Acta Physico-Chimica Sinica ›› 2019, Vol. 35 ›› Issue (6): 565-571.doi: 10.3866/PKU.WHXB201805080
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Qin WANG,Minmin XUE,Zhuhua ZHANG*()
Received:
2018-05-28
Accepted:
2018-07-01
Published:
2018-10-31
Contact:
Zhuhua ZHANG
E-mail:chuwazhang@nuaa.edu.cn
Supported by:
MSC2000:
Qin WANG,Minmin XUE,Zhuhua ZHANG. Chemical Synthesis of Borophene: Progress and Prospective[J].Acta Physico-Chimica Sinica, 2019, 35(6): 565-571.
Fig 1
The parallel of chemistry between carbon and boron (a) Carbon can form sp3, sp2 and sp bonds, thus can form a variety of nanostructures, such as 1D atomic chains, nanotubes and diamond. (b) Because of electronic deficiency, boron can form a vast number of multicenter chemical bonds, forming a typical B12 icosahedron in bulk phases as well as planar, fullerene molecules and nanotube structure at nanoscale."
Fig 2
Theoretical and experimental synthesis of two-dimensional borophene (a) Historical evolution of theoretical models of borophene, from the initial triangular structure to the combined structure of triangular lattice and hollow hexagons, to the polymorphism of borophene, and then to the energetically preferred borophene on substrates. (b) High resolution scanning electron microscope (SEM) image of stripe borophene (S1) synthesized by molecular beam epitaxy, compared to simulated SEM image using the v1/6 model on Ag substrate. (c) SEM image of homogeneous phase borophene (S2), compared to simulated SEM image based on the v1/5 model. (b) is adopted from American Association for the Advancement of Science publisher and (c) is adopted from Springer Nature publisher 11, 12."
Fig 3
The nucleation selectivity of borophene (a) Schematic diagram of the free energy of boron growth on a substrate along two- and three-dimensional routes. The range of temperature corresponding to the energy range of yellow shaded area should benefit boron nucleation along the 2D route. (b) A schematic diagram of nucleation and growth of 3D boron along a step of metal substrate. (c) The same as (b) but for 2D boron. (a) is adopted from Springer Nature publisher 44."
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