Acta Phys. -Chim. Sin. ›› 2000, Vol. 16 ›› Issue (09): 776-778.doi: 10.3866/PKU.WHXB20000903

• Communication • Previous Articles     Next Articles

Reaction of C2H3+NO Studied by Time-Resolved Emission Spectroscopy

Feng Wen-Hui, Wang Bao-Shan, Wang Hui, Kong Fan-Ao   

  1. Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080
  • Received:2000-05-23 Revised:2000-06-21 Published:2000-09-15
  • Contact: Kong Fan-Ao E-mail:kong@mrdlab.icas.ac.cn

Abstract:

The elementary reaction of C2H3+ NO has been reported for the first time in this paper.C2H3 radical was produced by laser photolysis of vinyl bromide at 248 nm. Vibrationally excited reaction products H2CO,NCO and HCN were observed. Two exothermic reaction channels leading to HCN+ H2CO and CH3+ NCO are identified.

Key words: NO, C2H3, Reaction, FTIR