Acta Phys. -Chim. Sin. ›› 1985, Vol. 1 ›› Issue (05): 397-403.doi: 10.3866/PKU.WHXB19850501

• ARTICLE •     Next Articles

ALUMINUM-27 AND PROTON NMR SPECTROSCOPY OF THE ALUMINUM ETHER COMPLEX

Guo Guolin; Xie Youchang   

  1. Laboratory for Structure of Matter, Institute of Physical Chemistry, Peking University
  • Received:1984-10-04 Revised:1984-12-20 Published:1985-10-15

Abstract: The chemical shifts and linewidths for aluminum chloride in ethyl ether have been studied by O'Reilly~[1], Haragushi~[2] and Kidd. But-different values have been reported. Up to now the divergence of shifts and linewidths is still present on this question.
In studying the Ziegler-Natta catalyst, the ~(27)Al NMR datum of AlCl_3 Et_2O complex are very important. So we must re-examine them.
It has been verified that the chemical shifts and Iinewidths of the complex in ether are 100.9 ppm and 125Hz respectively, and no...