Acta Physico-Chimica Sinica ›› 2019, Vol. 35 ›› Issue (9): 1021-1026.doi: 10.3866/PKU.WHXB201811044
Special Issue: C–H Activation
• Article • Previous Articles Next Articles
Qingbing WANG,Zhengwei GUO,Gong CHEN*(),Gang HE*(
)
Received:
2018-11-30
Accepted:
2019-01-22
Published:
2019-01-24
Contact:
Gong CHEN,Gang HE
E-mail:gongchen@nankai.edu.cn;hegang@nankai.edu.cn
Supported by:
MSC2000:
Qingbing WANG,Zhengwei GUO,Gong CHEN,Gang HE. DPPF-Mediated C―H Arylation of Arenes with Aryl Iodides for Synthesis of Biaryl Linkages[J].Acta Physico-Chimica Sinica, 2019, 35(9): 1021-1026.
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Entry | Condition | Yield (%) b |
1 | Cs2CO3(2 equiv), 110 ℃ | < 10 |
2 | t-BuOK(2 equiv), 110 ℃ | 64 |
3 | t-BuONa (2 equiv), 110 ℃ | NR |
4 | t-BuOLi(2 equiv), 110 ℃ | NR |
5 | t-BuOK(2 equiv), 130 ℃ | 73 |
6 | t-BuOK(2 equiv), 140 ℃ | 78 (73)c |
7 | t-BuOK(2 equiv), TBAI (0.2 equiv), 130 ℃ | 28 |
8 | t-BuOK(2 equiv), TBAB (0.2 equiv), 130 ℃ | 30 |
9 | dppf (20% (x)), t-BuOK (2 equiv), 130 ℃ | 74 |
10 | t-BuOK (2 equiv), 18-crown-6 (40% (x)), 140 ℃ | 61 |
11 | t-BuOK (2 equiv), 18-crown-6 (40%(x)), 140 ℃ | 51 d |
12 | t-BuOK(2 equiv), 140 ℃ | 25 d |
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