磷酸盐辅助一步合成介孔Beta分子筛

doi:10.3866/PKU.WHXB20100806

Abstract

Abstract:

The addition of sodium phosphate monobasic (NaH₂PO₄) to a synthetic mixture allows a one-step synthesis of mesoporous Beta zeolite. Aggregation of the nanosized Beta zeolites allows the filtration difficulties to be overcome while the intercrystalline mesopores reduce the diffusion limitation and thus enhance the catalytic activity. The obtained Beta zeolite samples were characterized by X-ray diffraction, scanning electron microscopy, N₂ adsorption-desorption, and temperature-programmed desorption of ammonia. The amount of phosphate strongly influenced the mesopore volume of the Beta zeolites. When the molar ratio of NaH₂PO₄/SiO₂ was 0.1, the sample had good textural and acidic properties and exhibited the best catalytic activity for the alkylation of phenol with tert-butanol.

Key words: Hydrothermal synthesis, Beta zeolite, Mesoporous, Alkylation, Phosphate

MSC2000:

O643.36

LIU Shu-Ping, YUE Ming-Bo, WANG Yi-Meng. One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate[J].Acta Phys. -Chim. Sin., 2010, 26(08): 2224-2228.

References

[1]. Corma, A.; Gomez, V.; Martinez, A. Appl. Catal. A, 1994, 119: 83
[2]. Yang, B. L.; Lu, S. Q.; Wu, J.; Wang, H. J. Chin. J. Catal., 2007, 28(1):73. [杨伯伦, 路士庆, 吴江, 王华军. 催化学报, 2007, 28(1): 73]
[3]. Li, Q.; Dou, T.; Huo, Q.; Xu, Q. H.; Gong, Y. J.; Pan, H. F. Acta Phys. -Chim. Sin., 2008, 24:1192. [李强, 窦涛, 霍全, 徐庆虎, 巩雁军, 潘惠芳. 物理化学学报, 2008, 24: 1192]
[4]. van der Pol, A. J. H. P.; Verduyn, A. J.; van Hooff, J. H. C. Appl. Catal. A, 1992, 92: 113
[5]. Shiralkar, V. P.; Joshi, P. N.; Eapen, M. J.; Rao, B. S. Zeolites, 1991, 11: 511
[6]. Yamamura, M.; Chaki, K.; Wakatsuki, T.; Okado, H. Zeolites, 1994, 14: 643
[7]. Valtchev, V. Chem. Mater., 2002, 14: 956
[8]. Naydenov, V.; Tosheva, L.; Sterte, J. Chem. Mater., 2002, 14: 4881
[9]. Rhodes, K. H.; Davis, S. A.; Caruso, F.; Zhang, B.; Mann, S. Chem. Mater., 2000, 12: 2832
[10]. Dong, A.; Wang, Y.; Tang, Y.; Zhang, Y.; Ren, N.; Gao, Z. Adv. Mater., 2002, 14: 1506
[11]. Wang, Y.; Caruso, F. Adv. Funct. Mater., 2004, 14: 1012
[12]. Wang, X. D.; Yang, W. L.; Tang, Y.; Wang, Y. J.; Fu, S. K.; Gao, Z. Chem. Commun., 2000: 2161
[13]. Tao, Y. S.; Kanoh, H.; Abrams, L.; Kaneko, K. Chem. Rev., 2006, 106: 896
[14]. Perez-Ramirez, J.; Christensen, C. H.; Egeblad, K.; Christensen, C. H.; Groene, J. C. Chem. Soc. Rev., 2008, 37: 2530
[15]. Egeblad, K.; Christensen, C. H.; Kustova, M.; Christensen, C. H. Chem. Mater., 2008, 20: 946
[16]. Groen, J. C.; Abello, S.; Villaescusa, L. A.; Perez-Ramirez, J. Microporous Mesoporous Mat., 2008, 114: 93
[17]. Majano, G.; Mintova, S.; Ovsitser, O.; Mihailova, B.; Bein, T. Microporous Mesoporous Mat., 2005, 80: 227
[18]. Aguado, J.; Serrano, D. P.; Rodriguez, J. M. Microporous Mesoporous Mat., 2008, 115: 504
[19]. Kuechl, D. E.; Benin, A. I.; Knight, L. M.; Abrevaya, H.; Wilson, S. T.; Sinkler, W.; Mezza, T. M.; Willis, R. R. Microporous Mesoporous Mat., 2010, 127: 104
[20]. Choi, M.; Na, K.; Ryoo, R. Chem. Commun., 2009: 2845
[21]. Na, K.; Choi, M.; Ryoo, R. J. Mater. Chem., 2009, 19: 6713
[22]. Zhu, G.; Qiu, S.; Gao, F.; Li, D.; Li, Y. F.; Wang, R. W.; Gao, B.; Li, B. S.; Guo, Y. H.; Xu, R. R.; Liu, Z.; Terasaki, O. J. Mater. Chem., 2001, 11: 1687
[23]. Kang, Y.; Shan, W.; Wu, J.; Zhang, Y.; Wang, X.; Yang, W.; Tang, Y. Chem. Mater., 2006, 18: 1861
[24]. Song, J. W.; Ren, L. M.; Yin, C. Y.; Ji, Y. Y.; Wu, Z. F.; Li, J. X.; Xiao, F. S. J. Phys. Chem. C, 2008, 112: 8609
[25]. Zhu, H.; Liu, Z.; Kong, D.; Wang, Y.; Xie, Z. J. J. Phys. Chem. C, 2008, 112: 17257
[26]. Chen, R.; Gong, Y. J.; Li, Q.; Dou, T.; Zhao, Z.; Xu, Q. H. Acta Phys. -Chim. Sin., 2009, 25(3):539. [陈然, 巩雁军, 李强, 窦涛, 赵震, 徐庆虎. 物理化学学报, 2009, 25(3): 539]
[27]. Kumar, R.; Bhaumik, A.; Ganaphthy, S. Nature, 1996, 381: 298
[28]. Kumar, R.; Mukhrjee, P.; Pandey, R. K.; Rajmohanan, P.; Bhaumik, A. Microporous Mesoporous Mat., 1998, 22: 23
[29]. Fang, Y.; Hu, H.; Chen, G. Chem. Mater., 2008, 20: 1670

One-Step Synthesis of Mesoporous Beta Zeolite Using Phosphate

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