Fig 1

Rhodium(Ⅲ)-catalyzed C―H olefination for the synthesis of ortho-alkenyl phenols 29. Adapted from ACS publisher."

Fig 2

Rhodium(Ⅲ)-catalyzed N-phenoxyacetamides and α, β-unsaturated aldehydes to synthesis 1, 2-oxazepines 33. Adapted from RSC publisher."

Fig 3

Rhodium(Ⅲ)-catalyzed transannulation of cyclopropenes with N-phenoxyacetamides 34. Adapted from Wiley publisher."

Fig 4

Rh-catalyzed ortho C―H vinylation of arenes by vinylstannanes 35. Adapted from RSC publisher. "

Fig 5

Rhodium(Ⅲ) catalyzed carboamination of clkenes triggered by C―H activation of N-phenoxyacetamides 36. Adapted from ACS publisher."

Fig 6

Cobalt(Ⅲ)-catalyzed intermolecular carboamination of alkenes to synthesis unnatural amino acid 39. Adapted from Wiley publisher."

Fig 7

Rhodium-catalyzed cyclization of O, ω-unsaturated alkoxyamines 40. Adapted from Wiley publisher. "

Fig 8

Rhodium(Ⅲ)-catalyzed annulative carbooxygenation of 1, 1-disubstituted alkenes 45. Adapted from Wiley publisher."

Fig 9

Rh(Ⅲ)-catalyzed C―H alkylation reaction with allylic alcohols 46. Adapted from RSC publisher."

Fig 10

Rh-catalyzed arylation and cycloisomerization of cyclopropenes synthesis of arylated furans 47. Adapted from Wiley publisher."

Fig 11

Rhodium(Ⅲ)-catalyzed C―H activation and rearrangement reaction 48. Adapted from Wiley publisher."

Fig 12

Rhodium(Ⅲ)-catalyzed N-phenoxyacetamides and methyleneoxetanones synthesis of 2H-chromene-3-carboxylic acids 49. Adapted from ACS publisher."

Fig 13

Rhodium(Ⅲ)-catalyzed redox-neutral coupling of N-phenoxyacetamides and alkynes with tunable selectivity 50. Adapted from Wiley publisher. "

Fig 14

Ruthenium-catalyzed C―H functionalization to synthesis benzofurans 51. Adapted from RSC publisher."

Fig 15

Rhodium(Ⅲ)-catalyzed N-phenoxyacetamides and alkynes with multitasking functional group leads to structural diversity 52. Adapted from Nature publisher."

Fig 16

Rhodium(Ⅲ)-catalyzed synthesis of 3-alkylidene dihydrobenzofuran derivatives 53. Adapted from ACS publisher."

Fig 17

Ir(Ⅲ)-catalyzed direct C―H alkynylation of N-phenoxyacetamides with terminal alkyne 54. Adapted from ACS publisher."

Fig 18

Rh-Cu bimetallic catalyzed C≡C bond cleavage 55. Adapted from RSC publisher."

Fig 19

Rhodium-catalyzed synthesis of 3-arylbenzofuran-2-ylphosphines 56. Adapted from ACS publisher. "

Fig 20

Rh(Ⅲ)-catalyzed ortho C―H alkynylation of N-phenoxyacetamides with hypervalent iodine-alkyne reagents 57. Adapted from RSC publisher."

Fig 21

Rhodium(Ⅲ)-catalyzed N-aryloxyacetamides with alkynyloxiranes synthesis of 2, 3-dihydrobenzofurans 58. Adapted from ACS publisher."

Fig 22

Iridium(Ⅲ)-catalyzed regioselective C―H annulation of N-phenoxyacetamides with propargyl alcohols 59. Adapted from Wiley publisher."

Fig 23

Rhodium-catalyzed coupling of N-phenoxyacetamides and nonterminal propargyl alcohols 60. Adapted from ACS publisher."

Fig 24

Rh(Ⅲ)-catalyzed and solvent-controlled chemoselective synthesis of chalcone and benzofuran frameworks 61. Adapted from ACS publisher. "

Fig 25

Rhodium(Ⅲ)-catalyzed redox-neutral cascade [3 + 2] annulation of N phenoxyacetamides with propiolates 62. Adapted from ACS publisher. "

Fig 26

Metal-free direct construction of 2 (oxazol-5-yl)phenols from N phenoxyamides and alkynylbenziodoxolones 63. Adapted from ACS publisher."

Fig 27

Rhodium(Ⅲ)-catalyzed ortho alkenylation of N-phenoxyacetamides with N-tosylhydrazones or diazoesters 64. Adapted from Wiley publisher. "

Fig 28

Rh(Ⅲ)-catalyzed and alcohol-involved carbenoid C―H insertion into N-phenoxyacetamides using α-diazomalonates 65. Adapted from RSC publisher."

Fig 29

Rhodium(Ⅲ)-catalyzed synthesis of unsymmetrical ortho-biphenols 66. Adapted from Wiley publisher."

Fig 30

Rh(Ⅲ)-catalyzed one-pot reaction synthesis of polyaryl-substituted olefins 67. Adapted from ACS publisher."

Fig 31

Rh(Ⅲ)-catalyzed unsymmetrical alkylation and amidation reactions of N-phenoxyacetamides 68. Adapted from ACS publisher."

Fig 32

Palladium-catalyzed benzo[d]isoxazole synthesis by C―H activation/[4 + 1] annulation 69. Adapted from RSC publisher."

Fig 33

Tentative mechanism for the cross-coupling of N-aryloxyacetamide with azoles 70. Adapted from Wiley publisher."

Fig 34

Rh(Ⅲ)-catalyzed dehydrogenative coupling synthesis of mono/bis-arylated phenols 73. Adapted from RSC publisher."

Fig 35

Bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis 74. Adapted from Nature publisher."

Fig 36

Cp*Rh(Ⅲ)/bicyclic olefin cocatalyzed C―H bond amidation by intramolecular amide transfer 75. Adapted from ACS publisher."

Fig 37

Ir(Ⅲ)-catalyzed redox-neutral synthesis of catechol 76. Adapted from Nature publisher. "

Fig 38

Bioinspired selenium-catalysed para- amination of phenols 77. Adapted from Nature publisher."