树枝状钯纳米结构的控制合成及硝基苯加氢反应的催化活性

doi:10.3866/PKU.WHXB201207031

Abstract

Abstract:

Branched palladium nanostructures were synthesized under microwave irradiation using polyvinylpyrrolidone (PVP) as stabilizer and benzyl glycol as the reducing agent of H₂PdCl₄. Morphology and structure were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), and X-ray photoelectron spectroscopy (XPS), and showed that the branched Pd nanostructures were self-assemblies of hundreds of small spherical nanoparticles. Furthermore, catalytic properties of the branched Pd nanostructures were investigated for the hydrogenation of nitrobenzene, which indicated that the catalytic activity of the branched Pd nanostructures for this reaction is higher than that of a conventional Pd/C catalyst.

Key words: Palladium, Nanostructure, Microwave irradiation, Hydrogenation of nitrobenzene, Growth process

MSC2000:

O647

XIE Ting, LIU Hao-Wen, YANG Han-Min. Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene[J].Acta Phys. -Chim. Sin., 2012, 28(09): 2209-2213.

References

(1) Boal, A. K.; Ilhan, F.; DeRouchey, J. E.; Thurn-Albrecht, T.;Russell, T. P.; Rotello, V. M. Nature 2000, 404 (3), 746.
(2) Huang, L. Z.;Wang, Y.;Wang, Y. L. Noble Metal 1997, 18 (3),58. [黄黎中, 王瑛, 王永力. 贵金属, 1997, 18 (3), 58.]
(3) Nishihata, Y.; Mizuki, J.; Akao, T.; Tanaka, H.; Uenishi, M.;Kimura, M.; Okamoto, T.; Hamada, N. Nature 2002, 418, 164.doi: 10.1038/nature00893
(4) Huang, L.;Wong, P. K.; Tan, J. J. Phys. Chem. C 2009, 113,10120. doi: 10.1021/jp811188f
(5) Pacardo, D. B.; Sethi, M.; Jones, S. E.; Naik, R. R.; Knecht, M.R. ACS Nano 2009, 3 (5), 1288. doi: 10.1021/nn9002709
(6) Xiong, Y. J.; Xia, Y. N. Advanced Materials 2007, 19, 3385. doi: 10.1002/adma.200701301
(7) Xiong, Y. J.; Chen, J. Y.; Benjamin,W.; Xia, Y. N.; Yin, Y. D.;Li, Z. Y. Nano Letters 2005, 5 (7), 1237. doi: 10.1021/nl0508826
(8) Xiong, Y. J.; Joseph, M. M.; Yin, Y. D.; Xia, Y. N. Angew. Chem. Int. Edit. 2007, 46, 790. doi: 10.1002/anie.200604032
(9) Xiong, Y. J.; Cai, H. G.; Yin, Y. D.; Xia, Y. N. Chemical Physics Letters 2007, 440, 273. doi: 10.1016/j.cplett.2007.04.074
(10) Huang, X. Q.; Tang, S. H.; Mu, X. L.; Dai, Y.; Chen, G. X.;Zhou, Z. Y.; Ruan, F. X.; Yang, Z. L.; Zheng, N. F. Nat. Nanotechnol. 2011, 6, 28.
(11) Huang, X. Q.; Tang, S. H.; Zhang, H. H.; Zhou, Z. Y.; Zheng, N.F. J. Am. Chem. Soc. 2009, 131, 13916. doi: 10.1021/ja9059409
(12) Huang, X. Q.; Tang, S. H.; Yang, J.; Tan, Y. M.; Zheng, N. F.J. Am. Chem. Soc. 2011, 133, 15946. doi: 10.1021/ja207788h
(13) Lin, X. F.; Chen, Z. C.; Lü, D. S.; He, L.; Zhang, D. T. Polymer Science and Engineering 2000, 16 (4), 5. [林贤福, 陈志春,吕德水, 何琳, 张大同. 高分子材料科学与工程, 2000, 16 (4), 5.]
(14) Sun, Z. C.; Bai, F.;Wu, H. M.; Samantha, K. S.; Daniel, M. B.;Jiang, Z.;Wang, J.; Fan, H. Y. Chem. Eur. J. 2009, 15, 11128.doi: 10.1002/chem.200901786
(15) Naka, K.; Sato, M.; Chujo, Y. Langmuir 2008, 24 (6), 2719. doi: 10.1021/la7027109
(16) Zheng, L. Z.; Li, J. H. J. Phys. Chem. B 2005, 109 (3), 1108.doi: 10.1021/jp0456234
(17) Kochkar, H.; Aouine, M.; Ghorbel, A.; Berhault, G. J. Phys. Chem. C 2011, 115, 11364.
(18) Tong, X.; Zhao, Y. X.; Huang, T.; Liu, H. F.; Liew, K. Y. Applied Surface Science 2009, 255, 9463. doi: 10.1016/j.apsusc.2009.07.059
(19) Cheng, C. D.; Ravi, K. G.; Gu, Q.; Haynie, D. T. Nano Letters2005, 5 (1), 175. doi: 10.1021/nl048240q
(20) Chen, Y.; He, B.; Liu, H. J. Mater. Sci. Technol. 2005, 21 (2),187.
(21) Handbook of X-ray Photoelectron Spectroscopy;Wagner, C. D.,Riggs,W. M., Davis, L. E., Moulder, F., Muilenberg, G. E. Eds.;Perkin-Elmer: Phys. Electr. Division, Eden Prairie, 1979.

[1]	Zhicong Sun, Ergui Luo, Qinglei Meng, Xian Wang, Junjie Ge, Changpeng Liu, Wei Xing. High-Performance Palladium-Based Catalyst Boosted by Thin-Layered Carbon Nitride for Hydrogen Generation from Formic Acid [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 2003035-.
[2]	Kangning Zhao, Xiao Li, Dong Su. High-Entropy Alloy Nanocatalysts for Electrocatalysis [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2009077-.
[3]	Ping An, Yu Fu, Danlei Wei, Yanglong Guo, Wangcheng Zhan, Jinshui Zhang. Hollow Nitrogen-Rich Carbon Nanoworms with High Activity for Metal-Free Selective Aerobic Oxidation of Benzyl Alcohol [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2001025-.
[4]	Yuan Zhou, Na Han, Yanguang Li. Recent Progress on Pd-based Nanomaterials for Electrochemical CO₂ Reduction [J]. Acta Physico-Chimica Sinica, 2020, 36(9): 2001041-.
[5]	Ruijie Chen,Di Li,Zhenyuan Fang,Yuanyong Huang,Bifu Luo,Weidong Shi. Controlling Self-Assembly of 3D In₂O₃ Nanostructures for Boosting Photocatalytic Hydrogen Production [J]. Acta Physico-Chimica Sinica, 2020, 36(3): 1903047-.
[6]	Ganxing DONG,Chuanhong JIN. Probing the Controlled Oxidative Etching of Palladium Nanorods by Liquid Cell Transmission Electron Microscopy [J]. Acta Phys. -Chim. Sin., 2019, 35(1): 15-21.
[7]	Yu-Qiao GUAN,Gang CHEN,Juan SONG,Cheng-Xin WANG,Yan QIAN,Qin ZHANG,Ling-Ling DENG,Zeng-Qin FENG,Wen-Juan SHANG,You-Tian TAO,Shu-Fen CHEN,Lian-Hui WANG,Wei HUANG. One-Step Synthesized Novel Spiro[fluorene-9, 9'-xanthene]-Based Materials as Highly Efficient Blue Phosphorescent Hosts in Organic Light-Emitting Devices [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 816-822.
[8]	Yan-Gong ZHENG,Li-Na ZHU,Han-Yu LI,Jia-Wen JIAN,Hai-Ying DU. Operating Mechanism of Palladium Oxide as a Potentiometric Sensing Electrode [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 573-581.
[9]	Qiao-Wan CHANG,Fei XIAO,Yuan XU,Min-Hua SHAO. Core-Shell Electrocatalysts for Oxygen Reduction Reaction [J]. Acta Phys. -Chim. Sin., 2017, 33(1): 9-17.
[10]	Yu-Qiao GUAN,Juan SONG,Wei SUN,Qin ZHANG,Chao TANG,Xue LI,Xiao-Miao FENG,Yan QIAN,You-Tian TAO,Shu-Fen CHEN,Lian-Hui WANG,Wei HUANG. One-Step Synthesis of Spirobi[fluorene] and Spiro[fluorene-9,9′-xanthene] Derivatives and Their Applications in Organic Light-Emitting Devices: Performance Enhancement and Related Optical Phenomena [J]. Acta Phys. -Chim. Sin., 2016, 32(6): 1534-1542.
[11]	Yuan-Yuan WANG,Qun-Xing XU,Hua-Qing XIE,Zi-Hua WU,Jiao-Jiao XING. Monte-Carlo Simulations of the Effect of Surfactant on the Growth of Silver Dendritic Nanostructures [J]. Acta Phys. -Chim. Sin., 2016, 32(10): 2518-2522.
[12]	Liu-Xuan LUO,Shui-Yun SHEN,Feng-Juan ZHU,Jun-Liang ZHANG. Formic Acid Oxidation by Pd Monolayers on Pt₃Ni Nanocubes [J]. Acta Phys. -Chim. Sin., 2016, 32(1): 337-342.
[13]	ZU Guo-Qing, SHEN Jun, WANG Wen-Qin, ZOU Li-Ping, XU Wei-Wei, ZHANG Zhi-Hua. Preparation of Heat-Resistant, Core/Shell Nanostructured TiO₂/SiO₂ Composite Aerogels and Their Photocatalytic Properties [J]. Acta Phys. -Chim. Sin., 2015, 31(2): 360-368.
[14]	Yan-Zhong. HAO,Zhi-Min. GUO,Bao. SUN,Juan. PEI,Shang-Xin. WANG,Ying-Pin. LI. Photoelectrochemical Properties of Hierarchical ZnO Nanosheets Micro-Nanostructure Modified with Sb₂S₃ Nanoparticles [J]. Acta Phys. -Chim. Sin., 2015, 31(11): 2109-2116.
[15]	Hua-Feng. YU,Guo-Pei. ZHANG,Li-Na. HAN,Li-Ping. CHANG,Wei-Ren. BAO,Jian-Cheng. WANG. Cu-SSZ-13 Catalyst Synthesized under Microwave Irradiation and Its Performance in Catalytic Removal of NO_x from Vehicle Exhaust [J]. Acta Phys. -Chim. Sin., 2015, 31(11): 2165-2173.

Control Synthesis of Branched Palladium Nanostructures and the Catalytic Activity on Hydrogenation Reaction of Nitrobenzene

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0