硫粉为硫源,多元醇辅助合成硫化钼纳米片

doi:10.3866/PKU.WHXB201702081

Abstract

Abstract:

MoS₂ nanosheets are prepared with sulfur powder and Na₂MoO₄ by a one-pot two-phase method at 170-200 ℃ for 8 h. In addition, a three-step growth mechanism based on the aggregation and coalescence model is proposed. The reassembly of sulfur powder ensures the transformation from sulfur powder to H₂S to reduce Na₂MoO₄ and plays a key role in the successful preparation of MoS₂ nanosheets. The as-prepared MoS₂ nanosheets are rich in unsaturated sulfur atoms, probably resulting from the dislocation cores of the MoS₂ nanosheets, which have been found to be beneficial for hydrogen evolution reaction catalysis. The method and growth mechanism adopted in this study may be applied to other transition metal dichalogenides for similar structures. The facile and green method provides an alternative for the preparation of MoS₂ nanosheets.

Key words: MoS₂ nanosheet, Sulfur powder, Aggregation and coalescence model, Ethylene glycol, Two-phase method

MSC2000:

O643

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Hui WANG,De-Chun ZOU. Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source[J].Acta Phys. -Chim. Sin., 2017, 33(5): 1027-1032.

References

1	Radisavljevic B. ; Radenovic A. ; Brivio J. ; Giacometti V. ; Kis A. Nat. Nanotechnol 2011, 6, 147.
2	Mark K. F. ; He K. ; Shan J. ; Heinz T. F. Nat. Nanotechnol 2012, 7, 494.
3	Splendiani A. ; Sun L. ; Zhang Y. ; Li T. ; Kim J. ; Chim C. Y. ; Galli G. ; Wang F. Nano Lett 2010, 10, 1271.
4	Li Y. ; Wang H. ; Xie L. ; Liang Y. ; Hong G. ; Dai H. J. Am. Chem. Soc 2011, 133, 7296.
5	Dagge M. ; Chianelli R. R. J. Catal 1994, 149, 414.
6	Jaramillo T. F. ; Jorgensen K. P. ; Bonde J. ; Nielsen J. H. ; Horch S. ; Chorkendorff I. Science 2007, 317, 100.
7	Karunadasa H. I. ; Montalvo E. ; Sun Y. ; Majda M. ; Long J.R. ; Chang C. J. Science 2002, 335, 698.
8	Benck J. D. ; Chen Z. ; Kuritzky A. L. ; Froman A. J. ; Jaramillo T. F. ACS Catal 2012, 2, 1916.
9	Benchk J. D. ; Hellstern T. R. ; Kibsgaard J. ; Chakthranont P. ; Jaramillo T. F. ACS Catal 2014, 2, 3957.
10	Kibsgarrd J. ; Chen Z. ; Beinecke B. N. ; Jaramillo T. F. Nat.Mater 2012, 11, 963.
11	Xie J. ; Zhang J. ; Li S. ; Grote F. ; Zhang X. ; Zhang H. ; Wang R. ; Lei Y. ; Pan B. ; Xie Y. J. Am. Chem. Soc 2013, 135, 17881.
12	Xie J. ; Zhang H. ; Li S. ; Wang R. ; Sun X. ; Zhou M. ; Zhou J. ; Lou X.W. ; Xie Y. Angew. Chem. Int. Ed 2013, 25, 5807.
13	Lee Y. ; Zhang X. Q. ; Zhang W. ; Chang M. T. ; Lin C. T. ; Chang K. D. ; Yu Y. C. ; Wang J. T. ; Chang C. S. ; Li L. J. ; Lin T. W. Adv. Mat 2012, 24, 2320.
14	Novoselov K. S. ; Jiang D. ; Schedin F. ; Booth T. J. ; Khotkevich V. V. ; Morozov S. V. ; Geim A. K. Proc. Natl.Acad. Sci. U. S. A 2005, 102, 10451.
15	Zhan Y. ; Liu Z. ; Najmaei S. ; Ajayan P. M. ; Lou J. Small 2012, 10, 966.
16	Bissessur R. ; Heising J. ; Hirpo W. ; Kanatzidis M. Chem.Mater 1996, 8, 318.
17	Danot M. ; Mansot J. L. ; Golub A. S. ; Protzenko G. A. ; Fabritchnyi P. B. ; Novikov Y. N., Rouxel, J. Mater. Res. Bull 1994, 29, 833.
18	Golub A. S. ; Zubavichus Y. V. ; Slovokhotov Y. L. ; Novikov Y.N. ; Danot M. Solid State Ionics 2000, 128, 151.
19	Tachibana H. ; Yamanaka Y. ; Sakai H. ; Abe M. ; Matsumoto M. Chem. Mater 2000, 12, 854.
20	Benavente E. ; Santa Ana M. A. ; Mendizabal F. ; Gonzalez G. Coord. Chem. Rev 2002, 224, 87.
21	Coleman J. ; Lotya M. ; O'Neill A. ; Bergin S. D. ; King P. J. ; Khan U. ; Young K. ; Gaucher A. ; De S. ; Smith R. J. ; Shvets I. V. ; Arora S. ; Stanton G. ; Kim H. Y. ; Lee K. ; Kim G. T. ; Duesberg G. S. ; Hallam T. ; Boland J. J. ; Wang J. J. ; Donegan J. F. ; Grunlan J. ; Moriarty G. ; Shmeliov A. ; Nicholls R. J. ; Perkins J. M. ; Grieveson E. M. ; Theuwissen K. ; McComb D.W. ; Nellist P. D. ; Nicolosi V. Science 2011, 331, 568.
22	Zhou K. G. ; Mao N. N. ; Wang H. X. ; Peng Y. ; Zhang H. L. Angew. Chem. Int. Ed 2011, 50, 10839.
23	O'Neill A. ; Khan Umar ; Coleman J. N. Chem. Mater 2012, 24, 2414.
24	Voiry D. ; Salehi M. ; Silva R. ; Fujita T. ; Chen M. ; Asefa T. ; Shenoy V. B. ; Eda G. ; Chhowalla M. Nano Lett 2013, 13, 6222.
25	Jawaid A. ; Nepal D. ; Park K. ; Jespersen M. ; Qualley A. ; Mirau P. ; Drummy L. F. ; Vaia R. A. Chem. Mater 2016, 28, 337.
26	Zhou W. ; Zou X. L. ; Najmaei S. ; Zheng L. ; Shi Y. M. ; Kong J. ; Lou J. ; Ajayan P. M. ; Yakobson B. I. ; Idrobo J. Nano Lett 2013, 13, 2615.
27	Kalsin A. M. ; Fialkowski M. ; Paszewski M. ; Smoukov S. K. ; Bishop K. J. M. ; Grzybowski B. A. Science 2006, 321, 420.
28	Tang Z. Y. ; Zhang Z. L. ; Wang Y. ; Glotzer S. C. ; Kotov N. A. Science 2006, 314, 274.
29	Glotzer S. C. ; Solomon M. J. Nat. Mater 2007, 6, 557.
30	Min Y. J. ; Akbulut M. ; Kristiansen K. ; Golan Y. ; Israelachvili J. Nat. Mater. 2008, 7, 527.
31	Schliehe C. ; Juarez B. H. ; Pelletier M. ; Jander S. ; Greshnykh D. ; Nagel M. ; Meyer A. ; Foerster S. ; Kornowski A. ; Klinke C. ; Weller H. Science 2010, 329, 550.
32	Xia Y. S. ; Nguyen T. D. ; Yang M. ; Lee B. ; Santos A. ; Podsiadlo P. ; Tang Z. Y. ; Glotzer S. C. ; Kotov N. A. Nat.Nanotechnol 2011, 6, 580.
33	Plote J. ; Erler R. ; Thunemann A. F. ; Emmerling F. ; Kraehnert R. Chem. Commun 2010, 46, 9209.
34	Polte J. ; Ahner T. T. ; Delissen F. ; Sokolov S. ; Emmerling F. ; Thunemann A. F. ; Kraehnert R. J. Am. Chem. Soc 2010, 132, 1296.
35	Polte J. CrystEngComm 2015, 17, 6809.
36	Fairbrother F. ; Gee G. ; Merrall G. T. J. Polym. Sci 1955, 16, 459.
37	Zheng Y. ; Cheng Y. ; Wang Y. ; Zhou L. ; Bao F. ; Jia C. J. Phys. Chem. B 2006, 110 (16), 8284.
38	Fei L. F. ; Lei S. J. ; Zhang W. B. ; Lu W. ; Lin Z. Y. ; Lam C.H. ; Chai Y. ; Wang Y. Nat. Commun 2016, 7, 1.
39	Yue H. R. ; Zhao Y. J. ; Gong J. L. Chem. Soc. Rev 2012, 41, 4218.
40	Biacchi A. J. ; Schaak R. E. ACS Nano 2011, 5, 8089.
41	Fifvet F. ; Lagier J. P. ; Blin B. Solid State Ionics 1989, 32, 198.
42	Silvert P. V. ; Tekaia-Elhsissen K. Solid State Ionics 1995, 82, 53.
43	Bonet F. ; Delmas V. ; Grugeon S. ; Urina H. R. ; Silvert P. Y. ; Tekaia-Elhsissen K. Nano Structured Material 1999, 11, 1277.
44	Schmitt P. ; Brem N. ; Schunk S. ; Feldmann C. Adv. Funct.Mater. 2011, 21, 3037.
45	Feldmann C. Adv. Funct. Mater 2003, 13, 101.
46	Sun Y. G. ; Xia Y. N. Science 2002, 298, 2176.
47	Chen J. Y. ; Herricks T. ; Geissler M. ; Xia Y. N. J. Am. Chem.Soc 2004, 126, 10854.
48	Rusitskiy A. ; Xia Y. N. J. Am. Chem. Soc 2016, 138, 3161.
49	Akiya N. ; Savage P. E. Chem. Rev 2002, 102, 2725.
50	Erickson B. E. ; Helz G. R. Geochim. Cosmochim. Ac 2000, 64, 1149.

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Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source

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Polyol-Mediated Synthesis of MoS₂ Nanosheets Using Sulfur Powder as the Sulfur Source