基于自交联杂萘联苯聚芳醚阴离子交换膜制备及其物理化学性质

doi:10.3866/PKU.WHXB201310214

Abstract

Abstract:

Self-crosslinked poly(phthalazinone ether ketone) anion-exchange membranes (AEMs) were successfully fabricated from chloromethylated poly(phthalazinone ether ketone) (CMPPEK) by amination, membrane casting, and OH-exchange reaction steps. Triethylamine (TEA) was used as an ammonium agent, and diethylenetriamine (DETA) and diethylamine (DEA) were used as self-crosslinking agents in the quaternary reaction of CMPPEK, resulting in DETA-QPPEK-OH and DEA-QPPEK-OH AEMs, respectively. The chemical structures of DETA-QPPEK-OH and DEA-QPPEK-OH were characterized using Fourier transform infrared (FTIR) spectroscopy. The physicochemical properties of these AEMs were investigated including ion-exchange capacity (IEC), swelling ratios, water uptake, and ionic conductivities at 30 ℃. The results showed that the swelling ratio of the DETA-crosslinked AEM was lower than that of the DEAcrosslinked AEM. This could be attributed to multi-crosslinking of multi-amino groups in the DETA structure. The temperature dependences of the ionic conductivities of the AEMs were measured from 30 to 80 ℃. The ionic conductivities of the DEA-crosslinked and DETA-crosslinked AEMs were 0.060 and 0.028 S·cm^-1 at 80 ℃, respectively. The thermal stabilities of the resulting DETA-QPPEK-OH and DEAQPPEK-OH membranes were investigated using thermogravimetric analysis (TGA), under a nitrogen atmosphere. The obtained membranes have high dimensional stabilities and are very promising for potential applications in anion-exchange membrane fuel cells (AEMFCs).

Key words: Anion exchange membrane, Alkaline fuel cell, Poly(phthalazinone ether ketone), Diethylenetriamine, Self-crosslinking, Conductivity

MSC2000:

O646

LIU De-Zhi, HOU Xi-Xin, ZHU Xiu-Ling, WANG Rui, JING Jian, CUI Yue. Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes[J].Acta Phys. -Chim. Sin., 2013, 29(12): 2573-2578.

References

(1) Yi, B. L. Fuel Cell——A High Efficient and Environmental Friendly Power Generation; Chemical Industry Press: Beijing,2000; p 32. [衣宝廉. 燃料电池——高效环境友好的发电方式. 北京: 化学工业出版社, 2000: 32.]
(2) Zhou, Y. H. Chin. J. Power Sources 1996, 20, 161. [周运鸿. 电源技术, 1996, 20, 161.]
(3) Schultz, M. G.; Diehl, T.; Brasseur, G. P.; Zittel,W. Science2003, 302, 624. doi: 10.1126/science.1089527
(4) Inzelt, G.; Pineri, M.; Schultze, J.W.; Vorofyntsev, M. A.Electrochim. Acta 2000, 45, 2403. doi: 10.1016/S0013-4686(00)00329-7
(5) Varcoe, J. R.; Slade, R. C. T.; Yee, E. L. H. Chem. Commun.2006, 1428.
(6) Lu, S.; Pan, J.; Huang, A.; Zhuang, L. Proc. Natl. Acad. Sci. U. S. A. 2008, 105, 20611. doi: 10.1073/pnas.0810041106
(7) Ye, Y.; Elabd, Y. A. Macromolecule 2011, 44, 8494. doi: 10.1021/ma201864u
(8) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
(9) Liu, Z. Cross-linked Alkaline Exchange Membrane for FuelCell. Master's Thesis, Dalian University of Technology, Dalian,2011. [刘陟. 交联型燃料电池用阴离子交换膜的制备研究[D]. 大连: 大连理工大学, 2011.]
(10) Chen, Y. L.; Meng, Y. Z.; Hay, A. S. Macromolecules 2005, 38,3564. doi: 10.1021/ma047591o
(11) Zhu, X.; Liang, Y.; Pan, H.; Jian, X.; Zhang, Y. J. Membr. Sci.2008, 312, 59. doi: 10.1016/j.memsci.2007.12.058
(12) Pan, H.; Zhu, X.; Chen, J.; Jian, X. J. Membr. Sci. 2009, 326,453. doi: 10.1016/j.memsci.2008.10.047
(13) Gao, Y.; Robertson, G. P.; Guiver, M. D.; Jian, X. G. J. Polym. Sci. Part A: Polym. Chem. 2003, 41, 497.
(14) Zhang, S.; Yin, C.; Xing, D.; Yang, D.; Jian, X. J. Membr. Sci.2010, 363, 243. doi: 10.1016/j.memsci.2010.07.046
(15) Zhang, H.; Zhou, Z. J. Applied Polym. Sci. 2008, 110, 1756. doi: 10.1002/app.v110:3
(16) Fang, J.; Shen, P. K. J. Membr. Sci. 2006, 285, 317.
(17) Pan, J.; Chen, C.; Zhuang, L.; Lu, J. Accounts Chem. Res. 2012,45, 473. doi: 10.1021/ar200201x
(18) Pan, J.; Li, Y.; Zhuang, L.; Lu, J. Chem. Commun. 2010, 46,8597. doi: 10.1039/c0cc03618h
(19) Zhao, Y.; Yu, H.; Yang, D.; Li, J.; Shao, Z.; Yi, B. J. Power Sources 2013, 221, 247.
(20) Sun, H.; Zhang, G.; Liu, Z.; Zhang, N.; Zhang, L.; Ma,W.;Zhao, C.; Qi, D.; Li, G.; Na, H. Int. J. Hydrog. Energy 2012, 37,9873. doi: 10.1016/j.ijhydene.2012.03.115
(21) Gu, S.; Cai, R.; Yan, Y. Chem. Commun. 2011, 47, 2856. doi: 10.1039/c0cc04335d
(22) Yan, C.; Zhang, S.; Yang, D.; Jian, X. J. Appl. Polym. Sci. 2008,107, 1809.

[1]	Kunjie Wu, Yongyi Zhang, Zhenzhong Yong, Qingwen Li. Continuous Preparation and Performance Enhancement Techniques of Carbon Nanotube Fibers [J]. Acta Phys. -Chim. Sin., 2022, 38(9): 2106034-.
[2]	Xinrun Yu, Jun Ma, Chunbo Mou, Guanglei Cui. Percolation Structure Design of Organic-inorganic Composite Electrolyte with High Lithium-Ion Conductivity [J]. Acta Phys. -Chim. Sin., 2022, 38(3): 1912061-.
[3]	Houfu Song, Feiyu Kang. Recent Progress on Thermal Conduction of Graphene [J]. Acta Phys. -Chim. Sin., 2022, 38(1): 2101013-.
[4]	Runlin Fan, Yuhang Peng, Hao Tian, Junsheng Zheng, Pingwen Ming, Cunman Zhang. Graphite-Filled Composite Bipolar Plates for Fuel Cells: Material, Structure, and Performance [J]. Acta Phys. -Chim. Sin., 2021, 37(9): 2009095-.
[5]	Yaokun Ye, Zongxiang Hu, Jiahua Liu, Weicheng Lin, Taowen Chen, Jiaxin Zheng, Feng Pan. Research Progress of Theoretical Studies on Polarons in Cathode Materials of Lithium-Ion Batteries [J]. Acta Phys. -Chim. Sin., 2021, 37(11): 2011003-.
[6]	Guanghai Chen,Ying Bai,Yongsheng Gao,Feng Wu,Chuan Wu. Chalcogenide Electrolytes for All-Solid-State Sodium Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1905009-.
[7]	Laiqiang Xu,Jiayang Li,Cheng Liu,Guoqiang Zou,Hongshuai Hou,Xiaobo Ji. Research Progress in Inorganic Solid-State Electrolytes for Sodium-Ion Batteries [J]. Acta Physico-Chimica Sinica, 2020, 36(5): 1905013-.
[8]	Ting ZHANG,Jie SHEN. Aggregation Properties and Thermodynamics of Micellization of Gemini Surfactants with Diester and Rigid Spacers in Organic Alcohol-Water Mixed Media [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 795-802.
[9]	Qi-Ge ZHENG,Hui LIU,Quan XIA,Qing-Shan LIU,Lin MOU. Density, Dynamic Viscosity and Electrical Conductivity of Two Hydrophobic Phosphonium Ionic Liquids [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 736-744.
[10]	Yi-Fen GAO,Gui-Lin ZHUANG,Jia-Qi BAI,Xing ZHONG,Jian-Guo WANG. Temperature-Dependent Conductivity, Luminescence and Theoretical Calculations of a Novel Zn (Ⅱ)-Based Metal-Organic Framework [J]. Acta Phys. -Chim. Sin., 2017, 33(1): 242-248.
[11]	Wen-Hao WU,Xin-Yu HUANG,Rui-Min YAO,Ren-Jie CHEN,Kai LI,Ru-Qiang ZOU. Synthesis and Properties of Polyurethane/Coal-Derived Carbon Foam Phase Change Composites for Thermal Energy Storage [J]. Acta Phys. -Chim. Sin., 2017, 33(1): 255-261.
[12]	Bao-Lin AN,Fu-Fang YANG,Zhen YANG,Yuan-Yuan DUAN,Yang-Xin YU. Measurements of the Viscosity and Thermal Conductivity of a Gas at Definitive Thermodynamic States [J]. Acta Phys. -Chim. Sin., 2016, 32(5): 1129-1133.
[13]	Qing-Shan LIU,Hui LIU,Lin MOU. Properties of 1-(Cyanopropyl)-3-methylimidazolium Bis[(trifluoromethyl)sulfonyl]imide [J]. Acta Phys. -Chim. Sin., 2016, 32(3): 617-623.
[14]	Ling ZHENG,Yi PAN,Hong-Xiang JI,Xiao-Xue MA,Nan-Nan XING,Wei GUAN. Evaluation of the Walden Product of Ionic Liquids Using Experiments and a New Theory: An Ion Exchange Transition Model [J]. Acta Phys. -Chim. Sin., 2016, 32(11): 2663-2670.
[15]	Xiang-Lai. XIA,Lin-Yan. LI,Fang. GUO,Wei. SU,Yan. LIU,Xiao-Mou. CHEN,She-Qi. PAN. Simulation of the Immobilization of Pu in the Gd₂Zr₂O₇ Matrix by Investigating the Thermophysical Properties of (Gd_1-xCe_x)₂Zr₂O_7+x [J]. Acta Phys. -Chim. Sin., 2015, 31(9): 1810-1814.

Preparation and Physicochemical Property of Self-Crosslinked Poly(phthalazinone ether ketone) Anion-Exchange Membranes

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0