三个不同穿插的锌配合物的合成、结构和热动力学分析

doi:10.3866/PKU.WHXB201603102

Acta Phys. -Chim. Sin. ›› 2016, Vol. 32 ›› Issue (6): 1397-1403.doi: 10.3866/PKU.WHXB201603102

• ARTICLE • Previous Articles Next Articles

Synthesis, Structure and Thermodynamics/Kinetics Analysis of Three Different Interpenetrating Zinc(Ⅱ) Coordination Architectures

Tian HE¹,Ke-Fen YUE^1,*(),San-Ping CHEN¹,Chun-Sheng ZHOU^2,*(),Ni YAN¹

¹ Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education,College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China
² Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, College of Chemical Engineering and Modern Materials,Shangluo University, Shangluo 726000, Shaanxi Province, P. R. China

Received:2016-01-25 Published:2016-06-03
Contact: Ke-Fen YUE,Chun-Sheng ZHOU E-mail:ykflyy@nwu.edu.cn;slzhoucs@126.com.cn
Supported by:
National Natural Science Foundation of China(21543001, 21273137);Open Foundation of Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, China(338080041);Open Foundation of the Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, China(2014SKY-WK002)

Abstract

Abstract:

Based on flexible 1,4-bis(2-methyl-imidazol-1-yl)butane (bib) and three rigid line-shaped carboxylate mix-ligands, three Zn(Ⅱ) coordination polymers, {[Zn₂(bib)₂(1,4-ndc)₂]·H₂O}_n (1), {[Zn_0.5(bib)_0.5(bdc-Br₂)_0.5]·0.5H₂O}_n (2), {[Zn₂(bib) (4,4'- bpdc)₂]·H₂O}_n (3) (1,4-H₂ndc=1,4-naphthalenedicarboxylic acid, H₂bdc-Br₂=2,5-dibromoterephthalic acid, 4,4'-H₂bpdc=4,4'- biphenyldicarboxylic acid) have been synthesized under solvothermal conditions and characterized by elemental analysis, infrared (IR) spectrometry, and single crystal X-ray diffraction. 1 presents a 4-fold interpenetrating framework including three kinds of zigzag chains. 2 exhibits an unusual [2+2] interpenetrating framework. 3 features a 3-fold interpenetrating network. Their thermal decomposition behaviors were investigated by simultaneous thermogravimetry/differential thermal gravity and differential scanning calorimetry (TG/DTG-DSC) techniques. The TG curves indicate that the unusual [2+2] interpenetrating framework exhibits the highest thermal stability of the three frameworks, and the 4- fold interpenetrating framework exhibits higher thermal stability than the 3-fold interpenetrating framework. The thermodynamics and kinetics of skeleton collapse for the complexes were calculated by the integral Kissinger's method and Ozawa-Doyle's method. The activation energies (E) of 276.887, 318.515, and 149.310 kJ·mol^-1 illustrate the relationship of the reaction rates of complexes 1-3: 3 ＞ 1 ＞ 2. The structural characteristics could be elucidated from the thermodynamics and kinetics. Moreover, the fluorescent properties of complexes 1-3 were also studied.

Key words: Coordination polymer, Interpenetration, Thermodynamics, Kinetics

MSC2000:

O641

Click here to download Supporting Info material in PDF type

Tian HE,Ke-Fen YUE,San-Ping CHEN,Chun-Sheng ZHOU,Ni YAN. Synthesis, Structure and Thermodynamics/Kinetics Analysis of Three Different Interpenetrating Zinc(Ⅱ) Coordination Architectures[J].Acta Phys. -Chim. Sin., 2016, 32(6): 1397-1403.

References

1	Wu H. H. ; Liu Y. ; Liu Y. Y. ; Yang J. ; Liu B. ; Ma J. F. Chem. Commun 2011, 47, 1818.
2	Liu Z. Y. ; Yang E. C. ; Li L. L. ; Zhao X. J. Dalton Trans 2012, 41, 6827.
3	Parshamoni S. ; Jena H. S. ; Sanda S. ; Konar S. Inorg. Chem. Front 2014, 1, 611.
4	He Y. B. ; Li B. ; O'Keeffec M. C. Chem. Soc. Rev 2014, 43, 5618.
5	Weller M. T. ; Henry P. F. ; Wilson C. C. J.Phys. Chem. B 2000, 104, 12224.
6	Liu J. ; Liu M. Y. ; Nguyen J. B. J.Am. Chem. Soc 2009, 131, 8750.
7	Guilmard M. ; Croguennec L. ; Delmas C. Chem. Mater 2003, 15, 4484.
8	Wen T. ; Zhang D. X. ; Zhang H. X. ; Zhang H. B. ; Zhang J. ; Li D. S. Chem. Commun 2014, 50, 8754.
9	Zuo Y. ; Fang M. ; Xiong G. ; Shi P. F. ; Zhao B. ; Cui J. Z. ; Cheng P. Cryst. Growth Des 2012, 12, 3917.
10	Tong X. Q. ; Yan W. F. ; Yu J. H. ; Xu R. R. Chem. Commun 2013, 49, 11287.
11	Han M. L. ; Duan Y. P. ; Li D. S. ; Xu G. W. ; Wu Y. P. ; Zhao J. Dalton Trans 2014, 43, 17519.
12	Chang X. H. ; Qin J. H. ; Han M. L. ; Ma L. F. ; Wang L. Y. CrystEngComm 2014, 16, 870.
13	Liu Y. L. ; Yue K. F. ; Li D. S. ; Yu Y. ; Hou L. ; Wang Y. Y. CrystEngComm 2013, 15, 2791.
14	Hou Y. F. ; Liu B. ; Yue K. F. ; Zhou C. S. ; Wang Y. M. ; Yan N. ; Wang Y. Y. CrystEngComm 2014, 16, 9560.
15	Li X. Y. ; Han C. X. ; Yue K. F. ; Liu Y. L. ; Zhou C. S. ; Hou Y. F. ; He T. ; Yan N. Polyhedron 2015, 87, 156.
16	Huang X. Y. ; Yue K. F. ; Jin J. C. ; Liu J. Q. ; Wang Y. Y. Inorg. Chem. Commun 2010, 13, 338.
17	Sheldrick, G. M. SHELXL, version 6.12; Bruker Analytical Instrumentation: Madison, WI, 2000.
18	Li X. Y. ; Liu X. X. ; Yue K. F. ; Wu Y. P. ; He T. ; Yan N. RSC Adv 2015, 5, 81689.
19	Kissinger H. E. Anal. Chem 1957, 29, 1702.
20	Ozawa T. Bull. Chem. Soc. Jpn 1965, 38, 1881.
21	Doyle C. D. J.Appl. Polym. Sci 1961, 15, 285.
22	Straszko J. ; Olstak-Humienik M. ; Mozejko J. Thermochim. Acta 1997, 292, 145.
23	Olstak-Humienik M. ; Mozejko J. Thermochim. Acta 2000, 344, 73.
24	Fu X. C. ; Chen R. H. Physical Chemistry, Part 2Beijing:Peoples Education Press, 1979, 214.
24	傅献彩; 陈瑞华.物理化学.下册,北京:人民教育出版社, 1979, 214.
25	Zhang L. ; Li Q. Z. J. ; Lin P. ; Qin Y. Y. ; Zhang J. ; Yin P. X. ; Cheng J. K. ; Yao Y. G. Inorg. Chem 2009, 48, 6517.
26	Meng F. J. ; Jia H. Q. ; Hu N. H. ; Xu J. W. Inorg. Chem. Commun 2013, 28, 41.
27	Li S. L. ; Lan Y. Q. ; Ma J. F. ; Fu Y. M. ; Yang J. ; Ping G. J. ; Liu J. ; Su Z. M. Cryst. Growth Des 2008, 8, 1610.
28	Chen W. J. ; Wang Y. ; Chen C. ; Yue Q. ; Yuan H. M. ; Chen J. S. ; Wang S. N. Inorg. Chem 2003, 42, 944.
29	Zhang X. M. ; Tong M. L. ; Gong M. L. ; Chen X. M. Eur. J.Inorg. Chem 2003, 1, 138.

[1]	Ning Ren,Fang Wang,Jianjun Zhang,Xinfang Zheng. Progress in Thermal Analysis Kinetics [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905062-0.
[2]	Ting Zhang,Cuicui Li,Wei Wang,Zhaoqi Guo,Aimin Pang,Haixia Ma. Construction of Three-Dimensional Hematite/Graphene with Effective Catalytic Activity for the Thermal Decomposition of CL-20 [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905048-0.
[3]	Jing Miao,Ruifeng Guo,Zhihong Liu. Preparation of BaO·4B₂O₃·5H₂O Nanomaterial and Evaluation of Its Flame Retardant Performance to PP by Thermal Decomposition Kinetics Method [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905052-0.
[4]	Wen Xie,Lianjiao Zhou,Juan Xu,Qinglian Guo,Fenglei Jiang,Yi Liu. Advances in Biothermochemistry and Thermokinetics [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905051-0.
[5]	Chengfang Qiao,Lei Lü,Wenfeng Xu,Zhengqiang Xia,Chunsheng Zhou,Sanping Chen,Shengli Gao. Synthesis, Thermal Decomposition Kinetics and Detonation Performance of a Three-Dimensional Solvent-Free Energetic Ag(I)-MOF [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905085-0.
[6]	Fanghong Qin, Ting Wan, Jiangyuan Qiu, Yihui Wang, Biyuan Xiao, Zaiyin Huang. Temperature Effects on Photocatalytic Heat Changes and Kinetics via In Situ Photocalorimetry-Fluorescence Spectroscopy [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905087-0.
[7]	Yucheng He, Kefeng Xie, Youhao Wang, Dongshan Zhou, Wenbing Hu. Characterization of Polymer Crystallization Kinetics via Fast-Scanning Chip-Calorimetry [J]. Acta Physico-Chimica Sinica, 2020, 36(6): 1905081-0.
[8]	Minyi Su,Huisi Liu,Haixia Lin,Renxiao Wang. Machine-Learning Model for Predicting the Rate Constant of ProteinLigand Dissociation [J]. Acta Physico-Chimica Sinica, 2020, 36(1): 1907006-0.
[9]	Wen XIE,Huan HE,Jiaxin DONG,Qinglian GUO,Yi LIU. Thermodynamics of the Interaction of Morin with Bovine Serum Albumin [J]. Acta Phys. -Chim. Sin., 2019, 35(7): 725-733.
[10]	Paul GEERLINGS,Frank DE PROFT,Stijn FIAS. Analogies between Density Functional Theory Response Kernels and Derivatives of Thermodynamic State Functions [J]. Acta Phys. -Chim. Sin., 2018, 34(6): 699-707.
[11]	Xue HAN,Jin YANG,Yingying LIU,Jianfang MA. Syntheses and Luminescent Properties of Coordination Polymers Based on 1, 2, 4-Triazole-Substituted Resorcin[4]arene [J]. Acta Phys. -Chim. Sin., 2018, 34(5): 476-482.
[12]	Changjiang LIU,Hongwen MA,Pan ZHANG. Thermodynamics of the Hydrothermal Decomposition Reaction of Potassic Syenite with Zeolite Formation [J]. Acta Phys. -Chim. Sin., 2018, 34(2): 168-176.
[13]	Fang CHENG,Han-Qi WANG,Kuang XU,Wei HE. Preparation and Characterization of Dithiocarbamate Based Carbohydrate Chips [J]. Acta Phys. -Chim. Sin., 2017, 33(2): 426-434.
[14]	Hai-Yang YU,Fang WANG,Qi-Chun LIU,Qing-Yu MA,Zheng-Gui GU. Structure and Kinetics of Thermal Decomposition Mechanism of Novel Silk Fibroin Films [J]. Acta Phys. -Chim. Sin., 2017, 33(2): 344-355.
[15]	Ming XIAO,Zai-Yin HUANG,Huan-Feng TANG,Sang-Ting LU,Chao LIU. Facet Effect on Surface Thermodynamic Properties and In-situ Photocatalytic Thermokinetics of Ag₃PO₄ [J]. Acta Phys. -Chim. Sin., 2017, 33(2): 399-406.

Synthesis, Structure and Thermodynamics/Kinetics Analysis of Three Different Interpenetrating Zinc(Ⅱ) Coordination Architectures

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Supporting Info

Cite this article

share this article

References

Related Articles 15

Metrics

Comments

Recommended 0