拉曼光谱在燃料电池领域的应用

doi:10.3866/PKU.WHXB202004052

Abstract

Abstract:

Recently, the problems of environmental pollution and energy shortages arise along with the rapid development of the economy, and gradually becoming significant challenges faced by society. To realize truly sustainable development, novel environment-friendly clean energy technologies need to be developed. The fuel cell is a chemical device that can directly convert the chemical energy of a fuel and an oxidant into electrical energy via an electrochemical reaction. The electrochemical reaction is usually clean and complete, and rarely produces harmful substances. Therefore, fuel cells are considered to be one of the most promising clean energy technologies. Fuel cells can be classified based on their electrolytes: alkaline fuel cells (AFC), phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), and proton exchange membrane fuel cells (PEMFC). Although there have been many studies regarding the materials and reactions of fuel cells, direct spectroscopic evidence to understand the reaction mechanisms in the electrodes is lacking. Raman spectroscopy, as a non-destructive molecular spectroscopy technique with ultra-high sensitivity, is suitable for studying fuel cell materials. Over the past decade, the development of surface-enhanced Raman spectroscopy (SERS) and shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) has overcome the material and morphology limitations of traditional Raman spectroscopy. The extraordinary progress in SHINERS has enabled researchers to acquire high-quality Raman spectra for many types of materials instead of only on the surface of noble metals such as Au, Ag, and Cu. This strategy can also be applied to trace intermediate reactants on electrodes to fully understand the reaction mechanism of the fuel cell. Although many kinds of characterization methods including X-ray absorption spectroscopy (XAS), X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy (AES), low-energy electron diffraction (LEED), scanning tunneling microscopy (STM), and X-ray diffraction (XRD) also exhibit excellent sensitivity for studying electrode reactions, they require material pretreatments and long-duration experiments. Compared with the abovementioned methods, SERS and SHINERS show better performance for in situ experiments, which will aid in the rational design of catalysts and electrode materials with higher efficiency. This article provides an overview of the basic concepts of fuel cells, as well as SERS and SHINERS. In addition, the application of Raman spectroscopy, SERS, and SHINERS in fuel cell development is discussed along with future prospects.

Key words: Fuel cell, Raman spectroscopy, Surface enhanced Raman spectroscopy, Shell-isolated nanoparticle enhanced Raman spectroscopy

MSC2000:

O646

Yue-Jiao Zhang, Yue-Zhou Zhu, Jian-Feng Li. Application of Raman Spectroscopy in Fuel Cell[J].Acta Phys. -Chim. Sin., 2021, 37(9): 2004052.

Figures/Tables 5

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References 52

1	Wilberforce T. ; El-Hassan Z. ; Khatib F. N. ; Al Makky A. ; Baroutaji A. ; Carton J. G. ; Olabi A. G. Int. J. Hydrogen Energy 2017, 42, 25695. doi: 10.1016/j.ijhydene.2017.07.054
2	Wilberforce T. ; Alaswad A. ; Palumbo A. ; Dassisti M. ; Olabi A. G. Int. J. Hydrogen Energy 2016, 41, 16509. doi: 10.1016/j.ijhydene.2016.02.057
3	Alaswad A. ; Baroutaji A. ; Achour H. ; Carton J. ; Al Makky A. ; Olabi A. G. Int. J. Hydrogen Energy 2016, 41, 16499. doi: 10.1016/j.ijhydene.2016.03.164
4	Majlan E. H. ; Rohendi D. ; Daud W. R. W. ; Husaini T. ; Haque M. A. Renew. Sust. Energy Rev. 2018, 89, 117. doi: 10.1016/j.rser.2018.03.007
5	Brandon N. P. ; Skinner S. ; Steele B. C. H. Ann. Rev. Mater. Res. 2003, 33, 183. doi: 10.1146/annurev.matsci.33.022802.094122
6	Sung S. S. ; Hoffmann R. J. Am. Chem. Soc. 1985, 107, 578. doi: 10.1021/ja00289a009
7	Anderson A. B. Electrochim. Acta 2002, 47, 3759. doi: 10.1016/S0013-4686(02)00346-8
8	Damjanovic A. ; Dey A. ; Bockris J. O. M. Electrochim. Acta 1966, 11, 791. doi: 10.1016/0013-4686(66)87056-1
9	Damjanovic A. ; Brusic V. Electrochim. Acta 1967, 12, 615. doi: 10.1016/0013-4686(67)85030-8
10	Wei C. ; Rao R. R. ; Peng J. ; Huang B. ; Stephens I. E. L. ; Risch M. ; Xu Z. J. ; Shao-Horn Y. Adv. Mater. 2019, 31, 1806296. doi: 10.1002/adma.201806296
11	Wang X. X. ; Swihart M. T. ; Wu G. Nat. Catal. 2019, 2, 578. doi: 10.1038/s41929-019-0304-9
12	Luo M. C. ; Sun Y. J. ; Qin Y. N. ; Yang Y. ; Wu D. ; Guo S. J. Acta Phys. -Chim. Sin. 2018, 34, 361.
	骆明川; 孙英俊; 秦英楠; 杨勇; 吴冬; 郭少军. 物理化学学报, 2018, 34, 361. doi: 10.3866/PKU.WHXB201708312
13	Chang Q. W. ; Xiao F. ; Xu Y. ; Shao M. H. Acta Phys. -Chim. Sin. 2017, 33, 9.
	常乔婉; 肖菲; 徐源; 邵敏华. 物理化学学报, 2017, 33, 9. doi: 10.3866/PKU.WHXB201609202
14	Itoh T. ; Abe K. ; Dokko K. ; Mohamedi M. ; Uchida I. ; Kasuya A. J. Electrochem. Soc. 2004, 151, A2042. doi: 10.1149/1.1812735
15	Itoh T. ; Maeda T. ; Kasuya A. Faraday Discuss. 2006, 132, 95. doi: 10.1039/b506197k
16	Pomfret M. B. ; Owrutsky J. C. ; Walker R. A. Annu. Rev. Anal. Chem. 2010, 3, 151. doi: 10.1146/annurev.anchem.111808.073641
17	Maher R. C. ; Duboviks V. ; Offer G. J. ; Kishimoto M. ; Brandon N. P. ; Cohen L. F. Fuel Cells 2013, 13, 455. doi: 10.1002/fuce.201200173
18	Dong J. C. ; Zhang X. G. ; Briega-Martos V. ; Jin X. ; Yang J. ; Chen S. ; Yang Z. L. ; Wu D. Y. ; Feliu J. M. ; Williams C. T. ; et al Nat. Energy 2018, 4, 60. doi: 10.1038/s41560-018-0292-z
19	Wang Y. H. ; Le J. B. ; Li W. Q. ; Wei J. ; Radjenovic P. M. ; Zhang H. ; Zhou X. S. ; Cheng J. ; Tian Z. Q. ; Li J. F. Angew. Chem. Int. Ed. 2019, 58, 16062. doi: 10.1002/anie.201908907
20	Jeanmaire D. L. ; Van Duyne R. P. J. Electroanal. Chem. 1977, 84, 1. doi: 10.1016/S0022-0728(77)80224-6
21	Lane L. A. ; Qian X. M. ; Nie S. M. Chem. Rev. 2015, 115, 10489. doi: 10.1021/acs.chemrev.5b00265
22	Li J. F. ; Zhang Y. J. ; Ding S. Y. ; Panneerselvam R. ; Tian Z. Q. Chem. Rev. 2017, 117, 5002. doi: 10.1021/acs.chemrev.6b00596
23	Nie S. ; Emory S. R. Science 1997, 275, 1102. doi: 10.1126/science.275.5303.1102
24	Xu H. X. ; Bjerneld E. J. ; Kall M. ; Borjesson L. Phys. Rev. Lett. 1999, 83, 4357. doi: 10.1103/PhysRevLett.83.4357
25	Tian, Z. Q.; Ren, B.; Li, J. F.; Yang, Z. L. Chem. Commun. 2007, 3514. doi: 10.1039/B616986D
26	Li J. F. ; Huang Y. F. ; Ding Y. ; Yang Z. L. ; Li S. B. ; Zhou X. S. ; Fan F. R. ; Zhang W. ; Zhou Z. Y. ; Wu D. Y. ; et al Nature 2010, 464, 392. doi: 10.1038/nature08907
27	Li J. F. ; Tian X. D. ; Li S. B. ; Anema J. R. ; Yang Z. L. ; Ding Y. ; Wu Y. F. ; Zeng Y. M. ; Chen Q. Z. ; Ren B. ; et al Nat. Protoc. 2013, 8, 52. doi: 10.1038/nprot.2012.141
28	Zhang, H.; Duan, S.; Radjenovic, P. M.; Tian, Z. Q.; Li, J. F. Acc. Chem. Res. 2020, doi: 10.1021/acs.accounts.9b00545
29	Wei, J.; Qin, S. N.; Liu, J. L.; Ruan, X. Y.; Guan, Z.; Yan, H.; Wei, D. Y.; Zhang, H.; Cheng, J.; Xu, H.; et al. Angew. Chem. Int. Ed. 2020, doi: 10.1002/anie.202000426
30	Li C. Y. ; Le J. B. ; Wang Y. H. ; Chen S. ; Yang Z. L. ; Li J. F. ; Cheng J. ; Tian Z. Q. Nat. Mater. 2019, 18, 697. doi: 10.1038/s41563-019-0356-x
31	Wang C. ; Chen X. ; Chen T. M. ; Wei J. ; Qin S. N. ; Zheng J. F. ; Zhang H. ; Tian Z. Q. ; Li J. F. ChemCatChem 2020, 12, 75. doi: 10.1002/cctc.201901747
32	Wang Y. H. ; Wei J. ; Radjenovic P. ; Tian Z. Q. ; Li J. F. Anal. Chem. 2019, 91, 1675. doi: 10.1021/acs.analchem.8b05499
33	Jiang S. P. Int. J. Hydrogen Energy 2019, 44, 7448. doi: 10.1016/j.ijhydene.2019.01.212
34	Fan L. ; Zhu B. ; Su P.C. ; He C. Nano Energy 2018, 45, 148. doi: 10.1016/j.nanoen.2017.12.044
35	Abdalla A. M. ; Hossain S. ; Azad A. T. ; Petra P. M. I. ; Begum F. ; Eriksson S. G. ; Azad A. K. Renew. Sust. Energy Rev. 2018, 82, 353. doi: 10.1016/j.rser.2017.09.046
36	Hossain S. ; Abdalla A. M. ; Jamain S. N. B. ; Zaini J. H. ; Azad A. K. Renew. Sust. Energy Rev. 2017, 79, 750. doi: 10.1016/j.rser.2017.05.147
37	da Silva F. S. ; de Souza T. M. Int. J. Hydrogen Energy 2017, 42, 26020. doi: 10.1016/j.ijhydene.2017.08.105
38	Gorte R. J. ; Vohs J. M. Annu. Rev. Chem. Biomol. 2011, 2, 9. doi: 10.1146/annurev-chembioeng-061010-114148
39	Shaikh S. P. S. ; Muchtar A. ; Somalu M. R. Renew. Sust. Energy Rev. 2015, 51, 1. doi: 10.1016/j.rser.2015.05.069
40	Connor P. A. ; Yue X. ; Savaniu C. D. ; Price R. ; Triantafyllou G. ; Cassidy M. ; Kerherve G. ; Payne D. J. ; Maher R. C. ; Cohen L. F. ; et al Adv. Energy Mater. 2018, 8, 1800120. doi: 10.1002/aenm.201800120
41	Rosli R. E. ; Sulong A. B. ; Daud W. R. W. ; Zulkifley M. A. ; Husaini T. ; Rosli M. I. ; Majlan E. H. ; Haque M. A. Int. J. Hydrogen Energy 2017, 42, 9293. doi: 10.1016/j.ijhydene.2016.06.211
42	Araya S. S. ; Zhou F. ; Liso V. ; Sahlin S. L. ; Vang J. R. ; Thomas S. ; Gao X. ; Jeppesen C. ; Kær S. K. Int. J. Hydrogen Energy 2016, 41, 21310. doi: 10.1016/j.ijhydene.2016.09.024
43	Zhang J. ; Xie Z. ; Zhang J. ; Tang Y. ; Song C. ; Navessin T. ; Shi Z. ; Song D. ; Wang H. ; Wilkinson D. P. ; et al J. Power Sources 2006, 160, 872. doi: 10.1016/j.jpowsour.2006.05.034
44	Zeis R. Beilstein J. Nanotech. 2015, 6, 68. doi: 10.3762/bjnano.6.8
45	Mack F. ; Heissler S. ; Laukenmann R. ; Zeis R. J. Power Sources 2014, 270, 627. doi: 10.1016/j.jpowsour.2014.06.171
46	Daletou M. K. ; Geormezi M. ; Vogli E. ; Voyiatzis G. A. ; Neophytides S. G. J. Mater. Chem. A 2014, 2, 1117. doi: 10.1039/C3TA13335D
47	Li X. ; Lee J. P. ; Blinn K. S. ; Chen D. ; Yoo S. ; Kang B. ; Bottomley L. A. ; El-Sayed M. A. ; Park S. ; Liu M. Energy Environ. Sci. 2014, 7, 306. doi: 10.1039/c3ee42462f
48	Li X. ; Blinn K. ; Chen D. ; Liu M. Electro. Energy Rev. 2018, 1, 433. doi: 10.1007/s41918-018-0017-9
49	Chen X. ; Liang M. M. ; Xu J. ; Sun H. L. ; Wang C. ; Wei J. ; Zhang H. ; Yang W. M. ; Yang Z. L. ; Sun J. J. ; et al Nanoscale 2020, 12, 5341. doi: 10.1039/C9NR10304J
50	Gómez-Marín A. M. ; Feliu J. M. ChemSusChem 2013, 6, 1091. doi: 10.1002/cssc.201200847
51	Briega-Martos V. ; Herrero E. ; Feliu J. M. Electrochim. Acta 2017, 241, 497. doi: 10.1016/j.electacta.2017.04.162
52	Dong J. C. ; Su M. ; Briega-Martos V. ; Li L. ; Le J. B. ; Radjenovic P. ; Zhou X. S. ; Feliu J. M. ; Tian Z. Q. ; Li J. F. J. Am. Chem. Soc. 2020, 142, 715. doi: 10.1021/jacs.9b12803

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Application of Raman Spectroscopy in Fuel Cell

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