面向金属离子电池研究的固体核磁共振和电子顺磁共振方法

doi:10.3866/PKU.WHXB201902019

Abstract

Abstract:

The rapid development of batteries, especially lithium-ion batteries, has dramatically changed our daily lives. From portable electronics to electric vehicles and smart grids, batteries are extensively used in many fields and are difficult to be replaced in terms of their excellent energy and power densities. The advancement of battery technology requires the thorough understanding of electrochemical reaction mechanisms, which strongly depends on the collaboration of researchers from different fields. Magnetic resonance spectroscopy includes the important techniques of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR), and the former is suitable for studying light elements commonly found in batteries including Li, Na, P and O, while the latter is suitable for studying heavier transition metals such as Co, Mn, Fe and V. In addition, NMR and EPR are capable of quantitatively analysis in a nondestructive manner regardless of sample crystallinity. Hence, NMR and EPR spectroscopies have allowed for significant research progress and have become increasingly important for battery research over the past three decades. Herein, we will provide our perspective of magnetic resonance methods and first summarize the main interactions and the Hamiltonian forms of solid-state NMR and EPR (dipole-dipole interaction, electric quadrupole interaction, chemical shift, and hyperfine interaction). Subsequently, we summarize the important and frequently-used methods of solid-state NMR and EPR spectroscopies and introduce their representative applications in metal ion battery research (mainly lithium- and sodium-ion batteries). Specifically, we introduce the basic principles and representative applications of (ⅰ) MQMAS (multiple-quantum magic angle spinning), (ⅱ) pjMATPASS (MAT = magic-angle turning, PASS = phase-adjusted sideband separation, and pj = projection), (ⅲ) WURST-CPMG (WURST = wide band uniform rate smooth truncation, CPMG = Carr-Purcell Meiboom-Gil), (ⅳ) 2D homonuclear correlation and exchange (2D EXSY), (ⅴ) 2D homonuclear correlation based on dipole coupling (i.e. RFDR), (ⅵ) perpendicular mode EPR, (ⅶ) parallel mode EPR, (ⅷ) in situ NMR, and (ⅸ) in situ EPR. In addition, we briefly introduce representative applications of 2D heteronuclear correlation (i.e. CP-HETCOR), pulsed field gradient NMR, spin-lattice relaxation (SLR), spin alignment echo (SAE), DFT calculations, and dynamic nuclear polarization (DNP). Previous reviews regarding the application of magnetic resonance technology in battery research are almost all reported in terms of the classification of battery materials. In other words, they are written from the perspective of applications in cathode, anode, and electrolyte research. Herein, we summarize from the perspective of solid-state NMR and EPR methods, which may be beneficial for the readers to fully understand the value of these important technologies. We believe this review can serve as a guide to solve challenges related to using solid-state NMR and EPR spectroscopies in battery research.

Key words: Solid-state NMR, Electron paramagnetic resonance, Lithium-ion battery, Sodium-ion battery, Charge-discharge mechanism, Structure-function ralationship, Local structure

MSC2000:

O641

Chao Li, Ming Shen, Bingwen Hu. Solid-State NMR and EPR Methods for Metal Ion Battery Research[J].Acta Physico-Chimica Sinica, 2020, 36(4): 1902019.

Figures/Tables 10

Fig 1

Fig 2

Fig 3

Fig 4

Fig 5

Fig 6

Fig 7

Fig 8

Fig 9

Fig 10

References 136

1	Li M. ; Lu J. ; Chen Z. ; Amine K. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561
2	Larcher D. ; Tarascon J. M. Nat. Chem. 2015, 7, 19. doi: 10.1038/nchem.2085
3	Goodenough J. B. ; Park K. S. J. Am. Chem. Soc. 2013, 135, 1167. doi: 10.1021/ja3091438
4	Yang Z. ; Zhang W. ; Shen Y. ; Yuan L. X. ; Huang Y. H. Acta Phys. -Chim. Sin. 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
	杨泽; 张旺; 沈越; 袁利霞; 黄云辉. 物理化学学报, 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
5	Goodenough J. B. Energy Storage Mater. 2015, 1, 158. doi: 10.1016/j.ensm.2015.07.001
6	Tarascon J. M. Nat. Chem. 2010, 2, 510. doi: 10.1038/nchem.680
7	Choi J. W. ; Aurbach D. Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13
8	Slater M. D. ; Kim D. ; Lee E. ; Johnson C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.201200691
9	Fang C. ; Huang Y. ; Zhang W. ; Han J. ; Deng Z. ; Cao Y. ; Yang H. Adv. Energy Mater. 2016, 6, 1501727. doi: 10.1002/aenm.201501727
10	Wang P. F. ; You Y. ; Yin Y. X. ; Guo Y. G. Adv. Energy Mater. 2018, 8, 1701912. doi: 10.1002/aenm.201701912
11	Fang Y. J. ; Chen Z. X. ; Ai X. P. ; Yang H. X. ; Cao Y. L. Acta Phys. -Chim. Sin. 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
	方永进; 陈重学; 艾新平; 杨汉西; 曹余良. 物理化学学报, 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
12	Wu X. ; Leonard D. P. ; Ji X. Chem. Mater. 2017, 29, 5031. doi: 10.1021/acs.chemmater.7b01764
13	Li C. ; Hu X. ; Hu B. Electrochim. Acta 2017, 253, 439. doi: 10.1016/j.electacta.2017.09.090
14	Zhang Z. ; Dong S. ; Cui Z. ; Du A. ; Li G. ; Cui G. Small Methods 2018, 2, 1800020. doi: 10.1002/smtd.201800020
15	Wang M. ; Jiang C. ; Zhang S. ; Song X. ; Tang Y. ; Cheng H. M. Nat. Chem. 2018, 10, 667. doi: 10.1038/s41557-018-0045-4
16	Lin M. C. ; Gong M. ; Lu B. ; Wu W. ; Wang D. Y. ; Guan. M. ; Angell M. ; Chen C. ; Yang. J. ; Hwang B. J. ; et al Nature 2015, 520, 324. doi: 10.1038/nature14340
17	Kim D. J. ; Yoo D. J. ; Otley M. T. ; Prokofjevs A. ; Pezzato C. ; Owczarek M. ; Lee S. J. ; Choi J. W. ; Stoddart J. F. Nat. Energy 2018, 4, 51. doi: 10.1038/s41560-018-0291-0
18	Grey C. P. ; Tarascon J. M. Nat. Mater. 2017, 16, 45. doi: 10.1038/nmat4777
19	Lu J. ; Wu T. ; Amine K. Nat. Energy 2017, 2, 17011. doi: 10.1038/nenergy.2017.11
20	Pecher O. ; Carretero-González J. ; Griffith K. J. ; Grey C. P. Chem. Mater. 2017, 29, 213. doi: 10.1021/acs.chemmater.6b03183
21	Grey C. P. ; Dupre N. Chem. Rev. 2004, 104, 4493. doi: 10.1021/cr020734p
22	Zhong G. ; Liu Z. ; Wang D. ; Li Q. ; Fu R. ; Yang. Y. J. Electrochem. 2016, 22, 231. doi: 10.13208/j.electrochem.151246
	钟贵明; 刘子庚; 王大为; 李琦; 傅日强; 杨勇. 电化学, 2016, 22, 231. doi: 10.13208/j.electrochem.151246
23	Duer, M. J. Solid-State Nmr Spectroscopy: Principles and Applications; Blackwell Sci., London, 2002.
24	Pigliapochi R. ; Pell A. J. ; Seymour I. D. ; Grey C. P. ; Ceresoli D. ; Kaupp M. Phys. Rev. B 2017, 95, 054412. doi: 10.1103/PhysRevB.95.054412
25	Frydman L. ; Harwood J. S. J. Am. Chem. Soc. 1995, 117, 5367. doi: 10.1021/ja00124a023
26	Hrobárik P. ; Reviakine R. ; Arbuznikov A. V. ; Malkina O. L. ; Malkin V. G. ; Köhler F. H. ; Kaupp M. J. Chem. Phys. 2007, 126, 024107. doi: 10.1063/1.2423003
27	Amoureux J. P. ; Fernandez C. ; Steuernagel S. J. Magn. Reson. A 1996, 123, 116. doi: 10.1006/jmra.1996.0221
28	Gan Z. ; Kwak H. T. J. Magn. Reson. 2004, 168, 346. doi: 10.1016/j.jmr.2004.03.021
29	Gan Z. J. Am. Chem. Soc. 2000, 122, 3242. doi: 10.1021/ja9939791
30	Morita R. ; Gotoh K. ; Fukunishi M. ; Kubota K. ; Komaba S. ; Nishimura N. ; Yumura T. ; Deguchi K. ; Ohki S. ; Shimizu T. ; et al J. Mater. Chem. A 2016, 4, 13183. doi: 10.1039/C6TA04273B
31	Li C. ; Shen M. ; Hu B. ; Lou X. ; Zhang X. ; Tong W. ; Hu B. J. Mater. Chem. A 2018, 6, 8340. doi: 10.1039/C8TA00568K
32	Li C. ; Shen M. ; Lou X. ; Hu B. J. Phys. Chem. C 2018, 122, 27224. doi: 10.1021/acs.jpcc.8b09151
33	Reeve Z. E. M. ; Franko C. J. ; Harris K. J. ; Yadegari H. ; Sun X. ; Goward G. R. J. Am. Chem. Soc. 2017, 139, 595. doi: 10.1021/jacs.6b11333
34	Hung I. ; Zhou L. ; Pourpoint F. ; Grey C. P. ; Gan Z. J. Am. Chem. Soc. 2012, 134, 1898. doi: 10.1021/ja209600m
35	Clement R. J. ; Pell A. J. ; Middlemiss D. S. ; Strobridge F. C. ; Miller J. K. ; Whittingham M. S. ; Emsley L. ; Grey C. P. ; Pintacuda G. J. Am. Chem. Soc. 2012, 134, 17178. doi: 10.1021/ja306876u
36	Li X. ; Tang M. ; Feng X. ; Hung I. ; Rose A. ; Chien P. H. ; Gan Z. ; Hu Y. Y. Chem. Mater. 2017, 29, 8282. doi: 10.1021/acs.chemmater.7b02589
37	Xu J. ; Lee D. H. ; Clément R. J. ; Yu X. ; Leskes M. ; Pell A. J. ; Pintacuda G. ; Yang X. Q. ; Grey C. P. ; Meng Y. S. Chem. Mater. 2014, 26, 1260. doi: 10.1021/cm403855t
38	Clément R. J. ; Xu J. ; Middlemiss D. S. ; Alvarado J. ; Ma C. ; Meng Y. S. ; Grey C. P. J. Mater. Chem. A 2017, 5, 4129. doi: 10.1039/c6ta09601h
39	Hung I. ; Gan Z. J. Magn. Reson. 2010, 204, 150. doi: 10.1016/j.jmr.2010.02.004
40	Gan Z. J. Am. Chem. Soc. 1992, 114, 8307. doi: 10.1021/ja00047a062
41	Antzutkin O. N. ; Shekar S. C. ; Levitt M. H. J. Magn. Reson., Series A 1995, 115, 7. doi: 10.1006/jmra.1995.1142
42	Lee J. ; Kitchaev D. A. ; Kwon D. H. ; Lee C. W. ; Papp J. K. ; Liu Y. S. ; Lun Z. ; Clément R. ; Shi T. ; McCloskey B. D. ; et al Nature 2018, 556, 185. doi: 10.1038/s41586-018-0015-4
43	Lee J. ; Urban A. ; Li X. ; Su D. ; Hautier G. ; Ceder G. Science 2014, 343, 519. doi: 10.1126/science.1246432
44	Xu S. ; Wang G. ; Biswal B. P. ; Addicoat M. ; Paasch S. ; Sheng W. ; Zhuang X. ; Brunner E. ; Heine T. ; Berger R. ; et al Angew. Chem. Int. Ed. 2019, 58, 849. doi: 10.1002/anie.201812685
45	O'Dell L. A. ; Schurko R. W. Chem. Phys. Lett. 2008, 464, 97. doi: 10.1016/j.cplett.2008.08.095
46	MacGregor A. W. ; O'Dell L. A. ; Schurko R. W. J. Magn. Reson. 2011, 208, 103. doi: 10.1016/j.jmr.2010.10.011
47	Hung I. ; Gan Z. J. Magn. Reson. 2010, 204, 256. doi: 10.1016/j.jmr.2010.03.001
48	Harris K. J. ; Reeve Z. E. M. ; Wang D. ; Li X. ; Sun X. ; Goward G. R. Chem. Mater. 2015, 27, 3299. doi: 10.1021/acs.chemmater.5b00323
49	Peng B. ; Shen M. ; Amoureux J. P. ; Hu B. Solid State Nucl. Magn. Reson. 2016, 78, 1. doi: 10.1016/j.ssnmr.2016.05.002
50	Takegoshi K. ; Nakamura S. ; Terao T. J. Chem. Phys. 2003, 118, 2325. doi: 10.1063/1.1534105
51	Takegoshi K. ; Nakamura S. ; Terao T. Chem. Phys. Lett. 2001, 344, 631. doi: 10.1016/S0009-2614(01)00791-6
52	Hu B. ; Lafon O. ; Trébosc J. ; Chen Q. ; Amoureux J. P. J. Magn. Reson. 2011, 212, 320. doi: 10.1016/j.jmr.2011.07.011
53	Hu B. ; Trébosc J. ; Lafon O. ; Chen Q. ; Masuda Y. ; Takegoshi K. ; Amoureux J. P. ChemPhysChem 2012, 13, 3585. doi: 10.1002/cphc.201200548
54	Cahill L. S. ; Chapman R. P. ; Britten J. F. ; Goward G. R. J. Phys. Chem. B 2006, 110, 7171- 7177. doi: 10.1021/jp057015+
55	Langer J. ; Smiley D. L. ; Bain A. D. ; Goward G. R. ; Wilkening M. J. Phys. Chem. C 2016, 120, 3130. doi: 10.1021/acs.jpcc.5b09894
56	Bain A. D. Prog. Nucl. Magn. Reson. Spectrosc. 2003, 43, 63. doi: 10.1016/j.pnmrs.2003.08.001
57	Davis L. J. M. ; He X. J. ; Bain A. D. ; Goward G. R. Solid State Nuclear Magnetic Resonance 2012, 42, 26. doi: 10.1016/j.ssnmr.2012.01.002
58	Davis L. J. M. ; Heinmaa I. ; Goward G. R. Chem. Mater. 2010, 22, 769. doi: 10.1021/cm901402u
59	Smiley D. L. ; Davis L. J. M. ; Goward G. R. J. Phys. Chem. C 2013, 117, 24181. doi: 10.1021/jp407510h
60	Hu Y. Y. ; Liu Z. ; Nam K. W. ; Borkiewicz O. J. ; Cheng J. ; Hua X. ; Dunstan M. T. ; Yu X. ; Wiaderek K. M. ; Du L. S. ; et al Nat. Mater. 2013, 12, 1130. doi: 10.1038/nmat3784
61	Kuhn A. ; Dupke S. ; Kunze M. ; Puravankara S. ; Langer T. ; Pöttgen R. ; Winter M. ; Wiemhöfer H. D. ; Eckert H. ; Heitjans P. J. Phys. Chem. C 2014, 118, 28350. doi: 10.1021/jp505386u
62	Smiley D. L. ; Goward G. R. Chem. Mater. 2016, 28, 7645. doi: 10.1021/acs.chemmater.6b02539
63	Zheng J. ; Tang M. ; Hu Y. Y. Angew. Chem. Int. Ed. 2016, 55, 12538. doi: 10.1002/anie.201607539
64	van Wullen L. ; Echelmeyer T. ; Meyer H. W. ; Wilmer D. Phys. Chem. Chem. Phys. 2007, 9, 3298. doi: 10.1039/b703179c
65	Wang D. ; Zhong G. ; Pang W. K. ; Guo Z. ; Li Y. ; McDonald M. J. ; Fu R. ; Mi J. X. ; Yang Y. Chem. Mater. 2015, 27, 6650. doi: 10.1021/acs.chemmater.5b02429
66	Liu Q. ; Li C. ; Wei L. ; Shen M. ; Yao Y. ; Hu B. ; Chen Q. Polymer 2014, 55, 5454. doi: 10.1016/j.polymer.2014.08.055
67	Cadars S. ; Sein J. ; Duma L. ; Lesage A. ; Pham T. N. ; Baltisberger J. H. ; Brown S. P. ; Emsley L. J. Magn. Reson. 2007, 188, 24. doi: 10.1016/j.jmr.2007.05.016
68	Fayon F. ; Le Saout G. ; Emsley L. ; Massiot D. Chem. Commun. 2002, 1702. doi: 10.1039/B205037B
69	Feike M. ; Demco D. E. ; Graf R. ; Gottwald J. ; Hafner S. ; Spiess H. W. J. Magn. Reson., Series A 1996, 122, 214. doi: 10.1006/jmra.1996.0197
70	Bennett A. E. ; Griffin R. G. ; Ok J. H. ; Vega S. J. Chem. Phys. 1992, 96, 8624. doi: 10.1063/1.462267
71	Shen M. ; Hu B. ; Lafon O. ; Trébosc J. ; Chen Q. ; Amoureux J. P. J. Magn. Reson. 2012, 223, 107. doi: 10.1016/j.jmr.2012.07.013
72	Nishiyama Y. ; Zhang R. ; Ramamoorthy A. J. Magn. Reson. 2014, 243, 25. doi: 10.1016/j.jmr.2014.03.004
73	Wang Q. ; Hu B. ; Lafon O. ; Trébosc J. ; Deng F. ; Amoureux J. P. J. Magn. Reson. 2009, 200, 251. doi: 10.1016/j.jmr.2009.07.009
74	Hu B. ; Wang Q. ; Lafon O. ; Trébosc J. ; Deng F. ; Amoureux J. P. J. Magn. Reson. 2009, 198, 41. doi: 10.1016/j.jmr.2009.01.002
75	Wang Q. ; Hu B. ; Fayon F. ; Trébosc J. ; Legein C. ; Lafon O. ; Deng F. ; Amoureux J. P. Phys. Chem. Chem. Phys. 2009, 11, 10391. doi: 10.1039/B914468D
76	Messinger R. J. ; Ménétrier M. ; Salager E. ; Boulineau A. ; Duttine M. ; Carlier D. ; Mba J. M. A. ; Croguennec L. ; Masquelier C. ; Massiot D. ; et al Chem. Mater. 2015, 27, 5212. doi: 10.1021/acs.chemmater.5b01234
77	Michan A. L. ; Divitini G. ; Pell A. J. ; Leskes M. ; Ducati C. ; Grey C. P. J. Am. Chem. Soc. 2016, 138, 7918. doi: 10.1021/jacs.6b02882
78	Michan A. L. ; Leskes M. ; Grey C. P. Chem. Mater. 2016, 28, 385. doi: 10.1021/acs.chemmater.5b04408
79	Neuberger S. ; Culver S. P. ; Eckert H. ; Zeier W. G. ; Auf der Gunne J. S. Dalton Trans. 2018, 47, 11691. doi: 10.1039/c8dt02619j
80	Pecquenard B. ; Gourier D. ; Baffier N. Solid State Ionics 1995, 78, 287. doi: 10.1016/0167-2738(95)00099-R
81	Massarotti V. ; Capsoni D. ; Bini M. ; Azzoni C. B. ; Paleari A. J. Solid State Chem. 1997, 128, 80. doi: 10.1006/jssc.1996.7158
82	Stoyanova R. ; Gorova M. ; Zhecheva E. J. Phys. Chem. Solids 2000, 61, 609. doi: 10.1016/S0022-3697(99)00244-9
83	Sathiya M. ; Rousse. G. ; Ramesha K. ; Laisa C. P. ; Vezin H. ; Sougrati M. T. ; Doublet M. L. ; Foix D. ; Gonbeau D. ; Walker W. ; et al Nat. Mater. 2013, 12, 827. doi: 10.1038/nmat3699
84	Liao Y. ; Li C. ; Lou X. ; Hu X. ; Ning Y. ; Yuan F. ; Chen B. ; Shen M. ; Hu B. Electrochimica Acta 2018, 271, 608. doi: 10.1016/j.electacta.2018.03.100
85	Li C. ; Lou X. ; Shen M. ; Hu X. ; Yan W. ; Zou Y. ; Tong W. ; Hu B. Energy Storage Materials 2017, 7, 195. doi: 10.1016/j.ensm.2017.02.002
86	Li C. ; Lou X. ; Yang Q. ; Zou Y. ; Hu B. Chem. Eng. J. 2017, 326, 10008. doi: 10.1016/j.cej.2017.06.048
87	Ning Y. ; Lou X. ; Li C. ; Hu X. ; Hu B. Chem. -Euro. J. 2017, 23, 15984. doi: 10.1002/chem.201703077
88	Hendrich M. P. ; Debrunner P. G. Biophys. J. 1989, 56, 489. doi: 10.1016/S0006-3495(89)82696-7
89	Petasis D. T. ; Hendrich M. P. Methods in Enzymology 2015, 563, 171. doi: 10.1016/bs.mie.2015.06.025
90	Chevallier F. ; Letellier M. ; Morcrette M. ; Tarascon J. M. ; Frackowiak E. ; Rouzaud J. N. ; Bexguin F. Electrochem. Solid-State Lett. 2003, 6, A225. doi: 10.1149/1.1612011
91	Poli F. ; Wong A. ; Kshetrimayum J. S. ; Monconduit L. ; Letellier M. Chem. Mater. 2016, 28, 1787. doi: 10.1021/acs.chemmater.5b04802
92	Shimoda K. ; Murakami M. ; Komatsu H. ; Arai H. ; Uchimoto Y. ; Ogumi Z. J. Phys. Chem. C 2015, 119, 13472. doi: 10.1021/acs.jpcc.5b03273
93	Jung H. ; Allan P. K. ; Hu Y. Y. ; Borkiewicz O. J. ; Wang X. L. ; Han W. Q. ; Du L. S. ; Pickard C. J. ; Chupas P. J. ; Chapman K. W. ; et al Chem. Mater. 2015, 27, 1031. doi: 10.1021/cm504312x
94	Bayley P. M. ; Trease N. M. ; Grey C. P. J. Am. Chem. Soc. 2016, 138, 1955. doi: 10.1021/jacs.5b12423
95	Feng X. ; Tang M. ; O'Neill S. ; Hu Y. Y. J. Mater. Chem. A 2018, 6, 22240. doi: 10.1039/c8ta05433a
96	Letellier M. ; Chevallier F. ; Béguin F. J. Phys. Chem. Solids 2006, 67, 1228. doi: 10.1016/j.jpcs.2006.01.088
97	Liu Z. ; Hu Y. Y. ; Dunstan M. T. ; Huo H. ; Hao X. ; Zou H. ; Zhong G. ; Yang Y. ; Grey C. P. Chem. Mater. 2014, 26, 2513. doi: 10.1021/cm403728w
98	Salager E. ; Kanian V. S. ; Sathiya M. ; Tang M. ; Leiche J. B. ; Melin P. ; Wang Z. ; Vezin H. ; Bessada C. ; Deschamps M. ; et al Chem. Mater. 2014, 26, 7009. doi: 10.1021/cm503280s
99	Shimoda K. ; Murakami M. ; Takamatsu D. ; Arai H. ; Uchimoto Y. ; Ogumi Z. Electrochim. Acta 2013, 108, 343. doi: 10.1016/j.electacta.2013.06.120
100	Stratford J. M. ; Allan P. K. ; Pecher O. ; Chater P. A. ; Grey C. P. Chem Commun 2016, 52, 12430. doi: 10.1039/c6cc06990h
101	Key B. ; Bhattacharyya R. ; Morcrette M. ; Seznéc V. ; Tarascon J. M. ; Grey C. P. J. Am. Chem. Soc. 2009, 131, 9239. doi: 10.1021/ja8086278
102	Zhou L. ; Leskes M. ; Liu T. ; Grey C. P. Angew. Chem. Int. Ed. 2015, 54, 14782. doi: 10.1002/anie.201507632
103	Poli F. ; Kshetrimayum J. S. ; Monconduit L. ; Letellier M. Electrochem. Commun. 2011, 13, 1293. doi: 10.1016/j.elecom.2011.07.019
104	Sathiya M. ; Leriche J. B. ; Salager E. ; Gourier D. ; Tarascon J. M. ; Vezin H. Nat. Commun. 2015, 6, 6276. doi: 10.1038/ncomms7276
105	Tang M. ; Dalzini A. ; Li X. ; Feng X. ; Chien P. H. ; Song L. ; Hu Y. Y. J. Phys. Chem. Lett. 2017, 8, 4009. doi: 10.1021/acs.jpclett.7b01425
106	Wandt J. ; Marino C. ; Gasteiger H. A. ; Jakes P. ; Eichel R. A. ; Granwehr J. Energy Environ. Sci. 2015, 8, 1358. doi: 10.1039/c4ee02730b
107	Wandt J. ; Jakes P. ; Granwehr J. ; Eichel R. A. ; Gasteiger H. A. Mater. Today 2018, 21, 231. doi: 10.1016/j.mattod.2017.11.001
108	Pines A. ; Gibby M. G. ; Waugh J. S. J. Chem. Phys. 1973, 59, 569. doi: 10.1063/1.1680061
109	Hartmann S. R. ; Hahn E. L. Phys. Rev. 1962, 128, 2042. doi: 10.1103/PhysRev.128.2042
110	Lesage A. ; Emsley L. J. Magn. Reson. 2001, 148, 449. doi: 10.1006/jmre.2000.2249
111	Wang Q. ; Trébosc J. ; Li Y. ; Xu J. ; Hu B. ; Feng N. ; Chen Q. ; Lafon O. ; Amoureux J. P. ; Deng F. Chem. Commun. 2013, 49, 6653. doi: 10.1039/C3CC42961J
112	Trebosc J. ; Hu B. ; Amoureux J. P. ; Gan Z. J. Magn. Reson. 2007, 186, 220. doi: 10.1016/j.jmr.2007.02.015
113	Gan Z. J. Magn. Reson. 2007, 184, 39. doi: 10.1016/j.jmr.2006.09.016
114	Hu B. ; Trébosc J. ; Amoureux J. P. J. Magn. Reson. 2008, 192, 112. doi: 10.1016/j.jmr.2008.02.004
115	Cavadini S. ; Lupulescu A. ; Antonijevic S. ; Bodenhausen G. J. Am. Chem. Soc. 2006, 128, 7706. doi: 10.1021/ja0618898
116	Peng B. ; Yao Y. ; Chen Q. ; Hu B. Annual Rep. NMR Spectros. 2014, 85, 1. doi: 10.1016/bs.arnmr.2014.12.002
117	Lee H. H. ; Park Y. ; Shin K. H. ; Lee K. T. ; Hong S. Y. ACS Appl. Mater. Interfaces 2014, 6, 19118. doi: 10.1021/am505090p
118	Peng C. ; Ning G. H. ; Su J. ; Zhong G. ; Tang W. ; Tian B. ; Su C. ; Yu D. ; Zu L. ; Yang J. ; et al Nat. Energy 2017, 2, 17074. doi: 10.1038/nenergy.2017.74
119	Griffith K. J. ; Wiaderek K. M. ; Cibin G. ; Marbella L. E. ; Grey C. P. Nature 2018, 559, 556. doi: 10.1038/s41586-018-0347-0
120	Xiang Y. X. ; Zheng G. ; Zhong G. ; Wang D. ; Fu R. ; Yang Y. Solid State Ionics 2018, 318, 19. doi: 10.1016/j.ssi.2017.11.025
121	Engelke S. ; Marbella L. E. ; Trease N. M. ; De Volder M. ; Grey C. P. Phys. Chem. Chem. Phys. 2019, 21, 4538. doi: 10.1039/c8cp07776b
122	Prutsch D. ; Gadermaier B. ; Brandstätter H. ; Pregartner V. ; Stanje B. ; Wohlmuth D. ; Epp V. ; Rettenwander D. ; Hanzu I. ; Wilkening H. M. R. Chem. Mater. 2018, 30, 7575. doi: 10.1021/acs.chemmater.8b02753
123	Liang X. ; Wang L. ; Jiang Y. ; Wang J. ; Luo H. ; Liu C. ; Feng J. Chem. Mater. 2015, 27, 5503. doi: 10.1021/acs.chemmater.5b01384
124	Kuhn A. ; Sreeraj P. ; Pottgen R. ; Wiemhofer H. D. ; Wilkening M. ; Heitjans P. J. Am. Chem. Soc. 2011, 133, 11018. doi: 10.1021/ja2020108
125	Wilkening M. ; Heitjans P. ChemPhysChem 2012, 13, 53. doi: 10.1002/cphc.201100580
126	Pigliapochi R. ; Seymour I. D. ; Merlet C. ; Pell A. J. ; Murphy D. T. ; Schmid S. ; Grey C. P. Chem. Mater. 2018, 30, 817. doi: 10.1021/acs.chemmater.7b04314
127	Middlemiss D. S. ; Ilott A. J. ; Clément R. l. J. ; Strobridge F. C. ; Grey C. P. Chem. Mater. 2013, 25, 1723. doi: 10.1021/cm400201t
128	Castets A. ; Carlier D. ; Zhang Y. ; Boucher F. ; Ménétrier M. J. Phys. Chem. C 2012, 116, 18002. doi: 10.1021/jp302549s
129	Liu Y. ; Zeng L. ; Xu C. ; Geng F. ; Shen M. ; Yuan Q. ; Hu B. Chem. Phys. Lett. 2019, 736, 136779. doi: 10.1016/j.cplett.2019.136779
130	Liu Z. ; Lee J. ; Xiang G. ; Glass H. F. J. ; Keyzer E. N. ; Dutton S. E. ; Grey C. P. Chem. Commun. 2017, 53, 743. doi: 10.1039/C6CC08430C
131	Lee J. ; Seymour I. D. ; Pell A. J. ; Dutton S. E. ; Grey C. P. Phys. Chem. Chem. Phys. 2017, 19, 613. doi: 10.1039/C6CP06338A
132	Canepa P. ; Bo S. H. ; Sai Gautam G. ; Key B. ; Richards W. D. ; Shi T. ; Tian Y. ; Wang Y. ; Li J. ; Ceder G. Nat. Commun. 2017, 8, 1759. doi: 10.1038/s41467-017-01772-1
133	Leroy C. ; Bryce D. L. Prog. Nucl. Magn. Reson. Spectrosc. 2018, 109, 160. doi: 10.1016/j.pnmrs.2018.08.002
134	Leskes M. ; Kim G. ; Liu T. ; Michan A. L. ; Aussenac F. ; Dorffer P. ; Paul S. ; Grey C. P. J. Phys. Chem. Lett. 2017, 8, 1078. doi: 10.1021/acs.jpclett.6b02590
135	Chakrabarty T. ; Goldin N. ; Feintuch A. ; Houben L. ; Leskes M. ChemPhysChem 2018, 19, 2139. doi: 10.1002/cphc.201800462
136	Wolf T. ; Kumar S. ; Singh H. ; Chakrabarty T. ; Aussenac F. ; Frenkel A. I. ; Major D. T. ; Leskes M. J. Am. Chem. Soc. 2018, 141, 451. doi: 10.1021/jacs.8b11015

[1]	Huifang An,Li Jiang,Feng Li,Ping Wu,Xiaoshu Zhu,Shaohua Wei,Yiming Zhou. Hydrogel-Derived Three-Dimensional Porous Si-CNT@G Nanocomposite with High-Performance Lithium Storage [J]. Acta Physico-Chimica Sinica, 2020, 36(7): 1905034-0.
[2]	Laiqiang Xu,Jiayang Li,Cheng Liu,Guoqiang Zou,Hongshuai Hou,Xiaobo Ji. Research Progress in Inorganic Solid-State Electrolytes for Sodium-Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1905013-0.
[3]	Haixia Li,Jiwei Wang,Lifang Jiao,Zhanliang Tao,Jing Liang. Spherical Nano-SnSb/C Composite as a High-Performance Anode Material for Sodium Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1904017-0.
[4]	Guifang Zeng,Yining Liu,Chunyan Gu,Kai Zhang,Yongling An,Chuanliang Wei,Jinkui Feng,Jiangfeng Ni. A Nonflammable Fluorinated Carbonate Electrolyte for Sodium-Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1905006-0.
[5]	Wenli Pan,Wenhao Guan,Yinzhu Jiang. Research Advances in Polyanion-Type Cathodes for Sodium-Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1905017-0.
[6]	Jing Deng,Tao Ma,Ziwei Chang,Weijing Zhao,Jun Yang. Determination of Three-Dimensional Structures of Protein Assemblies via Solid-State NMR [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905019-0.
[7]	Yuhong Li,Xin-Ping Wu,Cong Liu,Meng Wang,Benteng Song,Guiyun Yu,Gang Yang,Wenhua Hou,Xue-Qing Gong,Luming Peng. NMR and EPR Studies of Partially Reduced TiO₂ [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905021-0.
[8]	Fenfen Wang,Peng Wang,Hongyao Niu,Yingfeng Yu,Pingchuan Sun. Solid-State NMR Studies on Hydrogen Bonding Interactions and Structural Evolution in PAA/PEO Blends [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1912016-0.
[9]	Shihan Li,Zhenchao Zhao,Shikun Li,Youdong Xing,Weiping Zhang. Aluminum Distribution and Brønsted Acidity of Al-Rich SSZ-13 Zeolite: A Combined DFT Calculation and Solid-State NMR Study [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1903021-0.
[10]	Yi Ji,Lixin Liang,Changmiao Guo,Xinhe Bao,Tatyana Polenova,Guangjin Hou. Zero-Quantum Homonuclear Recoupling Symmetry Sequences in Solid-State Fast MAS NMR Spectroscopy [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905029-0.
[11]	Xiaolong Liu,Qiang Wang,Chao Wang,Jun Xu,Feng Deng. Hydrogen-Bond Induced Crystallization of Silicalite-1 Zeolite as Revealed by Solid-State NMR Spectroscopy [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905035-0.
[12]	Yongchao Shi,Mingxue Tang. NMR/EPR Investigation of Rechargeable Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905004-0.
[13]	Hui LI,Shuangyu LIU,Huiming WANG,Bo WANG,Peng SHENG,Li XU,Guangyao ZHAO,Huitao BAI,Xin CHEN,Yuliang CAO,Zhongxue CHEN. Improved Sodium Storage Performance of Na_0.44MnO₂ Cathode at a High Temperature by Al₂O₃ Coating [J]. Acta Physico-Chimica Sinica, 2019, 35(12): 1357-1364.
[14]	Lei. HE,Jun-Min. XU,Yong-Jian. WANG,Chang-Jin. ZHANG. LiFePO₄-Coated Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ as Cathode Materials with High Coulombic Efficiency and Improved Cyclability for Li-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1605-1613.
[15]	Ai-Hua TIAN,Wei WEI,Peng QU,Qiu-Ping XIA,Qi SHEN. One-Step Synthesis of SnS₂ Nanoflower/Graphene Nanocomposites with Enhanced Lithium Ion Storage Performance [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1621-1627.

Solid-State NMR and EPR Methods for Metal Ion Battery Research

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 136

Related Articles 15

Metrics

Comments

Recommended 10