Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols

doi:10.3866/PKU.WHXB201601081

Abstract

Abstract:

Sound velocity, density, and viscosity values have been measured at T = 303 K for four binary systems of morpholine + methanol, ethanol, 1-propanol, and 1-butanol. From these data, acoustical parameters, such as adiabatic compressibility, free length, free volume, and internal pressure, have been estimated using the standard relations. The results are interpreted in terms of the molecular interaction between the components of the mixtures. The observed excess values in all the mixtures indicate that the molecular symmetry existing in the system is highly disturbed by the addition of morpholine molecules. The interaction energy terms of the statistical mixing are also verified for these binary systems, and the dipole-dipole interactions are found to be predominant and are greatly affected by the chain length of the primary alkanols.

Key words: Ultrasonic velocity, Acoustic parameter, Dipolar interaction, Interaction

B. PRIYA,L. PALANIAPPAN. Effect of Chain Length on the Dipolar Interaction of Morpholine with Primary Alkanols[J].Acta Phys. -Chim. Sin., 2016, 32(4): 855-862.

References

1	Nithiyanantham S. ; Palaniappan L. ; Lenin M. Journal of Bionanosciences 2015, 9, 4.
2	Palaniappan L. Physica B 2008, 403, 3887.
3	Palaniappan L. ; Jaafar M. S. Main Group Chemistry 2009, 8, 89.
4	https://en.wikipedia.org/wiki/morpholine (accessed Nov 20, 2015)
5	Parkin A. ; Oswald I. ; Parsons S. Acta Cryst. 2004, B60, 219.
6	Gontrani L. ; Ramondo F. ; Caracciolo G. ; Caminiti R. Journal of Molecular Liquids 2008, 139, 23.
7	Jones P. G. ; Taouss C. ; Teschmit N. ; Thomas L. Acta Cryst 2013, B69, 405.
8	Klampfl C.W. Electrophoresis 2006,, 27 (Special Issue), 3.
9	Torchilin V. P. Nature Reviews Drug Discovery 2005, 4, 145.
10	Li Q. ; He Y. C. ; Xian M. ; Jun G. ; Xu X. ; Yang J. M. ; Li L. Z. Bioresource Technology 2009, 100, 3570.
11	Zhao H. ; Jones C. L. ; Baker G. A. ; Xia S. ; Olubajo O. Journal of Biotechnology 2009, 139, 47.
12	Nath J. ; Chaudhuri M. K. Catalysis Letters 2009, 133, 388.
13	Cheng H. ; Ma H. Journal of Salt and Chemical Industry 2012, 4, 19.
14	Haller J. ; Miecznik P. ; Kaatze U. Chem. Phys. Lett. 2006, 429, 97.
15	Baluja S. ; Parsania P. H. J. Pure Appl. Ultrason 1997, 19, 36.
16	Palaniappan L. ; Arul G. J. Acoust. Soc. India 2000, 28, 393.
17	Lide, D. R. Handbook of Chemistry and Physics, 81st ed.; CRC Press: Boca Raton, FL, 2000.
18	Williams G. The Theory of Resonance; JohnWiley: New York 1979.
19	Dean J. A. Lange's Handbook of Chemistry, 13th ed.; McGraw Hill International: New York 1987.
20	Kell G. S. J. Chem. Engg. Data 1975, 20, 97.
21	Arul G. ; Palaniappan L. Indian J. Pure Appl. Phys. 2005, 43, 755.
22	Subrahmanian B. Text Book on Sound, 5th ed.; New Delhi: S. Chand Publishers 1998.
23	Miecznik P. ; Golebiewski Z. ; Mielcarek S. Fluid Phase Equilibria 2004, 221, 41.
24	Sundharam N. ; Palaniappan L. Indian J. Phys. 2005, 79, 1173.
25	Suryanarayana C. V. ; Kuppusamy J. J. Acoust. Soc. India 1976, 4, 75.
26	Suryanarayana C. V. ; Govindasamy S. Acta Chim. Hung. 1960, 25, 341.
27	Peters E. I. Introduction to Chemical Principles, 3rd ed.; CBS College Publishing: Philadelphia 1982.
28	Palaniappan L. Indian J. Phys 2001, 75B, 515.
29	Vogel I. Practical Organic Chemistry; Orient Longman: London, 1978.
30	Sasikumar P. ; Thiyagarajan R. ; Palaniappan L. J. Indian Chem. Soc. 2015, 92, 991.
31	Ali A. ; Sabir S. ; Tariq M. Acta Phys. -Chim. Sin. 2007, 23, 79.
32	Nikam P. S. ; Mehdi H. J. Chem. Eng. Data 1988, 33, 165.
33	Palaniappan L. ; Devadoss D. ; Thairiyaraja M. Indian J. Phys 2003, 77B, 679.
34	Karthikeyan V. ; Palaniappan L. Indian J. Phys. 2005, 79, 153.
35	Vadivel S. ; Palaniappan L. Indian J. Phys. 2005, 79, 1383.
36	Nikam P. S. ; Kapade V. M. ; Hasan M. Indian J. Pure Appl. Phys. 2000, 38, 170.
37	https://en.wikipedia.org/wiki/Alcohol (accessed Nov 20, 2015)
38	Israelachvili J. N. Intermolecular and Surface Forces, 2nd ed.; Academic Press: New York 1992.
39	Ababneh A. M. ; Large C. C. ; Georghiou S. Biophysical Journal 2003, 85, 1111.

[1]	Xibao Li, Jiyou Liu, Juntong Huang, Chaozheng He, Zhijun Feng, Zhi Chen, Liying Wan, Fang Deng. All Organic S-Scheme Heterojunction PDI-Ala/S-C₃N₄ Photocatalyst with Enhanced Photocatalytic Performance [J]. Acta Phys. -Chim. Sin., 2021, 37(6): 2010030-0.
[2]	Congming Li, Kuo Chen, Xiaoyue Wang, Nan Xue, Hengquan Yang. Understanding the Role of Cu/ZnO Interaction in CO₂ Hydrogenation to Methanol [J]. Acta Phys. -Chim. Sin., 2021, 37(5): 2009101-0.
[3]	Zhaobi Xing,Zhijun Guo,Yuwei Zhang,Junling Liu,Yujie Wang,Guangyue Bai. Regulation of SDS on the Surface Charge Density of SB3-12 Micelles and Its Effect on Drug Dissolution [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1906006-0.
[4]	Wen Xie,Lianjiao Zhou,Juan Xu,Qinglian Guo,Fenglei Jiang,Yi Liu. Advances in Biothermochemistry and Thermokinetics [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905051-0.
[5]	Fenfen Wang, Peng Wang, Hongyao Niu, Yingfeng Yu, Pingchuan Sun. Solid-State NMR Studies on Hydrogen Bonding Interactions and Structural Evolution in PAA/PEO Blends [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1912016-0.
[6]	Junyan Xiao, Limin Qi. Controllable Self-Assembly of Gold Nanorods via Host–Guest Interaction between Cyclodextrins and Surfactants [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1910001-0.
[7]	Chengcheng Zhang, Ralph Crisci, Zhan Chen. Probing Molecular Structures of Antifouling Polymer/Liquid Interfaces In Situ [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1910003-0.
[8]	Guanqing Sun, Zonglin Yi, To Ngai. Particle-Stabilized Interfaces and Their Interactions at Interfaces [J]. Acta Physico-Chimica Sinica, 2020, 36(10): 1910005-0.
[9]	Jinxiu Zhan,Feng Feng,Min Xu,Li Yao,Maofa Ge. Progress in Chemo–Mechanical Interactions between Nanoparticles and Cells [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1905076-0.
[10]	Minyi Su,Huisi Liu,Haixia Lin,Renxiao Wang. Machine-Learning Model for Predicting the Rate Constant of ProteinLigand Dissociation [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907006-0.
[11]	Yanyan Qin, Pengfei She, Song Guo, Xiaomeng Huang, Shujuan Liu, Qiang Zhao, Wei Huang. Structural Manipulation and Triboluminescence of Tetrahalomanganese(Ⅱ) Complexes [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907078-0.
[12]	Changsheng Zhang,Luhua Lai. Physiochemical Mechanisms of Biomolecular Liquid-Liquid Phase Separation [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907053-0.
[13]	Tao ZHANG,Yunguang QIU,Qichao LUO,Xi CHENG,Lifen ZHAO,Xin YAN,Bo PENG,Hualiang JIANG,Huaiyu YANG. Concentration Dependent Effects of Ca²⁺ and Mg²⁺ on the Phosphatidylethanolamine-Phosphatidylglycerol Bilayer [J]. Acta Physico-Chimica Sinica, 2019, 35(8): 840-849.
[14]	Wen XIE,Huan HE,Jiaxin DONG,Qinglian GUO,Yi LIU. Thermodynamics of the Interaction of Morin with Bovine Serum Albumin [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 725-733.
[15]	Siqi LUO,Meina WANG,Weiwei ZHAO,Yilin WANG. Interactions between Surfactants and Folic Acid and the Effects of Surfactants on the Photodegradation of Folic Acid [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 766-774.