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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2007,Vol.23>> Issue(09)>> 1365-1369     doi: 10.3866/PKU.WHXB20070911         中文摘要
Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method
YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu
Shanghai Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
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MnO2 particles in the size less than 200 nm were prepared via the oxidation of MnSO4 using KMnO4 as oxidizer. The printing‘ink’was prepared by mixing MnO2 particles with acetylene black, dispersion additive Lomar-D, ethanolamine, binder CMCS and distilled water in the mass ratio of 200:40:4:1:1:4000, and dispersing under ultrasonic. The ultra thin MnO2 film electrodes were prepared by means of computer jet printing technique using this‘ink’. The SEMimages showed that the surface of the ultra thin MnO2 filmelectrode was uniform, and its thickness was about 2.5 μm. In 1 mol·L-1 Li2SO4 solution the electrodes present typical electrochemical supercapacitance behavior observed by voltammetry and charge-discharge measurements, in the potential region of 0-0.85 V(vs SCE). Its specific capacitance reached to 154 F·g-1 at the discharge current of 9.4 A·g-1, and remained almost no change after 2000 cycles.

Keywords: MnO2   Ultra thin electrode   Jet printing   Supercapacitor  
Received: 2007-02-13 Accepted: 2007-04-26 Publication Date (Web): 2007-06-12
Corresponding Authors: JIANG Zhi-Yu Email: zyjiang@fudan.ac.cn


Cite this article: YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu. Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23 (09): 1365-1369.    doi: 10.3866/PKU.WHXB20070911
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