mater 2014, 26, 6749.
18	Park J. ; Kim G. P. ; Nam I. ; Park S. ; Yi J. H. Nanotechnology 2013, 24, 025602.
19	Zhou Y. L. ; Jiang X. L. ; Chen L. ; Yu J. ; Xu H. Y. ; Yang J. ; Qian Y. T. Electrochim. Acta 2014, 127, 252.
20	Hong I. ; Scrosati B. ; Croce F. Solid State Ionics 2013, 232, 24.
21	Tao H. C. ; Fan L. Z. ; Qu X. H. Electrochim. Acta 2012, 71, 194.
22	Tao H. C. ; Huang M. ; Fan L. Z. ; Qu X.H. Solid State Ionics 2012, 220, 1.
23	Wang B. ; Li X. L. ; Qiu T. F. ; Luo B. ; Ning J. ; Li J. ; Zhang X. F. ; Liang M. H. ; Zhi L. J. Nano Lett 2013, 13, 5578d.
24	Lu Z. D. ; Liu N. ; Lee H.W. ; Zhao J. ; Li W. Y. ; Li Y. Z. ; Cui Y. ACS Nano 2015, 9, 2540.
25	Du Y. J. ; Zhu G. N. ; Wang K. ; Wang Y. G. ; Wang C. X. ; Xia Y. Y. Electrochem. Commun 2013, 36, 107.
26	Wang L. L. ; Munir Z. A. ; Maximov Y. M. J. Mater. Sci 1993, 28, 3693.
27	Jun S. ; Joo S. H. ; Ryoo R. ; Kruk M. ; Jaroniec M. ; Liu Z. ; Ohsuna T. ; Terasaki O. J. Am. Chem. Soc 2000, 122, 10712d.
28	Liu X. R. ; Yan H. J. ; Wang D. ; Wan L. J. Acta Phys.-Chim. Sin 2016, 32, 283.
28	刘兴蕊; 严会娟; 王栋; 万立骏. 物理化学学报, 2016, 32, 283.

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Magnesiothermic Reduction Preparation and Electrochemical Properties of a Highly Ordered Mesoporous Si/C Anode Material for Lithium-Ion Batteries

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