Acta Phys. -Chim. Sin. ›› 1995, Vol. 11 ›› Issue (04): 360-364.doi: 10.3866/PKU.WHXB19950415

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Crystal Structure of Dichloro-(5,10,15,20-tetraphenylporphinato) phosphorus(V) Chloride Dichloromethane Solvate

Guo Jin-Liang,Sun Feng,Li Yong,Dong Chang-Xiong   

  1. Department of Chemistry,Tsinghua University,Beijing 100084|Faculty of General Education,Ehime University,Matsuyama 790,Japan
  • Received:1994-04-16 Revised:1994-05-31 Published:1995-04-15
  • Contact: Guo Jin-Liang

Abstract:

The molecular and crystal structure of dichloro (5, 10, 15, 20-tetraphenylporphinato) phosphorus (Ⅴ) chloride dichloromethane solvate has been determined by X-ray difraction analysis. The crystallographic data are listed as follows. Monoclinic system, Space group P21/n, α=10.701(2)Å, b=24.843(3) Å, c=14.785(1) Å ,β=94.251(9)°, V=3919.5(8) Å3 Z=4, Dcalc=1.415g•cm-3.

Key words: Phosphorus porphyrin, X-ray diffraction, Crystal structure