卤化钙钛矿太阳能电池的缺陷容忍及缺陷钝化研究进展

doi:10.3866/PKU.WHXB202008048

Abstract

Abstract:

In less than a decade, metal halide perovskites (MHPs) have been demonstrated as promising solar cell materials because the photoelectric conversion efficiency (PCE) of the representative material CH₃NH₃PbI₃ rapidly increased from 3.8% in 2009 to 25.2% in 2009. However, defects play crucial roles in the rapid development of perovskite solar cells (PSCs) because they can influence the photovoltaic parameters of PSCs, such as the open circuit voltage, short-circuit current density, fill factor, and PCE. Among a series of superior optoelectronic properties, defect tolerance, i.e., the dominate defects are shallow and do not act as strong nonradiative recombination centers, is considered to be a unique property of MHPs, which is responsible for its surprisingly high PCE. Currently, the growth of PCE has gradually slowed, which is due to low concentrations of deep detrimental defects that can influence the performances of PSCs. To further improve the PCE and stability of PSCs, it is necessary to eliminate the impact of these minor detrimental defects in perovskites, including point defects, grain boundaries (GBs), surfaces, and interfaces, because nonradiative recombination centers seriously affect device performance, such as carrier generation and transport. Owing to its defect tolerance, most intrinsic point defects, such as V_I and V_MA, form shallow level traps in CH₃NH₃PbI₃. The structural and electronic characteristics of the charged point defect V_I_- are similar to those of the unknown donor center in a tetrahedral semiconductor. It is a harmful defect caused by a large atomic displacement and can be passivated to strengthen chemical bonds and prevent atom migration by the addition of Br atoms. Owing to the ionic nature of MHPs and high ion migration speed, there are a large number of deep detrimental defects that can migrate to the interfaces under an electric field and influence the performance of PSCs. In addition, the ionic nature of MHPs results in surface/interface dangling bonds terminated with cations or anions; thus, deep defects can be passivated through Coulomb interactions between charged ions and passivators. Hence, the de-active deep-level traps resulting from charged defects can be passivated via coordinate bonding or ionic bonding. Usually, surface-terminated anions or cations can be passivated by corresponding cations or anions through ionic bonding, and Lewis acids or bases can be passivated through coordinated bonding. In this review, we not only briefly summarize recent research progress in defect tolerance, including the soft phonon mode and polaron effect, but also strategies for defect passivation, including ionic bonding with cations or anions and coordinated bonding with Lewis acids or bases.

Key words: Defect tolerance, Defect passivation, Perovskite, Solar cell, Photoelectric conversion efficiency

MSC2000:

O649

Yuan Yin, Zhendong Guo, Gaoyuan Chen, Huifeng Zhang, Wan-Jian Yin. Recent Progress in Defect Tolerance and Defect Passivation in Halide Perovskite Solar Cells[J].Acta Phys. -Chim. Sin., 2021, 37(4): 2008048.

Figures/Tables 7

References 88

1	Weber D. Z. Naturforsch. B 1978, 33b, 1443. doi: 10.1515/znb-1978-0809
2	Kojima A. ; Teshima K. ; Shirai Y. ; Miyasaka T. J. Am. Chem. Soc. 2009, 131, 6050. doi: 10.1021/ja809598r
3	www.nrel.gov/pv/assets/pdfs/. (accessed 2019
4	Li X. ; Bi D. ; Yi C. ; Decoppet J. D. ; Luo J. ; Zakeeruddin S. M. ; Hagfeldt A. ; Grätzel M. Science 2016, 353, 58. doi: 10.1126/science.aaf8060
5	Dong Q. ; Fang Y. ; Shao Y. ; Mulligan P. ; Qiu J. ; Cao L. ; Huang J. Science 2015, 347, 967. doi: 10.1126/science.aaa5760
6	Kulkarni A. ; Jena A. K. ; Chen H. W. ; Sanehira Y. ; Ikegami M. ; Miyasaka T. Solar Energy 2019, 136, 379. doi: 10.1016/j.solener.2016.07.019
7	Lim J. ; Hörantner M. T. ; Sakai N. ; Ball J. M. ; Mahesh S. ; Noel N. K. ; Lin Y. H. ; McMeekin D. P. ; Johnston M. B. ; Wenger B. ; Snaith H. J. Energy Environ. Sci. 2019, 12, 169. doi: 10.1039/c8ee03395a
8	Herz L. M. ACS Energy Lett. 2017, 2, 1539. doi: 10.1021/acsenergylett.7b00276
9	Wang T. ; Daiber B. ; Frost J. M. ; Mann S. A. ; Garnett E. C. ; Walsh A. ; Ehrler B. Energy Environ. Sci. 2017, 10, 509. doi: 10.1039/C6EE03474H
10	Bi D. ; Tress W. ; Dar M. I. ; Gao P. ; Hagfeldt A. Sci. Adv. 2016, 2, e1501170. doi: 10.1126/sciadv.1501170
11	Yin W. J. ; Shi T. ; Yan Y. Appl. Phys. Lett. 2014, 104, 063903. doi: 10.1063/1.4864778
12	Li Z. ; Klein T. R. ; Kim D. H. ; Yang M. ; Berry J. J. ; van Hest M. F. A. M. ; Zhu K. Nat. Rev. Mater. 2018, 3, 18017. doi: 10.1038/natrevmats.2018.17
13	Rong Y. ; Hu Y. ; Mei A. ; Tan H. ; Saidaminov M. I. ; Seok S. I. ; McGehee M. D. ; Sargent E. H. ; Han H. Science 2018, 361, eaat8235. doi: 10.1126/science.aat8235
14	Li Z. ; Zhao Y. ; Xi W. ; Sun Y. ; Zhao Z. ; Li Y. ; Zhou H. ; Qi C. Joule 2018, 2, 1559. doi: 10.1016/j.joule.2018.05.001
15	Seok S. I. ; Grätzel M. ; Park N. G. Small 2018, 14, 1704177. doi: 10.1002/smll.201704177
16	Pazos Outón L. M. ; Xiao T. P. ; Yablonovitch E. J. Phys. Chem. Lett. 2018, 9, 1703. doi: 10.1021/acs.jpclett.7b03054
17	Albrecht S. ; Michael S. ; Correa B. J. P. ; Felix L. ; Lukas K. ; Mathias M. ; Ludmilla S. ; Antonio A. ; Jorg R. ; Lars K. ; et al Energy Environ. Sci. 2016, 9, 81. doi: 10.1039/c5ee02965a
18	Jérémie W. ; Arnaud W. ; Esteban R. ; Soo-Jin M. ; Davide S. ; Michael R. ; Robby P. ; Rolf B. ; Xavier N. ; De W.S. ; et al Appl. Phys. Lett. 2016, 109, 233902. doi: 10.1063/1.4971361
19	Sahli F. ; Werner J. ; Kamino B. A. ; Braeuninger M. ; Monnard R. ; Paviet-Salomon B. ; Barraud L. ; Ding L. ; Leon J. J. D. ; Sacchetto D. Nat. Mater. 2018, 17, 820. doi: 10.1038/s41563-018-0115-4
20	Tress W. ; Marinova N. ; Inganas O. ; Nazeeruddin M. K. ; Zakeeruddin S. M. ; Grätzel M. Adv. Energy Mater. 2015, 5, 1400812. doi: 10.1002/aenm.201400812
21	Agiorgousis M. L. ; Sun Y. Y. ; Zeng H. ; Zhang S. J. Am. Chem. Soc. 2014, 136, 14570. doi: 10.1021/ja5079305
22	Kim J. ; Lee S. H. ; Lee J. H. ; Hong K. H. J. Phys. Chem. Lett. 2014, 5, 1312. doi: 10.1021/jz500370k
23	Agiorgousis M. L. ; Sun Y. ; Zeng H. ; Zhang S. J. Am. Chem. Soc. 2014, 136, 14570. doi: 10.1021/ja5079305
24	Walsh A. ; Scanlon D. O. ; Chen S. ; Gong X. G. ; Wei S. H. Angew. Chem. Int. Ed. 2015, 54, 1791. doi: 10.1002/anie.201409740
25	Eames C. ; Frost J. M. ; Barnes P. R. F. ; Regan B. C. O. ; Walsh A. ; Islam M. S. Nat. Commun. 2015, 6, 7497. doi: 10.1038/ncomms8497
26	Buin A. ; Pietsch P. ; Xu J. ; Voznyy O. ; Ip A. H. ; Comin R. ; Sargent E. H. Nano Lett. 2014, 14, 6281. doi: 10.1021/nl502612m
27	Xu J. ; Buin A. ; Ip A. H. ; Li W. ; Voznyy O. ; Comin R. ; Yuan M. ; Jeon S. ; Ning Z. ; McDowell J.J. ; et al Nat. Commun. 2015, 6, 7081. doi: 10.1038/ncomms8081
28	Buin A. ; Comin R. ; Xu J. ; Ip A. H. ; Sargent E. H. Chem. Mater. 2015, 27, 4405. doi: 10.1038/ncomms8081
29	Steirer K. X. ; Schulz P. ; Teeter G. ; Stevanovic V. ; Yang M. ; Zhu K. ; Berry J. J. ACS Energy Lett. 2016, 1, 360. doi: 10.1021/acsenergylett.6b00196
30	Domanski K. ; Correa-Baena J. P. ; Mine N. ; Nazeeruddin M. K. ; Abate A. ; Saliba M. ; Tress W. ; Hagfeldt A. ; Grätzel M. ACS Nano 2016, 10, 6306. doi: 10.1021/acsnano.6b02613
31	Wu X. ; Trinh M. T. ; Niesner D. ; Zhu H. ; Norman Z. ; Owen J. S. ; Yaffe O. ; Kudisch B. J. ; Zhu X. Y. J. Am. Chem. Soc. 2015, 137, 2089. doi: 10.1021/ja512833n
32	Long R. ; Liu J. ; Prezhdo O. V. J. Am. Chem. Soc. 2016, 138, 3884. doi: 10.1021/jacs.6b00645
33	Tress W. ; Marinova N. ; Moehl T. ; Zakeeruddin S. M. ; Nazeeruddin M. K. ; Grätzel M. Energy Environ. Sci. 2015, 8, 995. doi: 10.1039/c4ee03664f
34	Chen B. ; Yang M. ; Priya S. ; Zhu K. J. Phys. Chem. Lett. 2016, 7, 905. doi: 10.1021/acs.jpclett.6b00215
35	Azpiroz J. M. ; Mosconi E. ; Bisquert J. ; Angelis F. D. Energy Environ. Sci. 2015, 8, 2118. doi: 10.1039/c5ee01265a
36	Yuan Y. ; Huang J. Acc. Chem. Res. 2016, 49, 286. doi: 10.1021/acs.accounts.5b00420
37	Stranks S. D. ACS Energy Lett. 2017, 2, 1515. doi: 10.17863/CAM.12818
38	Du M. H. J. Mater. Chem. A 2014, 2, 9091. doi: 10.1039/c4ta01198h
39	Brandt R. E. ; Stevanovic V. ; Ginley D. S. ; Buonassisi T. Mrs Commun. 2015, 5, 265. doi: 10.1557/mrc.2015.26
40	Walsh A. ; Zunger A. Nat. Mater. 2017, 16, 964. doi: 10.1038/nmat4973
41	Chu W. ; Zheng Q. ; Prezhdo O. V. ; Zhao J. ; Saidi W. A. Sci. Adv. 2020, 6, eaaw7453. doi: 10.1126/sciadv.aaw7453
42	Kim, S.; Walsh, A. Comment on "Low-frequency lattice phonons in halide perovskites explain high defect tolerance toward electron-hole recombination", arXiv: 2003.05394vl[cond-mat.mtrl-sci] 11 Mar 2020.
43	Miyata K. ; Meggiolaro D. ; Trinh M. T. ; Joshi P. P. ; Mosconi E. ; Jones S. C. ; Angelis F. D. ; Zhu X. Y. Sci. Adv. 2017, 3, e1701217. doi: 10.1126/sciadv.1701217
44	Neukirch A. J. ; Nie W. ; Blancon J. C. ; Appavoo K. ; Tsai H. ; Sfeir M. Y. ; Katan C. ; Pedesseau L. ; Even J. ; Crochet J.J. ; et al Nano Lett. 2016, 16, 3809. doi: 10.1021/acs.nanolett.6b01218
45	Ambrosio F. ; Wiktor J. ; Angelis F. D. ; Pasquarello A. Energy Environ. Sci. 2018, 11, 101. doi: 10.1039/c7ee01981e
46	Green M. A. ; Ho-Baillie A. ; Snaith H. J. Nature Photon. 2014, 8, 506. doi: 10.1038/nphoton.2014.134
47	Wang R. ; Xue J. J. ; Wang K. L. ; Wang Z. K. ; Luo Y. Q. ; Fenning D. ; Xu G. W. ; Nuryyeva S. ; Huang T. Y. ; Zhao Y.P. ; et al Science 2019, 366, 1509. doi: 10.1126/science.aay9698
48	Chen B. ; Rudd P. N. ; Yang S. ; Yuan Y. ; Huang J. Chem. Soc. Rev. 2019, 48, 3842. doi: 10.1039/C8CS00853A
49	Wu W. Q. ; Yang Z. ; Rudd P.N. ; Shao Y. ; Dai X. ; Wei H. ; Zhao J. ; Fang Y. ; Wang Q. ; Liu Y. ; et al Sci. Adv. 2019, 5, eaav8925. doi: 10.1126/sciadv.aav8925
50	Guo P. ; Ye Q. ; Yang X. ; Zhang J. ; Xu F. ; Shchukin D. ; Wei B. ; Wang H. J. Mater. Chem. A 2019, 7, 2497. doi: 10.1039/C8TA11524A
51	Li J. L. ; Yang J. ; Wu T. ; Wei S. H. J. Mater. Chem. C 2019, 7, 4230. doi: 10.1039/C8TC06222F
52	Klug M. T. ; Osherov A. ; Haghighirad A. A. ; Stranks S. D. ; Brown P. R. ; Bai S. ; Wang J. T. W. ; Dang X. ; Bulovic V. Energy Environ. Sci. 2017, 10, 236. doi: 10.1039/c6ee03201j
53	Ming W. ; Yang D. ; Li T. ; Zhang L. ; Du M. H. Adv. Sci. 2017, 5, 1700662. doi: 10.1002/advs.201700662
54	Wang J. ; Li W. ; Yin W. J. Adv. Mater. 2020, 32, 1906115. doi: 10.1002/adma.201906115
55	Wang R. ; Xue J. ; Wang K. L. ; Wang Z. K. ; Yang Y. Science 2019, 366, 1509. doi: 10.1126/science.aay9698
56	Ni Z. Y. ; Bao C. X. ; Liu Y. ; Jiang Q. ; Wu W. Q. ; Chen S. S. ; Dai X. Z. ; Chen B. ; Hartweg B. ; Yu Z. S. ; Holman Z. ; Huang J. S. Science 2020, 367, 1352. doi: 10.1126/science.aba0893
57	Son D. ; Kim S. ; Seo J. ; Lee S. ; Shin H. ; Lee D. ; Park N. J. Am. Chem. Soc. 2018, 140, 1358. doi: 10.1021/jacs.7b10430
58	Lin Y. ; Chen B. ; Fang Y. ; Zhao J. ; Bao C. ; Yu Z. ; Deng Y. ; Rudd P. N. ; Yan Y. ; Yuan Y. Nat. Commun. 2018, 9, 4981. doi: 10.1038/s41467-018-07438-w
59	Birkhold S. T. ; Precht J. T. ; Liu H. ; Giridharagopal R. ; Eperon G. E. ; Schmidt-Mende L. ; Li X. ; Ginger D. S. Acs Energy Lett. 2018, 3, 1279. doi: 10.1021/acsenergylett.8b00505
60	Gao F. ; Zhao Y. ; Zhang X. W. ; You J. B. Adv. Energy Mater. 2019, 1902650. doi: 10.1002/aenm.201902650
61	Abdi-Jalebi M. ; Andaji-Garmaroudi Z. ; Cacovich S. ; Stavrakas C. ; Philippe B. ; Richter J. M. ; Alsari M. ; Booker E. P. ; Hutter E. M. ; Pearson A. J. Nature 2018, 555, 497. doi: 10.1038/nature25989
62	Bi C. ; Zheng X. ; Chen B. ; Wei H. ; Huang J. ACS Energy Lett. 2017, 2, 1400. doi: 10.1021/acsenergylett.7b00356
63	Jung, M.; Shin, T. J.; Seo, J.; Kim, G.; Seok, S. I. Energy Environ. Sci. 2018, 11, 2188. doi: 10.1039.C8EE00995C
64	Fu Y. ; Wu T. ; Wang J. ; Zhai J. ; Shearer M. J. ; Zhao Y. ; Hamers R. J. ; Kan E. ; Deng K. ; Zhu X. Y. ; Jin S. Nano Lett. 2017, 17, 4405. doi: 10.1021/acs.nanolett.7b01500
65	Son D. Y. ; Lee J. W. ; Choi Y. J. ; Jang I. H. ; Lee S. ; Yoo P. J. ; Shin H. ; Ahn N. ; Choi M. ; Kim D. ; Park N. G. Nat. Energy 2016, 1, 16081. doi: 10.1080/01411599908224497
66	Shao Y. ; Xiao Z. ; Bi C. ; Yuan Y. ; Huang J. Nat. Commun. 2014, 5, 5784. doi: 10.1038/ncomms6784
67	Aberle A. G. Sol. Energy Mater. Sol. Cells 2001, 65, 239. doi: 10.1016/S0927-0248(00)00099-4
68	Grancini G. ; Roldán-Carmona C. ; Zimmermann I. ; Mosconi E. ; Lee X. ; Martineau D. ; Narbey S. ; Oswald F. ; De Angelis F. ; Grätzel M. Nat. Commun. 2017, 8, 15684. doi: 10.1038/ncomms15684
69	Lee D. S. ; Yun J. S. ; Kim J. ; Soufiani A. M. ; Chen S. ; Cho Y. ; Deng X. ; Seidel J. ; Lim S. ; Huang S. ACS Energy Lett. 2018, 3, 647.
70	Wang Z. ; Lin Q. ; Chmiel F. P. ; Sakai N. ; Herz L. M. ; Snaith H. J. Nat. Energy 2017, 6, 17135. doi: 10.1038/nenergy.2017.135
71	Lin Y. ; Bai Y. ; Fang Y. ; Chen Z. ; Yang S. ; Zheng X. ; Tang S. ; Liu Y. ; Zhao J. ; Hwang I. J. Phys. Chem. Lett. 2018, 9, 654. doi: 10.1021/acs.jpclett.7b02679
72	Jokar E. ; Chien C. H. ; Fathi A. ; Rameez M. ; Chang Y. H. ; Diau E. W. G. Energy Environ. Sci. 2018, 11, 2353. doi: 10.1039/C8EE00956B
73	Jiang Q. ; Zhao Y. ; Zhang X. ; Yang X. ; Chen Y. ; Chu Z. ; Ye Q. ; Li X. ; Yin Z. ; You J. Nat. Photonics 2019, 13, 460. doi: 10.1038/s41566-019-0398-2
74	Lee M. M. ; Teuscher J. ; Miyasaka T. ; Murakami T. N. ; Snaith H. J. Science 2012, 338, 643. doi: 10.1126/science.1228604
75	Li Q. ; Zhao Y. ; Fu R. ; Zhou W. ; Zhao Y. ; Liu X. ; Yu D. ; Zhao Q. Adv. Mater. 2018, 30, 1803095. doi: 10.1002/adma.201803095
76	Xie F. ; Chen C. C. ; Wu Y. ; Li X. ; Cai M. ; Liu X. ; Yang X. ; Han L. Energy Environ. Sci. 2017, 10, 1942. doi: 10.1039/C7EE01675A
77	Uribe J. I. ; Ciro J. ; Montoya J. F. ; Osorio J. ; Jaramillo F. ACS Appl. Energy Mater. 2018, 1, 1047. doi: 10.1021/acsaem.7b00194
78	Chen B. ; Yu Z. ; Liu K. ; Zheng X. ; Liu Y. ; Shi J. ; Spronk D. ; Rudd P. N. ; Holman Z. ; Huang J. Joule 2019, 3, 177. doi: 10.1016/j.joule.2018.10.003
79	Chen Q. ; Zhou H. ; Fang Y. ; Stieg A. Z. ; Song T. B. ; Wang H. H. ; Xu X. ; Liu Y. ; Lu S. ; You J. Nat. Commun. 2015, 6, 7269. doi: 10.1038/ncomms8269
80	Nan G. J. ; Zhang X. ; Abdi-Jalebi M. ; Andaji-Garmaroudi Z. ; Stranks S. D. ; Lu G. D. Beljonne. Adv. Energy Mater. 2018, 8, 1702754. doi: 10.1002/aenm.201702754
81	Li N. ; Tao S. ; Chen Y. ; Niu X. ; Zhou H. Nat. Energy 2019, 4, 408. doi: 10.1038/s41560-019-0382-6
82	Li X. ; Chen C. C. ; Cai M. ; Hua X. ; Xie F. ; Liu X. ; Hua J. ; Long Y. T. ; Tian H. ; Han L. Adv. Energy Mater. 2018, 8, 18007151. doi: 10.1002/aenm.201800715
83	Yang S. ; Dai J. ; Yu Z. H. ; Shao Y. C. ; Xun Z. J. Am. Chem. Soc. 2019, 141, 5781. doi: 10.1021/jacs.8b13091
84	Yin W. J. ; Wu Y. ; Wei S. H. ; Noufi R. ; Yan Y. Adv. Energy Mater. 2014, 4, 1. doi: 10.1002/aenm.201300712
85	Ke W. ; Xiao C. ; Wang C. ; Saparov B. ; Duan H. S. ; Zhao D. ; Xiao Z. ; Schulz P. ; Harvey S.P. ; Liao W. ; et al Adv. Mater. 2016, 28, 5214. doi: 10.1002/adma.201600594
86	Xu J. ; Buin A. ; Ip A. H. ; Li W. ; Voznyy O. ; Comin R. ; Yuan M. ; Jeon S. ; Ning Z. ; McDowell J.J. ; et al Nat. Commun. 2015, 6, 7081. doi: 10.1038/ncomms8081
87	Noel N. K. ; Abate A. ; Stranks S. D. ; Parrott E. S. ; Burlakov V. M. ; Goriely A. ; Snaith H. J. ACS Nano 2014, 8, 9815. doi: 10.1021/nn5036
88	Huang Y. ; Sun Q. D. ; Xu W. ; He Y. ; Yin W. J. Acta Phys. -Chim. Sin. 2017, 33, 1730.
	黄杨; 孙庆德; 徐文; 何垚; 尹万健. 物理化学学报, 2017, 33, 1730. doi: 10.3866/PKU.WHXB201705042

Passivators	Structures	Perovskite materials	Passivation functional groups	Target defects	V_OC	J_SC	FF	PCE	Ref.
Sodium chloride	NaCl	MAPbI₃	Na⁺	Anionic defects	23.5/24.4	1.05/1.06	0.76/0.78	18.8/20.2	60
Potassium iodide	KI	Cs_0.06FA_0.79MA_0.15Pb(I_0.85Br_0.15)₃	K⁺	Anionic defects	22.6/23.2	1.05/1.17	0.73/0.79	17.3/21.5	59
PEAI		MAPbI₃	PEA⁺	Anionic defects	19.8/18.6	0.99/1.08	0.70/0.73	13.6/14.9	61
BAI		MAPbI₃	Ammonium	Anionic defects	22.2/22.59	1.08/1.09	0.74/0.77	17.8/18.9	64
Octylammonium iodide		MAPbI₃	Ammonium	Anionic defects	21.8/22.6	1.06/1.11	0.79/0.82	18.4/20.6	65
Phenyl-C61-butyric acid methyl ester		MAPbI₃	Fullerene	PbI₃^- or V_I^-	12.7/20.3	0.98/0.98	0.59/0.75	7.3/14.9	81
C₆₀		MAPbI₃	Fullerene	PbI₃^- or V_I^-	18.4/19.6	1.04/1.07	0.72/0.69	13.6/14.5	83
Thiophene		MAPbI_3-xCl_x	Thiophene group	Pb²⁺	20.7/21.3	0.95/1.02	0.68/0.68	12.1/14.3	82
Pyridine		MAPbI_3-xCl_x	Pyridine group	Pb²⁺	20.7/24.1	0.95/1.05	0.68/0.72	12.1/15.5	85

[1]	Zejian Wang, Jiajia Hong, Sue-Faye Ng, Wen Liu, Junjie Huang, Pengfei Chen, Wee-Jun Ong. Recent Progress of Perovskite Oxide in Emerging Photocatalysis Landscape: Water Splitting, CO₂ Reduction, and N₂ Fixation [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2011033-0.
[2]	Yawen Li, Guangren Na, Shulin Luo, Xin He, Lijun Zhang. Structural, Thermodynamical and Electronic Properties of All-Inorganic Lead Halide Perovskites [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007015-0.
[3]	Guangruixing Zou, Ziming Chen, Zhenchao Li, Hin-Lap Yip. Blue Perovskite Light-Emitting Diodes: Opportunities and Challenges [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2009002-0.
[4]	Peiliang Lü, Caiyun Gao, Xiuhong Sun, Mingliang Sun, Zhipeng Shao, Shuping Pang. Synthesis of Cs-Rich CH(NH₂)₂)_xCs_1−xPbI₃ Perovskite Films Using Additives with Low Sublimation Temperature [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2009036-0.
[5]	Wentao Zhou, Yihua Chen, Huanping Zhou. Strategies to Improve the Stability of Perovskite-based Tandem Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2009044-0.
[6]	Peiquan Song, Liqiang Xie, Lina Shen, Kaikai Liu, Yuming Liang, Kebin Lin, Jianxun Lu, Chengbo Tian, Zhanhua Wei. Stable Perovskite Solar Cells Using Compact Tin Oxide Layer Deposited through Electrophoresis [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2004038-0.
[7]	Haomiao Li, Hua Dong, Jingrui Li, Zhaoxin Wu. Recent Advances in Tin-Based Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007006-0.
[8]	Tian Wang, Taiyang Zhang, Yuetian Chen, Yixin Zhao. Highly Moisture Resistant 5-Aminovaleric Acid Crosslinked CH₃NH₃PbBr₃ Perovskite Film with ALD-Al₂O₃ Protection [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007021-0.
[9]	Guiying Xu, Rongming Xue, Moyao Zhang, Yaowen Li, Yongfang Li. Synthesis of Pyrazine-based Hole Transport Layer and Its Application in p-i-n Planar Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2008050-0.
[10]	Jun Ji, Xin Liu, Hao Huang, Haoran Jiang, Mingjun Duan, Benyu Liu, Peng Cui, Yingfeng Li, Meicheng Li. Recent Progress on Perovskite Homojunction Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2008095-0.
[11]	Jionghua Wu, Yiming Li, Jiangjian Shi, Huijue Wu, Yanhong Luo, Dongmei Li, Qingbo Meng. UV Photodetectors Based on High Quality CsPbCl₃ Film Prepared by a Two-Step Diffusion Method [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2004041-0.
[12]	Jiaxin Wang, Weili Shen, Jinning Hu, Jun Chen, Xiaoming Li, Haibo Zeng. Mechanisms and Applications of Laser Action on Lead Halide Perovskites [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2008051-0.
[13]	Zhang Xin, Dengbao Han, Xiaomei Chen, Yu Chen, Shuai Chang, Haizheng Zhong. Effects of Solvent Coordination on Perovskite Crystallization [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2008055-0.
[14]	Chao Zheng, Aqiang Liu, Chenghao Bi, Jianjun Tian. SCN-doped CsPbI₃ for Improving Stability and Photodetection Performance of Colloidal Quantum Dots [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007084-0.
[15]	Zihao Zang, Hansheng Li, Xianyuan Jiang, Zhijun Ning. Progress and Perspective of Tin Perovskite Solar Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(4): 2007090-0.

Recent Progress in Defect Tolerance and Defect Passivation in Halide Perovskite Solar Cells

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 88

Related Articles 15

Metrics

Comments

Recommended 0