有序金属间化合物电催化剂在燃料电池中的应用进展

doi:10.3866/PKU.WHXB202010029

Abstract

Abstract:

Proton exchange membrane fuel cells (PEMFCs) are considered as one of the most promising energy conversion devices owing to their high power density, high energy conversion efficiency, environment-friendly merit, and low operating temperature. In the cathodic oxygen reduction reaction and anodic small-molecule oxidation reactions, Pt shows excellent catalytic activity. However, several factors limit the practical application of Pt nanoparticles in fuel cells, such as the high price of Pt, easy agglomeration during long-term cycling, and limited electrocatalytic performance. Alloying Pt with 3d-transition metal produces ligand and strain effects, which reduces the center of Pt-d band and weakens the binding strength of oxygen species, thereby improving the catalytic activity and reducing the cost. However, the performance of fuel cells degrades seriously because the transition metals tend to dissolve in acidic electrolytes. The disordered alloy transformed into ordered intermetallic nanoparticles can prevent the dissolution of transition metals. Ordered intermetallics have highly ordered atomic arrangements and strong Pt(5d)-M(3d) orbital interactions, which result in excellent stability in both acidic and alkaline electrolytes. Ordered intermetallic nanoparticles have attracted significant attention owing to their excellent electrocatalytic activity and stability, which can be attributed to controllable composition and structure. Pd has a similar electronic structure and lattice parameters to Pt, and has thus attracted significant attention. Several Pd-based ordered intermetallics have been synthesized, and they exhibit sufficient catalytic performance. This review discusses the recent progress in noble metal-based ordered intermetallic electrocatalysts based on the research status of our group over the years. First, the structural characteristics and characterization methods of ordered intermetallic nanoparticles are introduced, exhibiting approaches to distinguish ordered and disordered phases. Then, the controllable preparation of ordered nanoparticles is highlighted, including thermal annealing and direct liquid phase synthesis. The migration and interdiffusion of atoms in the ordering process is very difficult. High-temperature thermal annealing is the most commonly used method for preparing intermetallics, which can precisely control the composition and atomic ordered arrangement. However, thermal annealing can only produce thermodynamically stable spherical nanoparticles. Supports and coating layers are usually employed to prevent agglomeration of nanoparticles at high temperatures. Finally, the applications of ordered intermetallic nanoparticles in fuel cell electrocatalysts are reviewed, including the oxygen reduction reaction (ORR), hydrogen oxidation reaction (HOR), formic acid oxidation reaction (FAOR), methanol oxidation reaction (MOR), and ethanol oxidation reaction (EOR). In addition, the current challenges and future development directions of the catalysts are discussed and discussed to provide new ideas for the development of fuel cell electrocatalysts.

Key words: Fuel cell, Electrocatalysis, Intermetallics, Oxygen reduction reaction, Small-molecule oxidation

MSC2000:

O643

Zhengrong Li, Tao Shen, Yezhou Hu, Ke Chen, Yun Lu, Deli Wang. Progress on Ordered Intermetallic Electrocatalysts for Fuel Cells Application[J].Acta Phys. -Chim. Sin., 2021, 37(9): 2010029.

Figures/Tables 12

Fig 1

Fig 2

Fig 3

Table 1

Fig 4

Fig 5

Fig 6

Fig 7

Fig 8

Fig 9

Fig 10

Fig 11

References 161

1	Dunn B. ; Kamath H. ; Tarascon J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741
2	Bing Y. ; Liu H. ; Zhang L. ; Ghosh D. ; Zhang J. Chem. Soc. Rev. 2010, 39, 2184. doi: 10.1039/b912552c
3	Rößner L. ; Armbrüster M. ACS Catal. 2019, 9, 2018. doi: 10.1021/acscatal.8b04566
4	Luo M. C. ; Sun Y. J. ; Qin Y. N. ; Yang Y. ; Wu D. ; Guo S. J. Acta Phys. -Chim. Sin. 2018, 34, 361.
	骆明川; 孙英俊; 秦英楠; 杨勇; 吴冬; 郭少军. 物理化学学报, 2018, 34, 361. doi: 10.3866/PKU.WHXB201708312
5	Ma Z. ; Cano Z. P. ; Yu A. ; Chen Z. ; Jiang G. ; Fu X. ; Yang L. ; Wu T. ; Bai Z. ; Lu J. Angew. Chem. Int. Ed. 2020, 59, 18334. doi: 10.1002/anie.202003654
6	Wang X. X. ; Sokolowski J. ; Liu H. ; Wu G. Chin. J. Catal. 2020, 41, 739. doi: 10.1016/s1872-2067(19)63407-8
7	Bashyam R. ; Zelenay P. Nature 2006, 443, 63. doi: 10.1038/nature05118
8	Shao M. ; Chang Q. ; Dodelet J. P. ; Chenitz R. Chem. Rev. 2016, 116, 3594. doi: 10.1021/acs.chemrev.5b00462
9	Xia B. Y. ; Wu H. B. ; Wang X. ; Lou X. W. J. Am. Chem. Soc. 2012, 134, 13934. doi: 10.1021/ja3051662
10	Hodnik N. ; Jeyabharathi C. ; Meier J. C. ; Kostka A. ; Phani K. L. ; Recnik A. ; Bele M. ; Hocevar S. ; Gaberscek M. ; Mayrhofer K. J. Phys. Chem. Chem. Phys. 2014, 16, 13610. doi: 10.1039/c4cp00585f
11	Zhang Z. ; Luo Z. ; Chen B. ; Wei C. ; Zhao J. ; Chen J. ; Zhang X. ; Lai Z. ; Fan Z. ; Tan C. ; et al Adv. Mater. 2016, 28, 8712. doi: 10.1002/adma.201603075
12	Sun S. ; Murray C. B. ; Weller D. ; Folks L. ; Moser A. Science 2000, doi: 10.1002/chin.200027244
13	Liu Z. ; Jackson G. S. ; Eichhorn B. W. Energy Environ. Sci. 2011, 4, 1900. doi: 10.1039/c1ee01125a
14	Chung D. Y. ; Jun S. W. ; Yoon G. ; Kwon S. G. ; Shin D. Y. ; Seo P. ; Yoo J. M. ; Shin H. ; Chung Y. H. ; Kim H. ; et al J. Am. Chem. Soc. 2015, 137, 15478. doi: 10.1021/jacs.5b09653
15	Leonard B. M. ; Zhou Q. ; Wu D. ; DiSalvo F. J. Chem. Mater. 2011, 23, 1136. doi: 10.1021/cm1024876
16	Wang Y. ; Zou L. ; Huang Q. ; Zou Z. ; Yang H. Int. J. Hydrogen Energy 2017, 42, 26695. doi: 10.1016/j.ijhydene.2017.09.008
17	Wang D. ; Xin H. L. ; Hovden R. ; Wang H. ; Yu Y. ; Muller D. A. ; DiSalvo F. J. ; Abruna H. D. Nat. Mater. 2013, 12, 81. doi: 10.1038/nmat3458
18	Stamenkovic V. R. ; Mun B. S. ; Arenz M. ; Mayrhofer K. J. ; Lucas C. A. ; Wang G. ; Ross P. N. ; Markovic N. M. Nat. Mater. 2007, 6, 241. doi: 10.1038/nmat1840
19	Cui C. ; Gan L. ; Heggen M. ; Rudi S. ; Strasser P. Nat. Mater. 2013, 12, 765. doi: 10.1038/nmat3668
20	Zhang X. ; Lu G. J. Phys. Chem. Lett. 2014, 5, 292. doi: 10.1021/jz4024699
21	Bligaard T. ; Nørskov J. K. Electrochim. Acta 2007, 52, 5512. doi: 10.1016/j.electacta.2007.02.041
22	Mavrikakis M. ; Hammer B. ; Nørskov J. Phys. Rev. Lett. 1998, 81, 2819. doi: 10.1103/PhysRevLett.81.2819
23	Karamad M. ; Tripkovic V. ; Rossmeisl J. ACS Catal. 2014, 4, 2268. doi: 10.1021/cs500328c
24	Wang K. ; Gasteiger H. A. ; Markovic N. M. Electrochim. Acta 1996, 41, 2587. doi: 10.1016/0013-4686(96)00079-5
25	Jaksic M. M. ; Botton G. A. ; Papakonstantinou G. D. ; Nan F. ; Jaksic J. M. J. Phys. Chem. C 2014, 118, 8723. doi: 10.1021/jp412292w
26	Jaksic J. M. ; Nan F. ; Papakonstantinou G. D. ; Botton G. A. ; Jaksic M. M. J. Phys. Chem. C 2015, 119, 11267. doi: 10.1021/jp510234f
27	Abe H. ; Matsumoto F. ; Alden L. R. J. Am. Chem. Soc. 2008, 130, 5452. doi: 10.1021/ja075061c
28	DeSario D. Y. ; DiSalvo F. J. Chem. Mater. 2014, 26, 2750. doi: 10.1021/cm5007197
29	Wang D. ; Yu Y. ; Xin H. L. ; Hovden R. ; Ercius P. ; Mundy J. A. ; Chen H. ; Richard J. H. ; Muller D. A. ; DiSalvo F. J. ; Abruna H. D. Nano Lett. 2012, 12, 5230. doi: 10.1021/nl302404g
30	Liu S. ; Xiao W. ; Wang J. ; Zhu J. ; Wu Z. ; Xin H. ; Wang D. Nano Energy 2016, 27, 475. doi: 10.1016/j.nanoen.2016.07.038
31	Xiao W. ; Cordeiro M. A. L. ; Gao G. ; Zheng A. ; Wang J. ; Lei W. ; Gong M. ; Lin R. ; Stavitski E. ; Xin H. L. ; Wang D. Nano Energy 2018, 50, 70. doi: 10.1016/j.nanoen.2018.05.032
32	Galeano C. ; Meier J. C. ; Peinecke V. ; Bongard H. ; Katsounaros I. ; Topalov A. A. ; Lu A. ; Mayrhofer K. J. ; Schuth F. J. Am. Chem. Soc. 2012, 134, 20457. doi: 10.1021/ja308570c
33	Iihama S. ; Furukawa S. ; Komatsu T. ACS Catal. 2015, 6, 742. doi: 10.1021/acscatal.5b02464
34	Najafishirtari S. ; Brescia R. ; Guardia P. ; Marras S. ; Manna L. ; Colombo M. ACS Catal. 2015, 5, 2154. doi: 10.1021/cs501923x
35	Kim J. ; Lee Y. ; Sun S. J. Am. Chem. Soc. 2010, 132, 4996. doi: 10.1021/ja1009629
36	Zou L. ; Li J. ; Yuan T. ; Zhou Y. ; Li X. ; Yang H. Nanoscale 2014, 6, 10686. doi: 10.1039/c4nr02799j
37	Cui Y. ; Wu Y. ; Wang Z. ; Yao X. ; Wei Y. ; Kang Y. ; Du H. ; Li J. ; Gan L. J. Electrochem. Soc. 2020, 167, 064520. doi: 10.1149/1945-7111/ab8407
38	Hu Y. ; Lu Y. ; Zhao X. ; Shen T. ; Zhao T. ; Gong M. ; Chen K. ; Lai C. ; Zhang J. ; Xin H. L. ; Wang D. Nano Res. 2020, 13, 2365. doi: 10.1007/s12274-020-2856-z
39	Yang Y. ; Chen G. ; Zeng R. ; Villarino A. M. ; DiSalvo F. J. ; van Dover R. B. ; Abruna H. D. J. Am. Chem. Soc. 2020, 142, 3980. doi: 10.1021/jacs.9b13400
40	Shao M. J. Power Sources 2011, 196, 2433. doi: 10.1016/j.jpowsour.2010.10.093
41	Xiao W. ; Lei W. ; Wang J. ; Gao G. ; Zhao T. ; Cordeiro M. A. L. ; Lin R. ; Gong M. ; Guo X. ; Stavitski E. ; et al J. Mater. Chem. A 2018, 6, 11346. doi: 10.1039/c8ta03250e
42	Shen T. ; Chen S. ; Zeng R. ; Gong M. ; Zhao T. ; Lu Y. ; Liu X. ; Xiao D. ; Yang Y. ; Hu J. ; et al ACS Catal. 2020, 10, 9977. doi: 10.1021/acscatal.0c01537
43	Meku E. ; Du C. ; Sun Y. ; Du L. ; Wang Y. ; Yin G. J. Electrochem. Soc. 2015, 163, F132. doi: 10.1149/2.0031603jes
44	Takao G. ; Noh S. H. ; Fuma A. ; Toyokazu T. ; Byungchan H. ; Takeo O. J. Mater. Chem. A 2018, 6, 14828. doi: 10.1039/C8TA03233E
45	Casado-Rivera E. ; Volpe D. J. ; Alden L. ; Lind C. ; Downie C. ; Vazquez-Alvarez T. J. Am. Chem. Soc. 2004, 126, 4043. doi: 10.1021/ja038497a
46	Wang D. ; Yu Y. ; Zhu J. ; Liu S. ; Muller D. A. ; Abruna H. D. Nano Lett. 2015, 15, 1343. doi: 10.1021/nl504597j
47	Gong M. ; Zhu J. ; Liu M. ; Liu P. ; Deng Z. ; Shen T. ; Zhao T. ; Lin R. ; Lu Y. ; Yang S. ; et al Nanoscale 2019, 11, 20301. doi: 10.1039/c9nr04975d
48	Li J. ; Sun S. Acc. Chem. Res. 2019, 52, 2015. doi: 10.1021/acs.accounts.9b00172
49	Koh S. ; Toney M. F. ; Strasser P. Electrochim. Acta 2007, 52, 2765. doi: 10.1016/j.electacta.2006.08.039
50	Liu Z. ; Jackson G. S. ; Eichhorn B. W. Angew. Chem. Int. Ed. 2010, 49, 3173. doi: 10.1002/anie.200907019
51	Ji X. ; Lee K. T. ; Holden R. ; Zhang L. ; Zhang J. ; Botton G. A. ; Couillard M. ; Nazar L. F. Nat. Chem. 2010, 2, 286. doi: 10.1038/nchem.553
52	Ghosh T. ; Vukmirovic M. ; DiSalvoF. ; Adzic R. J. Am. Chem. Soc. 2010, 132, 906. doi: 10.1021/ja905850c
53	Xiao W. ; Lei W. ; Gong M. ; Xin H. L. ; Wang D. ACS Catal. 2018, 8, 3237. doi: 10.1021/acscatal.7b04420
54	Furukawa S. ; Komatsu T. ACS Catal. 2016, 7, 735. doi: 10.1021/acscatal.6b02603
55	Yoo T. Y. ; Yoo J. M. ; Sinha A. K. ; Bootharaju M. S. ; Jung E. ; Lee H. S. ; Lee B. H. ; Kim J. ; Antink W. H. ; Kim Y. M. ; et al J. Am. Chem. Soc. 2020, 142, 14190. doi: 10.1021/jacs.0c05140
56	Lee J. ; Yoo J. M. ; Ye Y. ; Mun Y. ; Lee S. ; Kim O. H. ; Rhee H. W. ; Lee H. I. ; Sung Y. E. ; Lee J. Adv. Energy Mater. 2015, 5, 1402093. doi: 10.1002/aenm.201402093
57	Li J. ; Xi Z. ; Pan Y. T. ; Spendelow J. S. ; Duchesne P. N. ; Su D. ; Li Q. ; Yu C. ; Yin Z. ; Shen B. ; Kim Y. S. ; Zhang P. ; Sun S. J. Am. Chem. Soc. 2018, 140, 2926. doi: 10.1021/jacs.7b12829
58	Li J. ; Sharma S. ; Liu X. ; Pan Y. T. ; Spendelow J. S. ; Chi M. ; Jia Y. ; Zhang P. ; Cullen D. A. ; Xi Z. ; et al Joule 2019, 3, 124. doi: 10.1016/j.joule.2018.09.016
59	Wang H. ; Shang P. ; Zhang J. ; Guo M. ; Mu Y. ; Li Q. ; Wang H. Chem. Mater. 2013, 25, 2450. doi: 10.1021/cm4004678
60	Lei W. ; Xu J. ; Yu Y. ; Yang W. ; Hou Y. ; Chen D. Nano Lett. 2018, 18, 7839. doi: 10.1021/acs.nanolett.8b03603
61	Wang C. ; Chen D. P. ; Sang X. ; Unocic R. R. ; Skrabalak S. E. ACS Nano 2016, 10, 6345. doi: 10.1021/acsnano.6b02669
62	Pacchioni G. ; Freund H. J. Chem. Soc. Rev. 2018, 47, 8474. doi: 10.1039/c8cs00152a
63	van Deelen T. W. ; Hernández Mejía C. ; de Jong K. P. Nat. Catal. 2019, 2, 955. doi: 10.1038/s41929-019-0364-x
64	Shim J. ; Lee J. ; Ye Y. ; Hwang J. ; Kim S. K. ; Lim T. H. ACS Nano 2012, 6, 6870. doi: 10.1021/nn301692y
65	Kang E. ; Jung H. ; Park J. G. ; Kwon S. ; Shim J. ; Sai H. ACS Nano 2011, 5, 1018. doi: 10.1021/nn102451y
66	Liu Z. ; Fu G. ; Li J. ; Liu Z. ; Xu L. ; Sun D. ; Tang Y. Nano Res. 2018, 11, 4686. doi: 10.1007/s12274-018-2051-7
67	Liu H. ; Dou M. ; Wang F. ; Liu J. ; Ji J. ; Li Z. RSC Adv. 2015, 5, 66471. doi: 10.1039/c5ra12291k
68	Kumar V. B. ; Sanetuntikul J. ; Ganesan P. ; Porat Z. E. ; Shanmugam S. ; Gedanken A. Electrochim. Acta 2016, 190, 659. doi: 10.1016/j.electacta.2015.12.193
69	Zhu W. ; Yuan H. ; Liao F. ; Shen Y. ; Shi H. ; Shi Y. ; Xu L. ; Ma M. ; Shao M. Chem. Eng. J. 2020, 389, 124240. doi: 10.1016/j.cej.2020.124240
70	Wang X. X. ; Hwang S. ; Pan Y. T. ; Chen K. ; He Y. ; Karakalos S. ; Zhang H. ; Spendelow J. S. ; Su D. ; Wu G. Nano Lett. 2018, 18, 4163. doi: 10.1021/acs.nanolett.8b00978
71	Chen D. ; Li Z. ; Zhou Y. ; Ma X. ; Lin H. ; Ying W. ; Peng X. Chem. Comm. 2020, 56, 4898. doi: 10.1039/d0cc00895h
72	Qi Z. ; Pei Y. ; Goh T. W. ; Wang Z. ; Li X. ; Lowe M. ; Maligal-Ganesh R. V. ; Huang W. Nano Res. 2018, 11, 3469. doi: 10.1007/s12274-018-2016-x
73	Hu M. ; Zhao S. ; Liu S. ; Chen C. ; Chen W. ; Zhu W. ; Liang C. ; Cheong W. C. ; Wang Y. ; Yu Y. ; et al Adv. Mater. 2018, 30, 1801878. doi: 10.1002/adma.201801878
74	Kwon T. ; Lim S. ; Jun M. ; Kang M. ; Joo J. ; Oh A. ; Baik H. ; Hong C. S. ; Lee K. Nanoscale 2020, 12, 1118. doi: 10.1039/c9nr09318d
75	Yan Y. ; Du J. S. ; Gilroy K. D. ; Yang D. ; Xia Y. ; Zhang H. Adv. Mater. 2017, 29, 1605997. doi: 10.1002/adma.201605997
76	Bernal S. ; Calvino J. J. ; Gatica J. M. ; Larese C. ; López-Cartes C. ; Pérez-Omil J. A. J. Catal. 1997, 169, 510. doi: 10.1006/jcat.1997.1707
77	Maligal-Ganesh R. V. ; Xiao C. ; Goh T. W. ; Wang L. L. ; Gustafson J. ; Pei Y. ; Qi Z. ; Johnson D. D. ; Zhang S. ; Tao F. ; Huang W. ACS Catal. 2016, 6, 1754. doi: 10.1021/acscatal.5b02281
78	Hu Y. ; Shen T. ; Zhao X. ; Zhang J. ; Lu Y. ; Shen J. ; Lu S. ; Tu Z. ; Xin H. L. ; Wang D. Appl. Catal. B 2020, 279, 119370. doi: 10.1016/j.apcatb.2020.119370
79	Takahashi Y. ; Kadono T. ; Yamamoto S. ; Singh V. R. ; Verma V. K. ; Ishigami K. ; Shibata G. ; Harano T. ; Takeda Y. ; Okane T. ; et al Phys. Rev. B 2014, 90, 024423. doi: 10.1103/PhysRevB.90.024423
80	Qi Z. ; Xiao C. ; Liu C. ; Goh T. W. ; Zhou L. ; Maligal-Ganesh R. ; Pei Y. ; Li X. ; Curtiss L. A. ; Huang W. J. Am. Chem. Soc. 2017, 139, 4762. doi: 10.1021/jacs.6b12780
81	Xiao W. ; Liutheviciene Cordeiro M. A. ; Gong M. ; Han L. ; Wang J. ; Bian C. ; Zhu J. ; Xin H. L. ; Wang D. J. Mater. Chem. A 2017, 5, 9867. doi: 10.1039/c7ta02479g
82	Kim J. ; Rong C. ; Liu J. P. ; Sun S. Adv. Mater. 2009, 21, 906. doi: 10.1002/adma.200801620
83	Chen H. ; Wang D. ; Yu Y. ; Newton K. A. ; Muller D. A. ; Abruna H. ; DiSalvo F. J. J. Am. Chem. Soc. 2012, 134, 18453. doi: 10.1021/ja308674b
84	Chen H. ; Yu Y. ; Xin H. L. ; Newton K. A. ; Holtz M. E. ; Wang D. ; Muller D. A. ; Abruña H. D. ; DiSalvo F. J. Chem. Mater. 2013, 25, 1436. doi: 10.1021/cm303489z
85	Cui Z. ; Chen H. ; Zhao M. ; DiSalvo F. J. Nano Lett. 2016, 16, 2560. doi: 10.1021/acs.nanolett.6b00121
86	Nguyen M. T. ; Wakabayashi R. H. ; Yang M. ; Abruña H. D. ; DiSalvo F. J. J. Power Sources 2015, 280, 459. doi: 10.1016/j.jpowsour.2015.01.076
87	Li D. ; Poudyal N. ; Nandwana V. ; Jin Z. ; Elkins K. ; Liu J. P. J. Appl. Phys. 2006, 99, 08E. doi: 10.1063/1.2166597
88	Kim J. ; Rong C. ; Lee Y. ; Liu J. P. ; Sun S. Chem. Mater. 2015, 20, 7242. doi: 10.1021/cm8024878
89	Yu Y. ; Sun K. ; Tian Y. ; Li X. Z. ; Kramer M. J. ; Sellmyer D. J. ; Shield J. E. ; Sun S. Nano Lett. 2013, 13, 4975. doi: 10.1021/nl403043d
90	Wang T. ; Liang J. ; Zhao Z. ; Li S. ; Lu G. ; Xia Z. ; Wang C. ; Luo J. ; Han J. ; Ma C. ; Huang Y. ; Li Q. Adv. Energy Mater. 2019, 9, 1803771. doi: 10.1002/aenm.201803771
91	Zhang S. ; Guo S. ; Zhu H. ; Su D. ; Sun S. J. Am. Chem. Soc. 2012, 134, 5060. doi: 10.1021/ja300708j
92	Kuttiyiel K. A. ; Sasaki K. ; Su D. ; Wu L. ; Zhu Y. ; Adzic R. R. Nat. Commun. 2014, 5, 5185. doi: 10.1038/ncomms6185
93	Yan Q. ; Kim T. ; Purkayastha A. ; Ganesan P. G. ; Shima M. ; Ramanath G. Phys. Inorg. Chem. 2005, 17, 2233. doi: 10.1002/chin.200546012
94	Takahashi Y. K. ; Ohnuma M. ; Hono K. J. Magn. Magn. Mater. 2002, 246, 259. doi: 10.1016/S0304-8853(02)00065-3
95	Kang S. ; Harrell J. W. ; Nikles D. E. Nano Lett. 2002, 2, 1033. doi: 10.1021/nl025614b
96	Rong H. ; Mao J. ; Xin P. ; He D. ; Chen Y. ; Wang D. ; Niu Z. ; Wu Y. ; Li Y. Adv. Mater. 2016, 28, 2540. doi: 10.1002/adma.201504831
97	Cheong S. ; Watt J. ; Ingham B. ; Toney M. F. ; Tilley R. D. J. Am. Chem. Soc. 2009, 131, 14590. doi: 10.1021/ja9065688
98	Chen W. ; Yu R. ; Li L. ; Wang A. ; Peng Q. ; Li Y. Angew. Chem. Int. Ed. 2010, 49, 2917. doi: 10.1002/anie.200906835
99	Bu L. ; Zhang N. ; Guo S. ; Zhang X. ; Li J. ; Yao J. Science 2016, 354, 1410. doi: 10.1126/science.aah6133
100	Qin Y. ; Luo M. ; Sun Y. ; Li C. ; Huang B. ; Yang Y. ; Li Y. ; Wang L. ; Guo S. ACS Catal. 2018, 8, 5581. doi: 10.1021/acscatal.7b04406
101	Stamenkovic V. R. ; Fowler B. ; Mun B. S. ; Wang G. ; Ross P. N. ; Lucas C. A. Science 2007, 315, 493. doi: 10.1126/science.1135941
102	Zhang X. ; Tian S. ; Yu W. ; Lu B. ; Shen T. ; Xu L. ; Sun D. ; Zhang S. ; Tang Y. CrystEngComm 2018, 20, 4277. doi: 10.1039/c8ce00601f
103	Liu S. ; Han L. ; Zhu J. ; Xiao W. ; Wang J. ; Liu H. ; Xin H. ; Wang D. J. Mater. Chem. A 2015, 3, 20966. doi: 10.1039/c5ta05202e
104	Bu L. ; Shao Q. ; E ; B.; Guo J. ; Yao J. ; Huang X. J. Am. Chem. Soc. 2017, 139, 9576. doi: 10.1021/jacs.7b03510
105	Wang C. ; Sang X. ; Gamler J. T. L. ; Chen D. P. ; Unocic R. R. ; Skrabalak S. E. Nano Lett. 2017, 17, 5526. doi: 10.1021/acs.nanolett.7b02239
106	Wang G. ; Huang B. ; Xiao L. ; Ren Z. ; Chen H. ; Wang D. ; Abruna H. D. ; Lu J. ; Zhuang L. J. Am. Chem. Soc. 2014, 136, 9643. doi: 10.1021/ja503315s
107	Guo S. ; Zhang X. ; Zhu W. ; He K. ; Su D. ; Mendoza-Garcia A. ; Ho S. F. ; Lu G. ; Sun S. J. Am. Chem. Soc. 2014, 136, 15026. doi: 10.1021/ja508256g
108	Jiang G.; Zhu H.; Zhang X.; Shen B.; Wu L.; Zhang S.; Lu G.; Wu Z.; Sun S. ACS Nano 2015, 9, 11014. doi: 10.1021/acsnano.5b04361
109	Zhao X. ; Xi C. ; Zhang R. ; Song L. ; Wang C. ; Spendelow J. S. ; Frenkel A. I. ; Yang J. ; Xin H. L. ; Sasaki K. ACS Catal. 2020, 10637. doi: 10.1021/acscatal.0c03036
110	Wang D. ; Yu Y. ; Zhu J. ; Liu S. ; Muller D. A. ; Abruna H. D. Nano Lett. 2015, 15, 1343. doi: 10.1021/nl504597j
111	Li L. ; Larsen A. H. ; Romero N. A. ; Morozov V. A. ; Glinsvad C. ; Abild-Pedersen F. ; Greeley J. ; Jacobsen K. W. ; Norskov J. K. J. Phys. Chem. Lett. 2013, 4, 222. doi: 10.1021/jz3018286
112	Yang Y. ; Xiao W. ; Feng X. ; Xiong Y. ; Gong M. ; Shen T. ; Lu Y. ; Abruna H. D. ; Wang D. ACS Nano 2019, 13, 5968. doi: 10.1021/acsnano.9b01961
113	Kuttiyiel K. A. ; Kattel S. ; Cheng S. ; Lee J. H. ; Wu L. ; Zhu Y. ; Park G. G. ; Liu P. ; Sasaki K. ; Chen J. G. ; Adzic R. R. ACS Appl. Energy Mater. 2018, 1, 3771. doi: 10.1021/acsaem.8b00555
114	He Y. ; Wu Y. L. ; Zhu X. X. ; Wang J. N. ACS Appl. Mater. Interfaces 2019, 11, 11527. doi: 10.1021/acsami.9b01810
115	Liang J. ; Li N. ; Zhao Z. ; Ma L. ; Wang X. ; Li S. ; Liu X. ; Wang T. ; Du Y. ; Lu G. ; Han J. ; Huang Y. ; Su D. ; Li Q. Angew. Chem. Int. Ed. 2019, 58, 15471. doi: 10.1002/anie.201908824
116	Dhavale V. M. ; Kurungot S. ACS Catal. 2015, 5, 1445. doi: 10.1021/cs501571e
117	Gong M. ; Xiao D. ; Deng Z. ; Zhang R. ; Xia W. ; Zhao T. ; Liu X. ; Shen T. ; Hu Y. ; Lu Y. ; et al Appl. Catal. B 2021, (282), 119617. doi: 10.1016/j.apcatb.2020.119617
118	A o ; X ; Zhang ; W ; Zhao B. ; Ding Y. ; Liu M. Energy Environ. Sci. 2020, 13, 3032. doi: 10.1039/D0EE00832J
119	Zhao X. ; Yin M. ; Ma L. ; Liang L. ; Liu C. ; Liao J. ; Lu T. ; Xing W. Energy Environ. Sci. 2011, 4, 2736. doi: 10.1039/c1ee01307f
120	Rossmeisl J. ; Ferrin P. ; Tritsaris G. A. ; Nilekar A. U. ; Koh S. ; Bae S. E. ; Brankovic S. R. ; Strasser P. ; Mavrikakis M. Energy Environ. Sci. 2012, 5, 8335. doi: 10.1039/c2ee21455e
121	Scofield M. E. ; Zhou Y. ; Yue S. ; Wang L. ; Su D. ; Tong X. ; Vukmirovic M. B. ; Adzic R. R. ; Wong S. S. ACS Catal. 2016, 6, 3895. doi: 10.1021/acscatal.6b00350
122	Wang Y. ; Wang G. ; Li G. ; Huang B. ; Pan J. ; Liu Q. ; Han J. ; Xiao L. ; Lu J. ; Zhuang L. Energy Environ. Sci. 2015, 8, 177. doi: 10.1039/c4ee02564d
123	Innocente A. F. ; Ângelo A. C. D. J. Power Sources 2006, 162, 151. doi: 10.1016/j.jpowsour.2006.06.057
124	Santos E. ; Pinto L. M. C. ; Soldano G. ; Innocente A. F. ; Ângelo A. C. D. ; Schmickler W. Catal. Today 2013, 202, 191. doi: 10.1016/j.cattod.2012.07.044
125	Bortoloti F. ; Garcia A. C. ; Angelo A. C. D. Int. J. Hydrogen Energy 2015, 40, 10816. doi: 10.1016/j.ijhydene.2015.06.145
126	Zhao T. ; Hu Y. ; Gong M. ; Lin R. ; Deng S. ; Lu Y. ; Liu X. ; Chen Y. ; Shen T. ; Hu Y. ; et al Nano Energy 2020, 74, 104877. doi: 10.1016/j.nanoen.2020.104877
127	Kang Y. ; Qi L. ; Li M. ; Diaz R. E. ; Su D. ; Adzic R. R. ACS Nano 2012, 6, 2818. doi: 10.1016/j.ijhydene.2015.06.145
128	Vidal-Iglesias F. J. ; Lopez-Cudero A. ; Solla-Gullon J. ; Feliu J. M. Angew. Chem. Int. Ed. 2013, 52, 964. doi: 10.1002/anie.201207517
129	Alden L. R. ; Han D. K. ; Matsumoto F. ; Héctor D. Abruña. ; Disalvo F. ; Disalvo F. J. Chem. Mater. 2006, 18, 5591. doi: 10.1021/cm060927j
130	Luo S. ; Chen W. ; Cheng Y. ; Song X. ; Wu Q. ; Li L. ; Wu X. ; Wu T. ; Li M. ; Yang Q. ; Deng K. ; Quan Z. Adv. Mater. 2019, 31, e1903683. doi: 10.1002/adma.201903683
131	Shen T. ; Zhang J. ; Chen K. ; Deng S. ; Wang D. Energy Fuels 2020, 34, 9137. doi: 10.1021/acs.energyfuels.0c01820
132	Roychowdhury C. ; Matsumoto F. ; Zeldovich V. B. ; Warren S. C. ; Mutolo P. F. ; Ballesteros M. J. Chem. Mater. 2006, 18, 3365. doi: 10.1021/cm060480e
133	Liu Y. ; Lowe M. A. ; Finkelstein K. D. ; Dale D. S. ; DiSalvo F. J. ; Abruna H. D. Chem 2010, 16, 13689. doi: 10.1002/chem.201001211
134	Wang C. Y. ; Yu Z. Y. ; Li G. ; Song Q. T. ; Li G. ; Luo C. X. ; Yin S. H. ; Lu B. A. ; Xiao C. ; Xu B. B. ; et al ChemElectroChem 2020, 7, 239. doi: 10.1002/celc.201901818
135	Zhu J. ; Zheng X. ; Wang J. ; Wu Z. ; Han L. ; Lin R. ; Xin H. L. ; Wang D. J. Mater. Chem. A 2015, 3, 22129. doi: 10.1039/c5ta05699c
136	Chen L. ; Zhu J. ; Xuan C. ; Xiao W. ; Xia K. ; Xia W. ; Lai C. ; Xin H. L. ; Wang D. J. Mater. Chem. A 2018, 6, 5848. doi: 10.1039/c7ta11051k
137	Wang J. Y. ; Zhang H. X. ; Jiang K. ; Cai W. B. J. Am. Chem. Soc. 2011, 133, 14876. doi: 10.1021/ja205747j
138	Sun D. ; Si L. ; Fu G. ; Liu C. ; Sun D. ; Chen Y. ; Tang Y. ; Lu T. J. Power Sources 2015, 280, 141. doi: 10.1016/j.jpowsour.2015.01.100
139	Shen T. ; Lu Y. ; Gong M. ; Zhao T. ; Hu Y. ; Wang D. ACS Sustain. Chem. Eng. 2020, 8, 12239. doi: 10.1021/acssuschemeng.0c03881
140	Jana R. ; Subbarao U. ; Peter S. C. J. Power Sources 2016, 301, 160. doi: 10.1016/j.jpowsour.2015.09.114
141	Kang Y. ; Qi L. ; Li M. ; Diaz R. E. ; Su D. ; Adzic ; Stach R. R. ; E.; Li J. ; Murray C. B. ACS Nano 2012, 6, 2818. doi: 10.1016/j.ijhydene.2015.06.145
142	Mun Y. ; Shim J. ; Kim K. ; Han J. W. ; Kim S. K. ; Ye Y. ; Hwang J. ; Lee S. ; Jang J. ; Kim Y. T. ; Lee J. RSC Adv. 2016, 6, 88255. doi: 10.1039/c6ra14861a
143	An L. ; Yan H. ; Li B. ; Ma J. ; Wei H. ; Xia D. Nano Energy 2015, 15, 24. doi: 10.1016/j.nanoen.2015.03.031
144	Zhu J. ; Yang Y. ; Chen L. ; Xiao W. ; Liu H. ; Abruña H. D. ; Wang D. Chem. Mater. 2018, 30, 5987. doi: 10.1021/acs.chemmater.8b02172
145	Zeng R. ; Yang Y. ; Shen T. ; Wang H. ; Xiong Y. ; Zhu J. ; Wang D. ; Abruña H. D. ACS Catal. 2019, 10, 770. doi: 10.1021/acscatal.9b04344
146	Chen Q. ; Zhang J. ; Jia Y. ; Jiang Z. ; Xie Z. ; Zheng L. Nanoscale 2014, 6, 7019. doi: 10.1039/c4nr00313f
147	Feng Q. ; Zhao S. ; He D. ; Tian S. ; Gu L. ; Wen X. ; Chen C. ; Peng Q. ; Wang D. ; Li Y. J. Am. Chem. Soc. 2018, 140, 2773. doi: 10.1021/jacs.7b13612
148	Yuan X. ; Jiang X. ; Cao M. ; Chen L. ; Nie K. ; Zhang Y. ; Xu Y. ; Sun X. ; Li Y. ; Zhang Q. Nano Res. 2018, 12, 429. doi: 10.1007/s12274-018-2234-2
149	Kang Y. ; Murray C. B. J. Am. Chem. Soc. 2010, 132, 7568. doi: 10.1021/ja100705j
150	Farias M. J. S. ; Cheuquepan W. ; Tanaka A. A. ; Feliu J. M. J. Phys. Chem. Lett. 2018, 9, 1206. doi: 10.1021/acs.jpclett.8b00030
151	Kodiyath R. ; Ramesh G. V. ; Koudelkova E. ; Tanabe T. ; Ito M. ; Manikandan M. ; Ueda S. ; Fujita T. ; Umezawa N. ; Noguchi H. ; et al Energy Environ. Sci. 2015, 8, 1685. doi: 10.1039/c4ee03746d
152	Sarkar S. ; Jana R. ; Suchitra ; Waghmare U. V. ; Kuppan B. ; Sampath S. ; Peter S. C. Chem. Mater. 2015, 27, 7459. doi: 10.1021/acs.chemmater.5b03546
153	Wang C. ; Wu Y. ; Wang X. ; Zou L. ; Zou Z. ; Yang H. Electrochim. Acta 2016, 220, 628. doi: 10.1016/j.electacta.2016.10.094
154	Zhang W. ; Wang R. ; Wang H. ; Lei Z. Fuel Cells 2010, 10, 734. doi: 10.1002/fuce.200900184
155	Singh R. N. ; Singh A. ; Anindita Int. J. Hydrogen Energy 2009, 34, 2052. doi: 10.1016/j.ijhydene.2008.12.047
156	Pattabiraman R. Appl. Catal. A 1997, 153, 9. doi: 10.1016/j.ijhydene.2008.12.047
157	Jiang K. ; Wang P. ; Guo S. ; Zhang X. ; Shen X. ; Lu G. ; Su D. ; Huang X. Angew. Chem. 2016, 128, 9176. doi: 10.1002/ange.201603022
158	Serov A. ; Martinez U. ; Atanassov P. Electrochem. Commun. 2013, 34, 185. doi: 10.1016/j.elecom.2013.06.003
159	Shi Q. ; Zhu C. ; Bi C. ; Xia H. ; Engelhard M. H. ; Du D. ; Lin Y. J. Mater. Chem. A 2017, 5, 23952. doi: 10.1039/c7ta08407b
160	Zhu Y. ; Bu L. ; Shao Q. ; Huang X. ACS Catal. 2020, 10, 3455. doi: 10.1021/acscatal.9b04313
161	Yun Q. ; Lu Q. ; Li C. ; Chen B. ; Zhang Q. ; He Q. ; Hu Z. ; Zhang Z. ; Ge Y. ; Yang N. ; et al ACS Nano 2019, 13, 14329. doi: 10.1021/acsnano.9b07775

Synthetic method	Composition	Reaction temperature/℃	Application	Particle size/nm	Ref.
Annealing with support	Pt₃Co	700	ORR	7.2	16
	PtPb	700	FAOR	42.4	60
	PtBi	600	FAOR	2–3.5	47
	Pd₃Fe	750	FAOR	11	62
	PtFe	650	ORR	6	63
	Pt₃Co	900	ORR	3	66
	Fe₃Pt	900	ORR	1–4	67
	CePt₅	900	–	8	72
Annealing with coating	PtFe	700	ORR	6.5	13
	PtFe	800	ORR	3.8	74
	PdFe	800	ORR	–	75
	PtZn	600	MOR	2.1	77
	Pd₂FeCo	500	ORR	6.5	78
	FePt	800	–	7	79
	Pt₃Fe	600	–	2	80
	Pd₃Pb	400	ORR	5.2	82
Annealing with defects	FePd	500	–	6	86
	PtNi_0.8Co_0.2	600	ORR	6	87
	FePtAu	600	FAOR	4	88
	AuPdCo	800	ORR	6.7	89
Solution phase synthesis	Pt₃Sn	180	–	12.8/22.8/18.3	93
	PtPb	–	–	16 (edge length)	96
	PtBi	160	–	2.5 (thickness)	97

[1]	Xiaohui Li, Xiaodong Li, Quanhu Sun, Jianjiang He, Ze Yang, Jinchong Xiao, Changshui Huang. Synthesis and Applications of Graphdiyne Derivatives [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2206029-0.
[2]	Mingliang Wu, Yehui Zhang, Zhanzhao Fu, Zhiyang Lyu, Qiang Li, Jinlan Wang. Structure-Activity Relationship of Atomic-Scale Cobalt-Based N-C Catalysts in the Oxygen Evolution Reaction [J]. Acta Phys. -Chim. Sin., 2023, 39(1): 2207007-0.
[3]	Tonghui Cui, Hangyue Li, Zewei Lyu, Yige Wang, Minfang Han, Zaihong Sun, Kaihua Sun. Identification of Electrode Process in Large-Size Solid Oxide Fuel Cell [J]. Acta Phys. -Chim. Sin., 2022, 38(8): 2011009-.
[4]	Mingjun Ma, Zhichao Feng, Xiaowei Zhang, Chaoyue Sun, Haiqing Wang, Weijia Zhou, Hong Liu. Progress in the Preparation and Application of Electrocatalysts Based on Microorganisms as Intelligent Templates [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2106003-.
[5]	Yuke Song, Wenfu Xie, Mingfei Shao. Recent Advances in Integrated Electrode for Electrocatalytic Carbon Dioxide Reduction [J]. Acta Phys. -Chim. Sin., 2022, 38(6): 2101028-.
[6]	Aidi Han, Xiaohui Yan, Junren Chen, Xiaojing Cheng, Junliang Zhang. Effects of Dispersion Solvents on Proton Conduction Behavior of Ultrathin Nafion Films in the Catalyst Layers of Proton Exchange Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912052-.
[7]	Xiaoxiong Huang, Yingjie Ma, Linjie Zhi. Ultrathin Nitrogenated Carbon Nanosheets with Single-Atom Nickel as an Efficient Catalyst for Electrochemical CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2011050-.
[8]	Yadong Du, Xiangtong Meng, Zhen Wang, Xin Zhao, Jieshan Qiu. Graphene-Based Catalysts for CO₂ Electroreduction [J]. Acta Phys. -Chim. Sin., 2022, 38(2): 2101009-.
[9]	Yongxia Shi, Man Hou, Junjun Li, Li Li, Zhicheng Zhang. Cu-Based Tandem Catalysts for Electrochemical CO₂ Reduction [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2206020-.
[10]	Yuxin Chen, Lijun Wang, Zhibo Yao, Leiduan Hao, Xinyi Tan, Justus Masa, Alex W. Robertson, Zhenyu Sun. Tuning the Coordination Structure of Single Atoms and Their Interaction with the Support for Carbon Dioxide Electroreduction [J]. Acta Phys. -Chim. Sin., 2022, 38(11): 2207024-0.
[11]	Fang Luo, Shuyuan Pan, Zehui Yang. Recent Progress on Electrocatalyst for High-Temperature Polymer Exchange Membrane Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009087-.
[12]	Mengting Li, Xingqun Zheng, Li Li, Zidong Wei. Research Progress of Hydrogen Oxidation and Hydrogen Evolution Reaction Mechanism in Alkaline Media [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2007054-.
[13]	Lei Huang, Shahid Zaman, Zhitong Wang, Huiting Niu, Bo You, Bao Yu Xia. Synthesis and Application of Platinum-Based Hollow Nanoframes for Direct Alcohol Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009035-.
[14]	Liliang Tian, Weiqi Zhang, Zheng Xie, Kai Peng, Qiang Ma, Qian Xu, Sivakumar Pasupathi, Huaneng Su. Enhanced Performance and Durability of High-Temperature Polymer Electrolyte Membrane Fuel Cell by Incorporating Covalent Organic Framework into Catalyst Layer [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009049-.
[15]	Miaomiao Liu, Maomao Yang, XinXin Shu, Jintao Zhang. Design Strategies for Carbon-Based Electrocatalysts and Application to Oxygen Reduction in Fuel Cells [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2007072-.

Progress on Ordered Intermetallic Electrocatalysts for Fuel Cells Application

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 12

References 161

Related Articles 15

Metrics

Recommended 0