ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2009,Vol.25>> Issue(01)>> 79-85     doi: 10.3866/PKU.WHXB20090114         中文摘要
Simultaneous Catalytic Removal of NOx and Diesel Soot over Cu-Containing Hydrotalcite Derived Catalysts
WANG Zhong-Peng; CHEN Ming-Xia; SHANGGUAN Wen-Feng
Research Center for Combustion and Environmental Technology, School of Mechanical and Power Engineering, Shanghai Jiao Tong University, Shanghai 200240, P. R. China; School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, P. R. China
Full text: PDF (316KB) Export: BibTeX | EndNote (RIS)
Copper-containing mixed oxides (CuAlO) were derived from hydrotalcites and prepared by co-precipitation and thermal evolution methods. The catalytic activity of the CuAlO was investigated for the simultaneous catalytic removal of NOx and diesel soot particulates by a temperature-programmed reaction (TPR) technique in a fixed-bed flow reactor. CuAlO showed good activity for the NOx-soot removal reaction under both tight and loose contact conditions. When the contact conditions between catalyst and soot changed from tight to loose, the ignition temperature (Ti) increased from 260 ℃ to 314 ℃ while the maximum conversion of NO to N2 (XN2-max) decreased from 40.4%to 29.2%. Soot content had no effect on the ignition temperature and all the Ti values were about 260 ℃ for different soot content. With an increase in NO concentration or O2 concentration the Ti value decreased. XN2-max values were about 40% when the O2 concentration changed from 2.5% to 7.5%. The total flow rate had no effect on the Ti values, while the XN2-max decreased from40.4%to 21.6%when the total flowrate increased from20 to 80 mL·min-1. Catalytic activity decreased when the catalyst was reused and this decrease may be related to an intermediate absorbed on the catalyst surface.

Keywords: Hydrotalcite   Mixed oxide   Soot   NOx   Catalytic removal  
Received: 2008-07-14 Accepted: 2008-10-07 Publication Date (Web): 2008-11-12
Corresponding Authors: SHANGGUAN Wen-Feng Email:

Cite this article: WANG Zhong-Peng; CHEN Ming-Xia; SHANGGUAN Wen-Feng. Simultaneous Catalytic Removal of NOx and Diesel Soot over Cu-Containing Hydrotalcite Derived Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25 (01): 79-85.    doi: 10.3866/PKU.WHXB20090114
1. LI Hong-Mei, LAN Li, CHEN Shan-Hu, LIU Da-Yu, WANG Wei, GONG Mao-Chu, CHEN Yao-Qiang.Preparation of CeO2-ZrO2-Al2O3 with a Composite Precipitant and Its Supported Pd-Only Three-Way Catalyst[J]. Acta Phys. -Chim. Sin., 2016,32(7): 1734-1746
2. SUN Meng-Ting, HUANG Bi-Chun, MA Jie-Wen, LI Shi-Hui, DONG Li-Fu.Morphological Effects of Manganese Dioxide on Catalytic Reactions for Low-Temperature NH3-SCR[J]. Acta Phys. -Chim. Sin., 2016,32(6): 1501-1510
3. LIU Xiao-Qing, LI Shi-Hui, SUN Meng-Ting, YU Cheng-Long, HUANG Bi-Chun.Preparation, Characterization and Low-Temperature NH3-SCR Activity of MnOx/SAPO-11 Catalysts[J]. Acta Phys. -Chim. Sin., 2016,32(5): 1236-1246
4. LIU Jie-Xiang, REN Ji-Hui, ZHAO Qiao, SHI Ting-Jing, LIU Zhi-Fang, LUO Zhao, ZHANG Xiao-Guang.Preparation and Characterization of Chlorpyrifos/Cyclodextrin Complex Intercalation into ZnAl-Layered Double Hydroxide[J]. Acta Phys. -Chim. Sin., 2016,32(2): 558-564
5. JIAO Jin-Zhen, LI Shi-Hui, HUANG Bi-Chun.Preparation of Manganese Oxides Supported on Graphene Catalysts and Their Activity in Low-Temperature NH3-SCR[J]. Acta Phys. -Chim. Sin., 2015,31(7): 1383-1390
6. XIE Xing-Xing, FEI Zhao-Yang, ZOU Chong, LI Zheng-Zhou, CHEN Xian, TANG Ji-Hai, CUI Mi-Fen, QIAO Xu.Effects of Rare-Earth Additives on Structures and Performances of CuO-CeO2-SiO2 Catalysts for Recycling Cl2 from HCl Oxidation[J]. Acta Phys. -Chim. Sin., 2015,31(6): 1153-1161
7. ZHANG Xiao-Qing, XU Yan YAN, YANG Chun-Hui, ZHANG Yan-Ping, YIN Yong-Xiang, SHANG Shu-Yong.In-situ Co-Precipitation of Ni-Mg-Al-LDH Catalytic Precursor on γ-Al2O3 for Dry Reforming of Methane: Synthesis and Evaluation[J]. Acta Phys. -Chim. Sin., 2015,31(5): 948-954
8. YAO Xiao-Jiang, GONG Ying-Tao, LI Hong-Li, YANG Fu-Mo.Research Progress of Ceria-Based Catalysts in the Selective Catalytic Reduction of NOx by NH3[J]. Acta Phys. -Chim. Sin., 2015,31(5): 817-828
9. CHEN Feng, HUANG Bi-Chun, YANG Ying-Xin, LIU Xiao-Qing, YU Cheng-Long.Synthesis, Characterization and NH3-SCR Activity of MnSAPO-34 Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2015,31(12): 2375-2385
10. Lü Jiao-Long, LI Feng-Li, LI Xin-Gang.NOx Storage Reduction Performance of Coupled BaFeO3-x+Cu-ZSM-5 Catalyst[J]. Acta Phys. -Chim. Sin., 2014,30(8): 1550-1558
11. GAO Peng, LI Feng, ZHAO Ning, WANG Hui, WEI Wei, SUN Yu-Han .Preparation of Cu/Zn/Al/(Zr)/(Y) Catalysts from Hydrotalcite-Like Precursors and Their Catalytic Performance for the Hydrogenation of CO2 to Methanol[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1155-1162
12. YU Zai-Lu, XIE Peng-Fei, TANG Xing-Fu, YUE Ying-Hong, HUA Wei-Ming, GAO Zi.Selective Catalytic Reduction of NO with NH3 over MnOx-CeO2-WO3-ZrO2:Effect of Calcination Temperature[J]. Acta Phys. -Chim. Sin., 2014,30(6): 1175-1179
13. YANG Chao, LIU Xiao-Qing, HUANG Bi-Chun, WU You-Ming.Structural Properties and Low-Temperature SCR Activity of Zirconium-Modified MnOx/MWCNTs Catalysts[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1895-1902
14. XIAN Hui, MA Ai-Jing, MENG Ming, LI Xin-Gang.Influence of Reductants on the NOx Storage Performances of the La0.7Sr0.3Co0.8Fe0.2O3 Perovskite-Type Catalyst[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2437-2443
15. JIAO Yi, QIN Li-Xiao, LI Xiong-Jian, WANG Jia, WANG Jian-Li, ZHU Quan, LI Xiang-Yuan, CHEN Yao-Qiang.Influence of Adding Zr0.5Ti0.5O2 on the Performance of Supercritical Cracking Catalyst for RP-3[J]. Acta Phys. -Chim. Sin., 2013,29(10): 2255-2262
16. HUANG Hai-Feng, JIA Jian-Ming, LU Han-Feng, ZHANG Hong-Hua, PAN Lie-Qun.Effect of Designed Zr/Ti Molar Ratio on the Photocatalytic Activity of Sr-Zr-Ti Mixed Oxide Catalysts under Visible Light[J]. Acta Phys. -Chim. Sin., 2013,29(06): 1319-1326
17. CHEN Yong-Dong, WANG Lei, GUAN Xiao-Xu, LIU Yong-Bing, GONG Mao-Chu, CHEN Yao-Qiang.Catalytic Oxidation of Soluble Organic Fraction in Diesel Exhausts Using Composite Oxides (CeO2)x(La-Al2O3)1-x[J]. Acta Phys. -Chim. Sin., 2013,29(05): 1048-1054
18. HU Jun, SHI Wei, NI Zhe-Ming, LIU Jiao, XUE Ji-Long.Influence of Interlayer Anion on Supermolecular Interaction in Quaternary Hydrotalcites[J]. Acta Phys. -Chim. Sin., 2013,29(03): 491-497
19. MENG Zhong-Hua, YANG Peng, ZHOU Ren-Xian.Influence of Ce/Cr Ratio on 2-CrOx Mixed Oxide Catalysts for the Catalytic Oxidation of 1,2-Dichloroethane[J]. Acta Phys. -Chim. Sin., 2013,29(02): 391-396
20. XU Da, LIU Shi-Yan, LIU Yun-Ling, WANG Zhen-Lü.Effect of pH Value on the Properties of Molybdenum-Based Multiphasic Oxide Catalysts in Selective Oxidation of Isobutene to Methacrolein[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2690-2696
21. NI Zhe-Ming, LI Yuan, SHI Wei, XUE Ji-Long, LIU Jiao.Supramolecular Structure, Electronic Property and Stability of Ni-Mg-Al Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2012,28(09): 2051-2056
22. SHI Wei, HU Jun, NI Zhe-Ming, LI Yuan, LIU Jiao.Influence of Interlayer Water Content on Supermolecular Interaction of Copper-Iron Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1869-1876
23. JIN Rong-Rong, LI Li-Fang, XU Xue-Feng, LIAN Ying-Hui, ZHAO Fan.Layered Double Hydroxide Supported Palladium Nanoparticles for Electrocatalytic Oxidation of Hydrazine[J]. Acta Phys. -Chim. Sin., 2012,28(08): 1929-1935
24. NI Zhe-Ming, LIU Jiao, XUE Ji-Long, LI Yuan, SHI Wei.Effect of Divalent Metal Ions on the Stability of Cu-Containing Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1714-1720
25. MAAi-Jing, WANG Shao-Zeng, ZOU Hong-Hu, MENG Ming, LI Zhi-Jun, BAO Jun, LI Xin-Gang.The Performance of the NOx Storage Capacity and Sulfur Tolerance of the La0.7Sr0.3Co1-xFexO3 Catalyst[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1474-1480
26. ZHOU Ju-Fa, ZHAO Ming, PENG Na, YANG Zheng-Zheng, GONG Mao-Chu, CHEN Yao-Qiang.Performance Effect of Pt/MOx-SiO2 (M=Ce, Zr, Al) Catalysts for CO and C3H8 Oxidation[J]. Acta Phys. -Chim. Sin., 2012,28(06): 1448-1454
27. ZHUANG Ke, QIU Jing, XU Bo-Lian, FAN Yi-Ning.Promotional Effect of Cerium Oxide on the Catalytic Properties of Ce-Mn-Ti-O Catalysts for Selective Catalytic Reduction of NO[J]. Acta Phys. -Chim. Sin., 2012,28(03): 681-685
28. WANG Li-Geng, SHI Wei, YAO Ping, NI Zhe-Ming, LI Yuan, LIU Jiao.Microstructure and Jahn-Teller Effect of Cu-Zn-Mg-Al Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2012,28(01): 58-64
29. XIAO Yi-Hong, YANG Huang-Gen, CAI Guo-Hui, ZHENG Yong, ZHENG Ying, WEI Ke-Mei.Influence of Reductive Treatment on the Performance of CeO2-ZrO2-Al2O3 Composite Oxide[J]. Acta Phys. -Chim. Sin., 2012,28(01): 245-250
30. WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong.Dimethyl Ether Synthesis from CO2 Hydrogenation over CuO-TiO2-ZrO2/HZSM-5 Catalysts[J]. Acta Phys. -Chim. Sin., 2011,27(11): 2651-2658
31. LIU Jiao, YAO Ping, NI Zhe-Ming, LI Yuan, SHI Wei.Jahn-Teller Effect of Cu-Mg-Al Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2011,27(09): 2088-2094
32. NIE Hong-Qian, HOU Wan-Guo.Methods and Applications for Delamination of Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2011,27(08): 1783-1796
33. LIU Jie-Xiang, ZHANG Xiao-Guang, DUAN Zhong-Yu, LIU Xiao-Li.NOx Molecule Adsorption in [Ag]-MAPO-5 (M=Si, Ti)Molecular Sieves[J]. Acta Phys. -Chim. Sin., 2010,26(10): 2679-2685
34. XU Hai-Di, QIU Chun-Tian, ZHANG Qiu-Lin, LIN Tao,GONG Mao-Chu, CHEN Yao-Qiang.Influence of Tungsten Oxide on Selective Catalytic Reduction of NOx with NH3 over MnOx -CeO2 /ZrO2-TiO2Monolith Catalyst[J]. Acta Phys. -Chim. Sin., 2010,26(09): 2449-2454
35. ZHANG Ye-Xin, SU Qing-Yun, WANG Zhong-Peng, GAO Xi-Yan, ZHANG Zhao-Liang.Surface Modification of Mg-Al Hydrotalcite Mixed Oxides with Potassium[J]. Acta Phys. -Chim. Sin., 2010,26(04): 921-926
36. YAN Dong-Xia, WANG Hua, LI Kong-Zhai, WEI Yong-Gang, ZHU Xing, CHENG Xian-Ming.Structure and Catalytic Property of Ce1-xFexO2 Mixed Oxide Catalysts for Low Temperature Soot Combustion[J]. Acta Phys. -Chim. Sin., 2010,26(02): 331-337
37. YAO Ping, NI Zhe-Ming, XU Qian, MAO Jiang-Hong, LIU Xiao-Ming, WANG Qiao-Qiao.Supermolecular Interactions in Magnesium-Tin Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(01): 175-182
38. HE Shu-Heng, PU Min, LI Jun-Nan, HE Jing, EVANS David G..Assembly, Structure and Properties of Acid Orange 7-Pillared Zn/Al Hydrotalcite[J]. Acta Phys. -Chim. Sin., 2010,26(01): 259-264
39. NI Zhe-Ming, XU Qian, YAO Ping, MAO Jiang-Hong, LIU Xiao-Ming.Influence of Interlayer Water Content on theMechanical Properties of Mg3Al-LDHs-Cl[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2325-2328
40. LI Peng, HE Chi, CHENG Jie, HAO Zheng-Ping.Catalytic Oxidation of Chlorobenzene on Composite Oxide Pd/M3AlO (M=Mg, Co, Ni, Cu, Zn) Catalysts Derived fromPd-Contained Hydrotalcite Precursors[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2279-2284
41. CAO Yong, JIAO Qing-Ze, ZHAO Yun.Synthesis of N-doped and Undoped Carbon Nanotubes on Fe/MgO Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2380-2384
42. LIU Chang, XUE Li, HE Hong.Influence of Alkaline Earth Metals on Cobalt-Cerium Composite Oxide Catalysts for N2O Decomposition[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1033-1039
43. CHEN Zhi-Hang, LI Xue-Hui, YANG Qing, LI Hua, GAO Xiang, JIANG Yan-Bin, WANG Fu-Rong, WANG Le-Fu.Removal of NOx Using Novel Fe-Mn Mixed-Oxide Catalysts at Low Temperature[J]. Acta Phys. -Chim. Sin., 2009,25(04): 601-605
44. YU Jun-Jie; ZHU Ling; ZHOU Bo; SHAO Li-Nan; ZHANG Yu-Ting; HE Xu-Wen.N2O Catalytic Decomposition over Mixed Oxides Derived from Zn-substituted Hydrotalcite-like Compounds[J]. Acta Phys. -Chim. Sin., 2009,25(02): 353-359
45. PAN Guo-Xiang; NI Zhe-Ming; WANG Fang; WANG Jian-Guo; LI Xiao-Nian.Molecular Dynamics Simulation on Structure, Hydrogen-Bond and Hydration Properties of Diflunisal Intercalated Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2009,25(02): 223-228
46. LIU Jie-Xiang; WEI Xian; ZHANG Xiao-Guang; WANG Gui-Xiang; HAN En-Shan; WANG Jian-Guo.NOx Adsorption in [Ag]-AlMOR Molecular Sieve[J]. Acta Phys. -Chim. Sin., 2009,25(01): 91-96
47. ZHU Rong-Shu; GUO Ming-Xin; OUYANG Feng.Simultaneous Catalytic Removal of Soot and NOx over Single Metal Oxide Catalysts[J]. Acta Phys. -Chim. Sin., 2009,25(01): 131-136
48. SUN Qi; REN Liang; NIU Jin-Hai; SONG Zhi-Min.Interactions of Dielectric Barrier Discharge Plasmas with NO or NO/O2 Adsorbed on CuZSM-5[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1214-1218
49. WANG Lin; CHEN Shun-Quan; LIU Yuan.NiO/LaMnO3 Catalysts for Steam Reforming of Ethanol[J]. Acta Phys. -Chim. Sin., 2008,24(05): 849-854
50. XU Qian; NI Zhe-Ming; PAN Guo-Xiang; CHEN Li-Tao; LIU Ting.Super-Molecular Interaction between Cl- and H2O within the Restricted Space of Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2008,24(04): 601-606
51. PAN Guo-Xiang; NI Zhe-Ming; LI Xiao-Nian.Supra-molecular Interaction between Host Layer and Guest CO2-3, H2O of Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1195-1200
52. FANG Ping; LU Ji-Qing; JIA Ai-Ping; LUO Meng-Fei.Catalytic Combustion of Diesel Soot on Nanocrystalline CeO2-based Solid Solutions[J]. Acta Phys. -Chim. Sin., 2007,23(08): 1275-1280
53. YANG Zuo-Yin; ZHOU Hong-Wei; ZHANG Jing-Chang; CAO Wei-Liang.Relationship between Al/Mg Ratio and the Stability of Single-layer Hydrotalcite[J]. Acta Phys. -Chim. Sin., 2007,23(06): 795-800
54. TAO Yan-Xin;YU Jun-Jie;LIU Chang-Chun;HAO Zheng-Ping;ZHANG Ze-Peng .Study on N2O Catalytic Decomposition over Mixed Oxides Derived from Co-Mg/Al Hydrotalcite-like Compounds[J]. Acta Phys. -Chim. Sin., 2007,23(02): 162-168
55. XIAO Jian-Hua;LI Xue-Hui;DENG Sha;XU Jian-Chang;WANG Le-Fu.The NOx Oxidation-Storage and Tolerance of SO2 Poison of Mn/Ba/Al2O3 Catalyst[J]. Acta Phys. -Chim. Sin., 2006,22(07): 815-819
56. ZHANG Guo-qiang; LI Ji-wei; YANG Lefu; LI Feng; FANG Rong-qian; GUO Debo; CAI Jun-xiu.Studies of the Mg-Al and Cation-Incorporated Hydrotalcites[J]. Acta Phys. -Chim. Sin., 2006,22(02): 146-151
57. ZHU Ling; WANG Xue-zhong; YU Jun-jie; HAO Zheng-ping.Catalytic Performance of K-Ce0.5Zr0.5O2 Catalysts for Soot Combustion[J]. Acta Phys. -Chim. Sin., 2005,21(08): 840-845
58. JI Hong-bing; WANG Le-fu; CHEN Qing-lin.Development of Catalysts with Tunable Catalytic Oxidative Performance for Alcohols Conversion[J]. Acta Phys. -Chim. Sin., 2005,21(07): 746-751
59. PEI Mei-Xiang; LIN He; SHANGGUAN Wen-Feng; HUANG Zhen.The Effects of Plasma on Simultaneously Catalytic Removal of NOx and Soot[J]. Acta Phys. -Chim. Sin., 2005,21(03): 255-260
60. KANG Shou-Fang; JIANG Zheng; HAO Zheng-Ping.Influence of Cu on NOx Storage Performance of Pt/Cu-Mg-Al-O Catalysts Derived from Hydrotalcites[J]. Acta Phys. -Chim. Sin., 2005,21(03): 278-282
61. SHAO Guang-Xin; LUO Lai-Tao; DUAN Zhan-Hui.Preparation, Catalytic Oxidation Properties and Characterization of LaSrCo0.9B’0.1O4 (B’=Mn, Fe, Ni, Cu) Mixed Oxides[J]. Acta Phys. -Chim. Sin., 2005,21(03): 328-332
62. SUN Qi;ZHU Ai-Min;NIU Jin-Hai;XU Yong;SONG Zhi-Min.Plasma-induced Conversion of Nitrogen Oxides in a Dielectric Barrier Discharge Reactor[J]. Acta Phys. -Chim. Sin., 2005,21(02): 192-196
63. YANG Xiao-Guang;DONG Peng;ZHOU Ya-Song;LIU Tao;ZHANG Jing;XIEYa-Ning;HU Tian-Dou.The Local Structure of Titania-Silica Composite Oxides[J]. Acta Phys. -Chim. Sin., 2005,21(01): 33-37
64. Yu Jun-Jie; Jiang Zheng; Kang Shou-Fang; Hao Zheng-Ping.Catalytic Combustion of Soot over Cu-Mg/Al Composite Oxides[J]. Acta Phys. -Chim. Sin., 2004,20(12): 1459-1464
65. Li Li-Fang;Hou Wan-Guo;Jiao Yan-Ni;Liu Chun-Xia.Effect of Permanent Charge on the Intrinsic Ionization Constant of Zn-Al Hydrotalcite-like Compounds[J]. Acta Phys. -Chim. Sin., 2004,20(05): 459-462
66. Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
67. Ren Qing-Li;Zhang Zan-Feng;Luo Qiang.Preparation and Thermal Decomposition Mechanism of Nanocrystalline Mg, Al-hydrotalcite[J]. Acta Phys. -Chim. Sin., 2004,20(03): 318-322
68. Tang Zhi-Yuan;Song Shi-Dong;Liu Jian-Hua;Pan Li-Zhu;Nan Jun-Min.Electrochemical Properties of La1-xSrxNi1-yCoyO3 Bifunctional Oxygen Electrodes[J]. Acta Phys. -Chim. Sin., 2003,19(09): 785-790
69. Liang Xin-Yi;Zhang Li-Ming;Ding Hong-Yuan;Qin Yong-Ning.Supported Catalyst LaCoO3/γ-Al2O3 Prepared by Impregnating under Ultrasound[J]. Acta Phys. -Chim. Sin., 2003,19(07): 666-669
70. Liang Jian;Huang Hui-Zhong;Xie You-Chang.The Phases of ZrO2-Al2O3 Composites with High Specific Surface Prepared by Co-precipitation[J]. Acta Phys. -Chim. Sin., 2003,19(01): 30-34
71. Zhao Feng;Liu Ying-Jun;Li Neng;Lin Bing-Xiong.CO-NO Reaction over ABO2 Complex Oxides with Dalofossite Structure[J]. Acta Phys. -Chim. Sin., 2001,17(06): 511-515
72. Zhao Liang-Zhong;Liu Fen;Zhang Lin.XPS Study on Electronic Structure for LnCu2O4(Ln=Gd, Nd)[J]. Acta Phys. -Chim. Sin., 2001,17(04): 310-313
73. Zhong Shun-He, Li Han-Sehng, Wang Jian-Wei, Xiao Xiu-Fen.Cu-Ni/V2O5-SiO2 Catalyst for the Direct Synthesis of Dimethyl Carbonate from Carbon Dioxide and Methanol[J]. Acta Phys. -Chim. Sin., 2000,16(03): 226-231
74. Bian Guo-Zhu, Han Bo, Fu Yi-Lu.Sol-gel Method Preparation and Characterization of NiMoO4 Ultrafine Particle Catalyst[J]. Acta Phys. -Chim. Sin., 1999,15(11): 1001-1004
75. Liu Hai-Chao, Yang Xi-Yao, Ran Guo-Peng, Min En-Ze.Bifunctional Catalysts of Supported Cobalt-Phthalocyanine with OppositivelyCharged lons for Autoxidation of Mercaptan[J]. Acta Phys. -Chim. Sin., 1999,15(10): 918-924
76. Wen Bin, He Ming-Yuan, Song Jia-Qing, Zong Bao-Ning, Shu Xing-Tian, Lu Yong.Study on the Reduction of NO by CO in the Presence of Oxygen[J]. Acta Phys. -Chim. Sin., 1999,15(10): 868-871
77. Ji Shi-Shan, Li Zeng-Xi, Tan Rui-Qin, Chen Zhi-Hua, Cao Li-Li.The Study of the Oxygen Nonstoichiometry in Oxide SrCoO3-δ[J]. Acta Phys. -Chim. Sin., 1999,15(07): 624-628
78. Liu Yu, Yang Xiang-Guang, Liu Yu-Min, Wu Yue.Study on the Synthesis of Mixed Oxide La2CuO4 and the Effect on the Catalytic Activity to Catalytic Removal of NO[J]. Acta Phys. -Chim. Sin., 1999,15(06): 506-511
79. Wang Xue-Zhong, Liu Yu-Min, Wu Yue.Catalytic Reduction of NO by CO with Hydrotalcite Derived Mixed Oxides[J]. Acta Phys. -Chim. Sin., 1999,15(01): 50-56
80. Zhang Ji-Jun, Liu Ying-Jun, Li Neng, Lin Bing-Xiong.Synergistic Effect between CuO and CeO2 for CO Oxidation[J]. Acta Phys. -Chim. Sin., 1999,15(01): 15-21
81. Ma Zhi, Qin Yong-Ning, Qi Xiao-Zhou, Liang Zhen-Cheng, He Fei.Studies on Prepartion and CO Oxidation Activity of LaSrBO4 Compound[J]. Acta Phys. -Chim. Sin., 1998,14(05): 453-457
82. Zhao Zhen,Yang Xiang-Guang,Wu Yue.Study on the Adsorption and Activation of NO and CO over Mixed Oxide Catalysts Containing Cu by Means of TPSR[J]. Acta Phys. -Chim. Sin., 1997,13(04): 344-350
83. Liu Chi-Biao,Zhao Zhen,Yang Xiang-Guang,Ye Xing-Kai,Wu Yue.Investigation of Catalysis of Y-Ba-Cu-O Mixed Oxides in Phenol Hydroxylation[J]. Acta Phys. -Chim. Sin., 1996,12(11): 1044-1048
84. Li Xing-Lin,She Yi-Min,Guo Jun,Jiang Da-Zhen.XPS Study of the Interaction between Layers and Pillars of Layered Double Hydroxides Pillared with Heteroplyanion(II)[J]. Acta Phys. -Chim. Sin., 1996,12(10): 929-932
85. Kuang Wen-Xing,Fan Yi-Ning,Chen Kai-Dong,Chen Yi.Preparation of La-Mo Series Complex Oxide Ultrafine Particle Catalysts by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 1996,12(09): 861-863
86. Guo Jun,Jiao Qing-Ze,Lv Hui-Juan,Jiang Da-Zhen,Yang Guang-Hui,Min En-Ze.Synthesis and Adsorption Properties of some Polyoxometalate Pillared Hydrotalcites[J]. Acta Phys. -Chim. Sin., 1996,12(06): 573-576
87. Li Xu-Yuan,Zhang Zi-Ping,Ma Jian-Tai,Zhu Zong-Zhen,Meng Yi-Min.The Catalytic Activity for CO Oxidation and Characterization of Perovskite-type Oxides Catalysts La1+X/2Sr1-x/2Co1-xCuxO3[J]. Acta Phys. -Chim. Sin., 1996,12(06): 502-507
88. Yang Xiang-Guang,Liu She-Tian,Ye Xing-Kai,Wu Yue,Sheng Shi-Shan,Xiong Guo-Xing.X-Ray Photoelectron Spectroscopy Study of LaMn1-xFexO3(x=0-1) Oxides[J]. Acta Phys. -Chim. Sin., 1995,11(08): 681-687
89. Xu Zheng, He He-Ming, Jiang Da-Zhen, Wu Yue.Alrylation Over Layered Double Hydrotalcites Pillared by Heteropolyoxometalate Catalysts[J]. Acta Phys. -Chim. Sin., 1994,10(01): 6-8
Copyright © 2006-2016 Editorial office of Acta Physico-Chimica Sinica
Address: College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P.R.China
Service Tel: +8610-62751724 Fax: +8610-62756388
^ Top