Acta Phys. -Chim. Sin. ›› 1986, Vol. 2 ›› Issue (06): 505-511.doi: 10.3866/PKU.WHXB19860605

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THE METHOD OF KINEMATICALLY DEFINED FORCE CONSTANTS IN MOLECULAR VIBRATION

Yan Guosen; Sun Zemin; Xiao Shenxiu; Zhou Xuefeng; Xue Ying   

  1. Chemistry Department of Sichuan University; Chengdu
  • Received:1985-07-11 Revised:1986-01-13 Published:1986-12-15

Abstract: Based on our previous work, the rule of the ordering of the elements in A matrix has been further studied from the faetorization of G matrix and vibrational frequencies. The Freeman's method for the ordering of λ_i was discussed, and the calculations of some typical examples show that this method is not Valid in general.