Acta Phys. -Chim. Sin. ›› 2001, Vol. 17 ›› Issue (07): 600-603.doi: 10.3866/PKU.WHXB20010705

• ARTICLE • Previous Articles     Next Articles

Orbital Symmetry of the Acetylene on Ru(1010) Surface

Zhang Jian-Hua;Wu Yue;Zhuang You-Yi;Zhang Han-Jie;Li Hai-Yang;He Pi-Mo;Bao Shi-Ning;Liu Feng-Qin;K.Yibulaxin;Qian Hai-Jie   

  1. Physics Department, Zhejiang University,Hangzhou 310027;Laboratory for Synchrotron Radiation,Institute of High Energy Physics,Chinese A cademy of Sciences,Beijing 100039
  • Received:2001-01-11 Revised:2001-02-26 Published:2001-07-15
  • Contact: Bao Shi-Ning E-mail:phybao@dial.zju.edu.cn

Abstract: The acetylene (C2H2) adsorbed on Ru() surface has been studied by usin g angle-resolved ultraviolet photoelectron spectroscopy (ARUPS). The dependence of the σCC peak intensity on incidence angle and emission angle shows that C- C axis of acetylene(C2H2)is not parallel to the Ru() surface(see Fig.2). The C -C axis of acetylene is tilted in <0001> azimuth according to its symmetry(see Fig.3). Not as the acetylene in gas phase,the C-H bond of the acetylene adsorbe d on Ru () surface is not along the direction of the C-C bond.

Key words: Acetylene, Ru(1010) surface, Molecular orbit, Symmetry, ARUPS