B-TS-1分子筛的合成及其催化氧化性能

doi:10.3866/PKU.WHXB201606294

Abstract

Abstract:

In this paper, boron-modified titanium silicalite-1 (B-TS-1) was synthesized, and its catalytic performance was studied. B-TS-1 improved the stability of cyclohexanone ammoximation. Combined with the root of deactivation of the catalyst and H₂O₂ reaction behavior in the liquid-phase ammoximation process, analysis showed that H₂O₂ is the key to control the side reactions of the cyclohexanone ammoximation system to form organic byproducts, and these byproducts result in the deactivation of catalyst because they block pores. It is concluded that B-TS-1 could effectively decrease the residual H₂O₂ to suppress the side reactions and prolong the catalyst lifetime in cyclohexanone ammoximation. Simultaneous introduction of appropriate amounts of B and Al to form B/Al-TS-1 resulted in a material that further improved the stability of cyclohexanone ammoximation.

Key words: B/Al-TS-1, Catalytic oxidation, H₂O₂, Cyclohexanone ammoximation, Deactivation

MSC2000:

O643

Lei WANG,Han-Mei YIN,Jian-Hao WANG,Li-Zhi WU,Yue-Ming LIU. Synthesis and Catalytic Oxidation Performance of B-TS-1[J].Acta Phys. -Chim. Sin., 2016, 32(10): 2574-2580.

References

1	Taramasso M., Perego G., Notari B. Preparation of PorousCrystalline Synthetic Material Comprised of Silicon andTitanium Oxides. US Patent 4410501, 1983-10-18.
2	Clerici M. G. ; Bellussi G. ; Romano U J. Catal. 1991, 129, 159.
3	Sheldon R. A. ; Dakka J Catal. Today 1994, 19, 215.
4	Lee J. S. ; Kim J. C. ; Kim Y. J Appl. Catal. 1990, 57, 1.
5	Dai Y. F. ; Liu X. X. ; Sa X. L J. Mol. Catal. 1998, 12, 48.
5	戴延凤; 刘希尧; 萨学理. 分子催化, 1998, 12, 48.
6	Ding J. ; Xu L. ; Yu Y. ; Wu H. ; Huang S. ; Yang Y. ; Wu J. ; Wu P Catal. Sci. Technol. 2013, 3, 2587.
7	Roffia P., Padovan M., Leofanti G., Mantegazza M. A., DeAlberti G., Tauszik G. R. Catalytic Process for theManufacture of Oximes. US Patent 4794198, 1988-12-27.
8	Fang X. ; Wang Q. ; Zheng A. ; Liu Y. ; Lin L. ; Wu H. ; Deng F. ; He Y. ; Wu P Phys. Chem. Chem. Phys. 2013, 15, 4930.
9	Yang Y. ; Ding J. ; Xu C. ; Zhu W. ; Wu P J. Catal. 2015, 325, 101.
10	Xue Y. ; Xie Y. ; Wei H. ; Wen Y. ; Wang X. ; Li B New J. Chem. 2014, 38, 4229.
11	Xu H. ; Zhang Y. ; Wu H. ; Liu Y. ; Li X. ; Jiang J. ; He M. ; Wu P J. Catal. 2011, 281, 263.
12	Wu X. ; Wang Y. ; Zhang T. ; Wang S. ; Yao P. ; Feng W. ; Lin Y. ; Xu J Catal. Commun. 2014, 50, 59.
13	Sun B Petr. Pro. Pet. 2005, 36, 54.
13	孙斌. 石油炼制与化工, 2005, 36, 54.
14	Wang Y. ; Zhang S. J. ; Zh ao ; Y. X; Lin M J. Mol. Catal. A: Chem. 2014, 385, 1.
15	Zhuo Z. X. ; Wang L. ; Zhang X. Q. ; Wu L. Z. ; Liu Y. M. ; He M. Y J. Catal. 2015, 329, 107.
16	Huang D. G. ; Zhang X. ; Chen B. H. ; Chao Z. S Catal. Today 2010, 158, 510.
17	Ke X. B. ; Xu L. ; Zeng C. F. ; Zhang L. X. ; Xu N. P Microporous Mesoporous Mat. 2007, 106, 68.
18	Fan W. B. ; Duan R. G. ; Yokoi T. ; Wu P. ; Kubota Y. ; Tatsumi T J. Am. Chem. Soc. 2008, 130, 10150.
19	Camblor M. A., Corma, A; Pérez-Pariente J. J. Chem. Soc. Chem. Commun., 1993, 557. doi: 10.1039/C39930000557
20	Kapoor M. P. ; Trong D. ; Gallot J. E. ; Kaliaguine S Catal. Lett. 1997, 43, 127.
21	Bellusi G. ; Carati A. ; Clerici M. G. ; Esposito A Stud. Surf. Sci. Catal. 1991, 63, 421.
22	Shen L. ; Deng X. J. ; Liu Y. M Chin. J. Catal. 2013, 34, 1232.
22	申璐; 邓秀娟; 刘月明. 催化学报, 2013, 34, 1232d.
23	Ovejero G. ; Grieken R. V. ; Uguina M. A. ; Serrano D. P. ; Melero J. A J. Mater. Chem. 1998, 8, 2269.
24	Serrano D. P. ; Uguina M. A. ; Ovejero G. ; Grieken R. V. ; Camacho M. ; Melero J. A J. Mater. Chem. 1999, 9, 2899.

[1]	Zhi-Dan FU,Jia-Xin ZANG,Qing YE,Shui-Yuan CHENG,Tian-Fang KANG. Cu-Doped Octahedral Layered Birnessites Catalysts for the Catalytic Oxidation of CO and Ethyl Acetate [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1855-1864.
[2]	Ling-Xiao HU,Lian WANG,Fei WANG,Chang-Bin ZHANG,Hong HE. Catalytic Oxidation of o-Xylene over Pd/γ-Al₂O₃ Catalysts [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1681-1688.
[3]	Lin-Jun ZHAN,Xiao-Yan SUN,Ying ZHOU,Qiu-Lian ZHU,Yin-Fei CHEN,Han-Feng Lu. Deactivation Mechanism of CeO₂-Based Mixed Oxide Catalysts Supported on SiO₂ [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1474-1482.
[4]	Yi-Hao HU,Tong-Yang SONG,Yue-Juan WANG,Geng-Sheng HU,Guan-Qun XIE,Meng-Fei LUO. Gas Phase Dehydrochlorination of 1, 1, 2-Trichloroethane over Zn/SiO₂ Catalysts: Acidity and Deactivation [J]. Acta Phys. -Chim. Sin., 2017, 33(5): 1017-1026.
[5]	Xin CHEN,Shao-Zheng HU,Ping LI,Wei LI,Hong-Fei MA,Guang LU. Photocatalytic Production of Hydrogen Peroxide Using g-C₃N₄ Coated MgO-Al₂O₃-Fe₂O₃ Heterojunction Catalysts Prepared by a Novel Molten Salt-Assisted Microwave Process [J]. Acta Phys. -Chim. Sin., 2017, 33(12): 2532-2541.
[6]	Jun DU,Xiang-Ying WU,Xing-Peng PAN,Jiang YU. Oxygenation and Oxidation Desulfurization Properties of CeO₂/NaY Catalysts [J]. Acta Phys. -Chim. Sin., 2016, 32(9): 2337-2345.
[7]	Yue LI,Ting-Ting ZHANG,Juan WANG,Zhen ZHU,Bing JIA,Jiang YU. Catalytic Combustion of n-Hexanal Using Cu-Mn Composite Oxide Supported on TiO₂ [J]. Acta Phys. -Chim. Sin., 2016, 32(8): 2084-2092.
[8]	Zhao-Xin LIU,Wei-Bin LI. Catalytic Activity and Deactivation of Toluene Combustion on Rod-Like Copper-Manganese Mixed Oxides [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1795-1800.
[9]	Bang-De LUO,Xian-Qiang XIONG,Yi-Ming XU. Improved Photocatalytic Activity for Phenol Degradation of Rutile TiO₂ on the Addition of CuWO₄ and Possible Mechanism [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1758-1764.
[10]	Ping YUAN,Hao WANG,Yan-Feng XUE,Yan-Chun LI,Kai WANG,Mei DONG,Wei-Bin FAN,Zhang-Feng QIN,Jian-Guo WANG. Catalytic Properties of Different Crystal Sizes for ZSM-5 Zeolites on the Alkylation of Benzene with Methanol and Optimization of the Reaction Conditions [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1775-1784.
[11]	Si HU,Qing ZHANG,Yan-Jun GONG,Ying ZHANG,Zhi-Jie WU,Tao DOU. Deactivation and Regeneration of HZSM-5 Zeolite in Methanol-to-Propylene Reaction [J]. Acta Phys. -Chim. Sin., 2016, 32(7): 1785-1794.
[12]	Jing ZOU,Zhi-Lin FAN,Li-Sha JIANG,Dan-Hong ZHOU. Theoretical Study of the Solvent Adsorption on Ti-Peroxo Active Center in Ti-MWW Zeolite [J]. Acta Phys. -Chim. Sin., 2016, 32(4): 935-942.
[13]	Yan. LI,Ting-Ting. ZHANG,Yue. LI,Bing. JIA,Hua-Hua. TAN,Jiang. YU. Influence of Calcination Temperature on Dechlorination Performance of V₂O₅/CNTs-TiO₂ Catalysts [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1541-1548.
[14]	Wen-Jie. TIAN,Hong. WANG,Zhen. YIN,Ying. YANG,Jian-Xin. LI. Preparation of Nano-Manganite Loaded Titanium Electocatalytic Membrane for the Catalytic Oxidation of Benzyl Alcohol [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1567-1574.
[15]	XIE Xing-Xing, FEI Zhao-Yang, ZOU Chong, LI Zheng-Zhou, CHEN Xian, TANG Ji-Hai, CUI Mi-Fen, QIAO Xu. Effects of Rare-Earth Additives on Structures and Performances of CuO-CeO₂-SiO₂ Catalysts for Recycling Cl₂ from HCl Oxidation [J]. Acta Phys. -Chim. Sin., 2015, 31(6): 1153-1161.

Synthesis and Catalytic Oxidation Performance of B-TS-1

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 10