Article
Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method
YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu
Shanghai Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
Shanghai Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
MnO2 particles in the size less than 200 nm were prepared via the oxidation of MnSO4 using KMnO4 as oxidizer. The printing‘ink’was prepared by mixing MnO2 particles with acetylene black, dispersion additive Lomar-D, ethanolamine, binder CMCS and distilled water in the mass ratio of 200:40:4:1:1:4000, and dispersing under ultrasonic. The ultra thin MnO2 film electrodes were prepared by means of computer jet printing technique using this‘ink’. The SEMimages showed that the surface of the ultra thin MnO2 filmelectrode was uniform, and its thickness was about 2.5 μm. In 1 mol·L-1 Li2SO4 solution the electrodes present typical electrochemical supercapacitance behavior observed by voltammetry and charge-discharge measurements, in the potential region of 0-0.85 V(vs SCE). Its specific capacitance reached to 154 F·g-1 at the discharge current of 9.4 A·g-1, and remained almost no change after 2000 cycles.
Keywords: MnO2 Ultra thin electrode Jet printing Supercapacitor
Received: 2007-02-13 Accepted: 2007-04-26 Publication Date (Web): 2007-06-12
Corresponding Authors: JIANG Zhi-Yu Email: zyjiang@fudan.ac.cn
Cite this article: YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu. Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23 (09): 1365-1369. doi: 10.3866/PKU.WHXB20070911
Keywords: MnO2 Ultra thin electrode Jet printing Supercapacitor
Received: 2007-02-13 Accepted: 2007-04-26 Publication Date (Web): 2007-06-12
Corresponding Authors: JIANG Zhi-Yu Email: zyjiang@fudan.ac.cn
Cite this article: YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu. Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23 (09): 1365-1369. doi: 10.3866/PKU.WHXB20070911
1．
ZHOU Xiao, SUN Min-Qiang, WANG Geng-Chao.Synthesis and Supercapacitance Performance of Graphene-Supported π-Conjugated Polymer Nanocomposite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2016,32(4): 975-982
2． WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
3． LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu.Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Phys. -Chim. Sin., 2016,32(2): 474-480
4． LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei .Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 493-502
5． LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping.Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Phys. -Chim. Sin., 2015,31(4): 676-684
6． LI Yang, XIE Hua-Qing, LI Jing.Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2015,31(4): 693-699
7． YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang.Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2015,31(4): 685-692
8． ZHANG Jie-Jing, WANG Yu-Xin, XU Li.Simulation of Sphere-Microstructure Model of the Catalyst Layer in a PEMFC[J]. Acta Phys. -Chim. Sin., 2015,31(3): 489-497
9． WU Yan-Bo, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers[J]. Acta Phys. -Chim. Sin., 2015,31(2): 315-321
10． LU Jian-Jian, YING Zong-Rong, LIU Xin-Dong, ZHAO Shuang-Sheng.Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2099-2108
11． HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2220-2228
12． YI Chao, XIONG Xin-Bo, ZOU Zhi-Biao, LI Jun-Jie, HUANG Tuo, LI Bin, MA Jun, ZENG Xie-Rong.Fabrication of Nickel-Based Composite Film Electrode for Supercapacitors by a New Method of Anodization/GCD[J]. Acta Phys. -Chim. Sin., 2015,31(1): 99-104
13． WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan.Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1659-1666
14． ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long.Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO2 Composites[J]. Acta Phys. -Chim. Sin., 2014,30(5): 881-890
15． SUN Xian-Zhong, ZHANG Xiong, HUANG Bo, MA Yan-Wei.Effects of Separator on the Electrochemical Performance of Electrical Double-Layer Capacitor and Hybrid Battery-Supercapacitor[J]. Acta Phys. -Chim. Sin., 2014,30(3): 485-491
16． CHEN Chan-Juan, HU Zhong-Ai, HU Ying-Ying, LI Li, YANG Yu-Ying, AN Ning, LI Zhi-Min, WU Hong-Ying.SnO2/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2256-2262
17． WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan.Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2077-2084
18． TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
19． MA Guo-Fu, MU Jing-Jing, ZHANG Zhi-Guo, SUN Kan-Jun, PENG Hui, LEI Zi-Qiang.Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2385-2391
20． HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
21． LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
22． WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
23． HU Ying-Ying, HU Zhong-Ai, ZHANG Ya-Jun, LU Ai-Lian, XU Huan, ZHANG Zi-Yu, YANG Yu-Ying, LI Li, WU Hong-Ying.Synthesis and Electrochemical Characterization of RuO2·xH2O/Graphite Nanosheet Composite Array Electrodes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(02): 305-310
24． LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang.Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Phys. -Chim. Sin., 2013,29(01): 111-116
25． ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
26． SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
27． HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
28． SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
29． CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
30． LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
31． ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping.Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28(02): 373-380
32． SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
33． GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
34． XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
35． LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
36． LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
37． ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
38． MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
39． YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
40． LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
41． TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
42． ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
43． ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
44． ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
45． TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
46． LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
47． JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
48． WANG Fan, WANG Yan-Min, WEN Yan-Xuan, SU Hai-Feng, LI Bin.Structural and Morphological Transformation of MnO2 Nanostructures from Mn3O4 Precursor[J]. Acta Phys. -Chim. Sin., 2010,26(02): 521-526
49． ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
50． PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
51． FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
52． SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
53． SU Zhi, XU Mao-Wen, YE Shi-Hai, WANG Yong-Long.Doping of Layered LiMnO2 as Cathode Materials for Lithium-Ion Batteries and Their Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1232-1238
54． HU Jie, YUAN An-Bao, WANG Yu-Qin, WANG Xiu-Ling.Improved Cyclability of Nano-MnO2/CNT Composite Supercapacitor Electrode Derived fromRoom-Temperature Solid Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(05): 987-993
55． JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
56． DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
57． CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
58． JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
59． HUANG Jun-Jie; JIANG Zhi-Yu.Electrochemical Performance of LiMn2O4 Thin Film Electrode Fabricated by Ink-Jet Printing Technique[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1563-1567
60． ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
61． YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
62． WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
63． WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
64． SONG Xu-Chun;ZHENG Yi-Fan;LIN Shen;WANG Yun.A Simple Method to Synthesize α-MnO2 and β-MnO2 Single-crystalline Nanorods[J]. Acta Phys. -Chim. Sin., 2007,23(02): 258-261
65． ZHAO Feng-Ming;MA Chun-An;CHU You-Qun;XU Ying-Hua.Oxygen Reduction on Ni-MnO2 Electrode in Alkaline Solution[J]. Acta Phys. -Chim. Sin., 2006,22(06): 716-720
66． YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
67． Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
68． Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
69． Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
70． Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
71． Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
72． Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288
2． WANG Yong-Fang, ZUO Song-Lin.Electrochemical Properties of Phosphorus-Containing Activated Carbon Electrodes on Electrical Double-Layer Capacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 481-492
3． LIN You-Cheng, ZHONG Xin-Xian, HUANG Han-Xing, WANG Hong-Qiang, FENG Qi-Peng, LI Qing-Yu.Preparation and Application of Polyaniline Doped with Different Sulfonic Acids for Supercapacitor[J]. Acta Phys. -Chim. Sin., 2016,32(2): 474-480
4． LI Ya-Jie, NI Xing-Yuan, SHEN Jun, LIU Dong, LIU Nian-Ping, ZHOU Xiao-Wei .Preparation and Performance of Polypyrrole/Nitric Acid Activated Carbon Aerogel Nanocomposite Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2016,32(2): 493-502
5． LI Zhao-Hui, LI Shi-Jiao, ZHOU Jin, ZHU Ting-Ting, SHEN Hong-Long, ZHUO Shu-Ping.Preparation and Supercapacitive Performance of N, S Co-Doped Activated Carbon Materials[J]. Acta Phys. -Chim. Sin., 2015,31(4): 676-684
6． LI Yang, XIE Hua-Qing, LI Jing.Hydrothermal Synthesis of Al-Doped α-MnO2 Nanotubes and Their Electrochemical Performance for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2015,31(4): 693-699
7． YANG Shuo, XU Gui-Yin, HAN Jin-Peng, BING Huan, DOU Hui, ZHANG Xiao-Gang.Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2015,31(4): 685-692
8． ZHANG Jie-Jing, WANG Yu-Xin, XU Li.Simulation of Sphere-Microstructure Model of the Catalyst Layer in a PEMFC[J]. Acta Phys. -Chim. Sin., 2015,31(3): 489-497
9． WU Yan-Bo, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Double-Perovskite La2CoNiO6 Inorganic Nanofibers[J]. Acta Phys. -Chim. Sin., 2015,31(2): 315-321
10． LU Jian-Jian, YING Zong-Rong, LIU Xin-Dong, ZHAO Shuang-Sheng.Preparation of Cross-Linked Porous Carbon Nanofiber Networks by Electrospinning Method and Their Electrochemical Capacitive Behaviors[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2099-2108
11． HAN Xiao-Mei, WU Yan-Bo, ZHAO Heng-Yan, BI Jun, WEI Bin-Bin.Preparation and Supercapacitor Properties of Carbon-Coated SnO2 Hollow Fibers[J]. Acta Phys. -Chim. Sin., 2015,31(11): 2220-2228
12． YI Chao, XIONG Xin-Bo, ZOU Zhi-Biao, LI Jun-Jie, HUANG Tuo, LI Bin, MA Jun, ZENG Xie-Rong.Fabrication of Nickel-Based Composite Film Electrode for Supercapacitors by a New Method of Anodization/GCD[J]. Acta Phys. -Chim. Sin., 2015,31(1): 99-104
13． WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan.Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials[J]. Acta Phys. -Chim. Sin., 2014,30(9): 1659-1666
14． ZHANG Xuan-Xuan, RAN Fen, FAN Hui-Li, KONG Ling-Bin, KANG Long.Hydrothermal Synthesis and Electrochemical Measurements of Interconnected Porous Carbon/MnO2 Composites[J]. Acta Phys. -Chim. Sin., 2014,30(5): 881-890
15． SUN Xian-Zhong, ZHANG Xiong, HUANG Bo, MA Yan-Wei.Effects of Separator on the Electrochemical Performance of Electrical Double-Layer Capacitor and Hybrid Battery-Supercapacitor[J]. Acta Phys. -Chim. Sin., 2014,30(3): 485-491
16． CHEN Chan-Juan, HU Zhong-Ai, HU Ying-Ying, LI Li, YANG Yu-Ying, AN Ning, LI Zhi-Min, WU Hong-Ying.SnO2/Graphite Nanosheet Composite Electrodes and Their Application in Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(12): 2256-2262
17． WANG Jian-De, PENG Tong-Jiang, SUN Hong-Juan, HOU Yun-Dan.Effect of the Hydrothermal Reaction Temperature on Three-Dimensional Reduced Graphene Oxide's Appearance, Structure and Super Capacitor Performance[J]. Acta Phys. -Chim. Sin., 2014,30(11): 2077-2084
18． TANG Jia-Yong, CAO Pei-Qi, FU Yan-Bao, LI Peng-Hui, MA Xiao-Hua.Synthesis of a Mesoporous Manganese Dioxide-Graphene Composite by a Simple Template-Free Strategy for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2014,30(10): 1876-1882
19． MA Guo-Fu, MU Jing-Jing, ZHANG Zhi-Guo, SUN Kan-Jun, PENG Hui, LEI Zi-Qiang.Preparation of Polypyrrole/Sodium Alginate Nanospheres and Their Application for High-Performance Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(11): 2385-2391
20． HUANG Bo, SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Organic Electrolytes for Activated Carbon-Based Supercapacitors with Flexible Package[J]. Acta Phys. -Chim. Sin., 2013,29(09): 1998-2004
21． LI Le, HE Yun-Qiu, CHU Xiao-Fei, LI Yi-Ming, SUN Fang-Fang, HUANG He-Zhou.Hydrothermal Synthesis of Partially Reduced Graphene Oxide-K2Mn4O8 Nanocomposites as Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(08): 1681-1690
22． WU Hong-Ying, WANG Huan-Wen.Synthesis and Characterization of NiCo2O4 Nanoflower/Activated Carbon Fiber Composite and Its Supercapacitor Properties[J]. Acta Phys. -Chim. Sin., 2013,29(07): 1501-1506
23． HU Ying-Ying, HU Zhong-Ai, ZHANG Ya-Jun, LU Ai-Lian, XU Huan, ZHANG Zi-Yu, YANG Yu-Ying, LI Li, WU Hong-Ying.Synthesis and Electrochemical Characterization of RuO2·xH2O/Graphite Nanosheet Composite Array Electrodes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2013,29(02): 305-310
24． LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang.Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Phys. -Chim. Sin., 2013,29(01): 111-116
25． ZhONG Hao-Xiang, ZHAO Chun-Bao, LUO Hao, ZHANG Ling-Zhi.Novel Organosilicon Ionic Liquid Based Electrolytes for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2641-2647
26． SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke.Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Phys. -Chim. Sin., 2012,28(11): 2745-2753
27． HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei.Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Phys. -Chim. Sin., 2012,28(10): 2269-2275
28． SHEN Bao-Shou, FENG Wang-Jun, LANG Jun-Wei, WANG Ru-Tao, TAI Zhi-Xin, YAN Xing-Bin.Nitric Acid Modification of Graphene Nanosheets Prepared by Arc- Discharge Method and Their Enhanced Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2012,28(07): 1726-1732
29． CHE Qian, ZHANG Fang, ZHANG Xiao-Gang, LU Xiang-Jun, DING Bing, ZHU Jia-Jia.Preparation of Ordered Mesoporous Carbon/NiCo2O4 Electrode and Its Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2012,28(04): 837-842
30． LIU Dong, SHEN Jun, LI Ya-Jie, LIU Nian-Ping, LIU Bin.Pore Structures of Carbon Aerogels and Their Effects on Electrochemical Supercapacitor Performance[J]. Acta Phys. -Chim. Sin., 2012,28(04): 843-849
31． ZHU Jian-Bo, XU You-Long, WANG Jie, WANG Jing-Ping.Electropolymerization and Characterization of Fast Charge-Discharge PPy/F-SWNTs Composite Materials[J]. Acta Phys. -Chim. Sin., 2012,28(02): 373-380
32． SUN Xian-Zhong, ZHANG Xiong, ZHANG Da-Cheng, MA Yan-Wei.Activated Carbon-Based Supercapacitors Using Li2SO4 Aqueous Electrolyte[J]. Acta Phys. -Chim. Sin., 2012,28(02): 367-372
33． GUO Pei-Zhi, JI Qian-Qian, ZHANG Li-Li, ZHAO Shan-Yu, ZHAO Xiu-Song.Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(12): 2836-2840
34． XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian.Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2340-2346
35． LU Xiang-Jun, DOU Hui, YANG Su-Dong, HAO Liang, ZHANG Fang, ZHANG Xiao-Gang.Fabrication and Electrochemical Capacitive Behavior of Freestanding Graphene/Polyaniline Nanofibre Film[J]. Acta Phys. -Chim. Sin., 2011,27(10): 2333-2339
36． LI Zhao, XU Ju-Liang, LI Xu-Yan, GUO Li-Fang, LI Jin, JIANG Yi-Ming.Preparation of Manganese Dioxide for Electrodes of Supercapacitors Based on Duplex Stainless Steel[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1424-1430
37． ZHOU Jin, LI Wen, XING Wei, ZHUO Shu-Ping.Capacitive Performance of Tunable Ordered Mesoporous Carbons in Organic and H2SO4 Electrolytes[J]. Acta Phys. -Chim. Sin., 2011,27(06): 1431-1438
38． MI Juan, WANG Yu-Ting, GAO Peng-Cheng, LI Wen-Cui.Effects of Thermal Treatment on the Electrochemical Behavior of Manganese Dioxide[J]. Acta Phys. -Chim. Sin., 2011,27(04): 893-899
39． YU Li-Qiu, CHEN Shu-Li, CHANG Sha, LI Yun-Hu, GAO Yin-Yi, WANG Gui-Ling CAO Dian-Xue.Supercapacitance of NiCo2O4 Nanowire Arrays Grown on Nickel Foam[J]. Acta Phys. -Chim. Sin., 2011,27(03): 615-619
40． LI Wen, ZHOU Jin, XING Wei, ZHUO Shu-Ping, Lü Yi-Min.Preparation of Microporous Carbon Using a Zeolite HY Template and Its Capacitive Performance[J]. Acta Phys. -Chim. Sin., 2011,27(03): 620-626
41． TIAN Ying, YAN Jing-Wang, XUE Rong, YI Bao-Lian.Influence of Electrolyte Concentration and Temperature on the Capacitance of Activated Carbon[J]. Acta Phys. -Chim. Sin., 2011,27(02): 479-485
42． ZHANG Hai-Jun, ZHANG Xiao-Gang, YUAN Chang-Zhou, GAO Bo, SUN Kang, FU Qing-Bin, LU Xiang-Jun, JIANG Jian-Chun.Preparation of Water Soluble Chitosan-Based Porous Carbon/NiO Composites and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2011,27(02): 455-460
43． ZHANG Fang, YUAN Chang-Zhou, ZHANG Xiao-Gang, ZHANG Luo-Jiang, XU Ke.5-Sulfosalicylic Acid-Assisted Hydrothermal Synthesis and Supercapacitive Properties of Co-Ni Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3175-3180
44． ZHANG Xiao-Bo, CHEN Ming-Hai, ZHANG Xiao-Gang, LI Qing-Wen.Preparation of Porous Carbon Nanofibers by Electrospinning and Their Electrochemical Capacitive Behavior[J]. Acta Phys. -Chim. Sin., 2010,26(12): 3169-3174
45． TIAN Ying, YAN Jing-Wang, LIU Xiao-Xue, XUE Rong, YI Bao-Lian.Electrochemical Capacitance of Composites with MnOx Loaded on the Surface of Activated Carbon Electrodes[J]. Acta Phys. -Chim. Sin., 2010,26(08): 2151-2157
46． LI Li-Min, LIU En-Hui, LI Jian, YANG Yan-Jing, SHEN Hai-Jie, HUANG Zheng-Zheng, XIANG Xiao-Xia.Polyaniline-Based Carbon for a Supercapacitor Electrode[J]. Acta Phys. -Chim. Sin., 2010,26(06): 1521-1526
47． JI Qian-Qian, GUO Pei-Zhi, ZHAO Xiu-Song.Preparation of Chitosan-Based Porous Carbons and Their Application as Electrode Materials for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2010,26(05): 1254-1258
48． WANG Fan, WANG Yan-Min, WEN Yan-Xuan, SU Hai-Feng, LI Bin.Structural and Morphological Transformation of MnO2 Nanostructures from Mn3O4 Precursor[J]. Acta Phys. -Chim. Sin., 2010,26(02): 521-526
49． ZANG Yang, HAO Xiao-Gang, WANG Zhong-De, ZHANG Zhong-Lin, LIU Shi-Bin.Copolymerization and Capacitive Performance of Composite Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Films[J]. Acta Phys. -Chim. Sin., 2010,26(02): 291-298
50． PANG Xu, MA Zheng-Qing, ZUO Lie.Sn Doped MnO2 Electrode Material for Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(12): 2433-2437
51． FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
52． SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
53． SU Zhi, XU Mao-Wen, YE Shi-Hai, WANG Yong-Long.Doping of Layered LiMnO2 as Cathode Materials for Lithium-Ion Batteries and Their Electrochemical Properties[J]. Acta Phys. -Chim. Sin., 2009,25(06): 1232-1238
54． HU Jie, YUAN An-Bao, WANG Yu-Qin, WANG Xiu-Ling.Improved Cyclability of Nano-MnO2/CNT Composite Supercapacitor Electrode Derived fromRoom-Temperature Solid Reaction[J]. Acta Phys. -Chim. Sin., 2009,25(05): 987-993
55． JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
56． DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
57． CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
58． JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
59． HUANG Jun-Jie; JIANG Zhi-Yu.Electrochemical Performance of LiMn2O4 Thin Film Electrode Fabricated by Ink-Jet Printing Technique[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1563-1567
60． ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
61． YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua.Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24(01): 13-19
62． WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
63． WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
64． SONG Xu-Chun;ZHENG Yi-Fan;LIN Shen;WANG Yun.A Simple Method to Synthesize α-MnO2 and β-MnO2 Single-crystalline Nanorods[J]. Acta Phys. -Chim. Sin., 2007,23(02): 258-261
65． ZHAO Feng-Ming;MA Chun-An;CHU You-Qun;XU Ying-Hua.Oxygen Reduction on Ni-MnO2 Electrode in Alkaline Solution[J]. Acta Phys. -Chim. Sin., 2006,22(06): 716-720
66． YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
67． Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
68． Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
69． Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
70． Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
71． Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
72． Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288