Acta Phys. -Chim. Sin. ›› 2006, Vol. 22 ›› Issue (07): 826-830.doi: 10.3866/PKU.WHXB20060711

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Influence of Thermal Initiators on the Electrochemical Performances of Gel Polymer Electrolytes

TANG Ding-Guo;CI Yun-Xiang;QI Lu   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
  • Received:2006-01-16 Revised:2006-03-10 Published:2006-06-27
  • Contact: QI Lu E-mail:qilu@pku.edu.cn

Abstract: Two thermal polymerization initiators, 2,2′-azobisisobutyronitrile(AIBN) and benzoyl peroxide(BPO), commonly used to prepare gel polymer electrolytes (GPEs) for lithium-ion polymer batteries (LiPBs), were studied by thermogravimetry/differential thermal analysis (TG/DTA). The GPEs prepared with thermal initiators showed different electrochemical performances and had great influence on the performance of LiPBs, such as rate capability, temperature reliability, and cycling performance. An appropriate thermal initiator is selected for the GPE system.

Key words: Thermal initiator, Polymerization, Gel polymer electrolyte, Lithium-ion polymer batteries, Electrochemical performance