硫粉为硫源,多元醇辅助合成硫化钼纳米片

doi:10.3866/PKU.WHXB201702081

Abstract

Abstract:

MoS₂ nanosheets are prepared with sulfur powder and Na₂MoO₄ by a one-pot two-phase method at 170-200 ℃ for 8 h. In addition, a three-step growth mechanism based on the aggregation and coalescence model is proposed. The reassembly of sulfur powder ensures the transformation from sulfur powder to H₂S to reduce Na₂MoO₄ and plays a key role in the successful preparation of MoS₂ nanosheets. The as-prepared MoS₂ nanosheets are rich in unsaturated sulfur atoms, probably resulting from the dislocation cores of the MoS₂ nanosheets, which have been found to be beneficial for hydrogen evolution reaction catalysis. The method and growth mechanism adopted in this study may be applied to other transition metal dichalogenides for similar structures. The facile and green method provides an alternative for the preparation of MoS₂ nanosheets.

Key words: MoS₂ nanosheet, Sulfur powder, Aggregation and coalescence model, Ethylene glycol, Two-phase method

MSC2000:

O643

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Hui WANG,De-Chun ZOU. Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source[J].Acta Phys. -Chim. Sin., 2017, 33(5): 1027-1032.

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Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

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Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source