Acta Phys. -Chim. Sin. ›› 1998, Vol. 14 ›› Issue (05): 435-438.doi: 10.3866/PKU.WHXB19980510

• ARTICLE • Previous Articles     Next Articles

The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure

Yu Jian-Feng, Qin Du-Jie, Wu Tong-Hao, Wang Guo-Jia, Sun Jia-Zhong   

  1. Department of Chemistry,Institute Chemistry,Changchun 130023
  • Received:1997-08-29 Revised:1997-12-22 Published:1998-05-15
  • Contact: Yu Jian-Feng

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Abstract:

The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configuration on the substituted ligands was characterizated by the vibration of P-O.

Key words: Transition-metal of the 4th period, Heteropoly complexes with Keggin structure, Lacunary monosubstitution, Vibration of P-O