Please wait a minute...
Acta Phys. -Chim. Sin.  2009, Vol. 25 Issue (03): 532-538    DOI: 10.3866/PKU.WHXB20090322
Article     
Chelation Adsorption Behavior of a Salicylic Acid-Type Chelate Resin for Fe(III) Ions
 ZHANG Jian, GAO Bao-Jiao, LU Jin-Hua
Salicylic acid; Chelate resin; Crosslinked polystyrene; Chelation adsorption; Entropy driving
Download:   PDF(740KB) Export: BibTeX | EndNote (RIS)      

Abstract  

The nucleophilic substitution reaction of phenyl chloride groups on chloromethylated cross-linked polystyrene (CMCPS) microspheres was conducted using 5-amino salicylic acid (ASA) as an amination reagent. The resultant product was a salicylic acid-type chelate resin (ASA-CPS). Chelation adsorption behavior of the ASA-CPS resin for metal ions was studied and adsorption thermodynamics as well as the adsorption mechanism was also investigated. The effect of mediumpH on adsorption of the ASA-CPS resin was examined and the chelation adsorption abilities of ASA-CPS for different metal ions were tested. Experimental results show that the salicylic acid-type chelate resin, ASA-CPS, possesses strong chelation adsorption ability for heavy metal ions. The resin is especially good at adsorbing Fe (III) ions and the adsorption capacity can reach 21 g/100 g at room temperature. Adsorption is a process driven by entropy and higher temperatures facilitate the adsorption process and thus increase the adsorption capacity. In the pH range where the hydrolysis of metal ions is inhibited, an increase in the pH value of the medium will strengthen the chelation adsorption ability of the ASA-CPS resin for heavy metal ions. For different metal ions, ASA-CPS exhibits different adsorption abilities with the following order of adsorption capacity: Fe3+>Ni2+>Cu2+>Zn2+.



Key wordsSalicylic acid      Chelate resin      Crosslinked polystyrene      Chelation adsorption      Entropy driving     
Received: 20 August 2008      Published: 10 December 2008
MSC2000:  O642  
Corresponding Authors: GAO Bao-Jiao     E-mail: gaobaojiao@126.com
Cite this article:

ZHANG Jian, GAO Bao-Jiao, LU Jin-Hua. Chelation Adsorption Behavior of a Salicylic Acid-Type Chelate Resin for Fe(III) Ions. Acta Phys. -Chim. Sin., 2009, 25(03): 532-538.

URL:

http://www.whxb.pku.edu.cn/10.3866/PKU.WHXB20090322     OR     http://www.whxb.pku.edu.cn/Y2009/V25/I03/532

[1] ZHANG Qiao-Ling, LI Lei, LIU You-Zhi, WEI Bing, GUO Jia-Xin, FENG Yu-Jie. Grafting Dynamics, Structures and Properties of Nano TiO2-SA Photocatalytic Materials[J]. Acta Phys. -Chim. Sin., 2015, 31(6): 1015-1024.
[2] LIU Wen-Han, YUAN Rong-Hui, TENG Yuan-Jie, MA Chun-An. Electrochemical SERS of Self-Assembled Monolayer of Thiosalicylic Acid Adsorbed on Activated Gold Electrodes[J]. Acta Phys. -Chim. Sin., 2013, 29(12): 2599-2607.
[3] ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke. 5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010, 26(12): 3175-3180.
[4] ZHU Hui, WANG Mei, CHENG Ling-Li, ZHU Rong-Rong, SUN Xiao-Yu, YAO Si-De, WU Qing-Sheng, WANG Shi-Long. Photoionization and Photoexcitation Mechanisms of Salicylic Acid[J]. Acta Phys. -Chim. Sin., 2010, 26(01): 87-93.
[5] Gao Zi; Yue Ying-Hong; Li Wen-Jun. Application of Pervaporation Membrane to Catalytic Esterification Reaction[J]. Acta Phys. -Chim. Sin., 1993, 9(02): 242-246.