二氧化硅负载的不同碱金属硝酸盐催化乳酸缩合反应制备2, 3-戊二酮的催化性能比较研究

doi:10.3866/PKU.WHXB201606225

Abstract

Abstract:

The production of 2, 3-pentanedione from lactic acid over SiO₂-supported alkali metal nitrates under various conditions was investigated. Using nitrate (NO₃^-) as the anion, the effect of alkali metal cations on Claisen condensation of lactic acid into 2, 3-pentanedione was focused on. Among precursors such as LiNO₃, NaNO₃, KNO₃, and CsNO₃, CsNO₃ displayed the best catalytic performance. Characterization of the fresh and used catalysts by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed that all MNO₃ (M=Li, Na, K, Cs) salts were transformed into alkali metal lactates during the reaction. Alkali metal lactates were identified as active species for catalytic Claisen condensation of lactic acid into 2, 3-pentanedione. CO₂ temperature-programmed desorption (TPD) results of the used catalysts showed that the CsNO₃/SiO₂ catalyst was the most alkaline. For that reason, the CsNO₃/SiO₂ catalyst displayed the highest catalytic performance of those examined. The effects of reaction temperature and loading amount of CsNO₃ on reaction performance were also discussed. Over the 4.4% (x, molar fraction) CsNO₃/SiO₂ catalyst, a 54.1% yield of 2, 3-pentanedione was achieved at 300 ℃.

Key words: Lactic acid, 2, 3-Pentanedione, Condensation, Alkali metal nitrate, Lactate

MSC2000:

O643

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Liang-Wei SUN,Xin-Li LI,Cong-Ming TANG. Comparative Study on Catalytic Performance of the Production of 2, 3-Pentanedione from Lactic Acid Condensation over SiO₂-Supported Alkali Metal Nitrates[J].Acta Phys. -Chim. Sin., 2016, 32(9): 2327-2336.

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Comparative Study on Catalytic Performance of the Production of 2, 3-Pentanedione from Lactic Acid Condensation over SiO₂-Supported Alkali Metal Nitrates

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Comparative Study on Catalytic Performance of the Production of 2, 3-Pentanedione from Lactic Acid Condensation over SiO₂-Supported Alkali Metal Nitrates