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Acta Physico-Chimica Sinica  2007, Vol. 23 Issue (Supp): 40-45    DOI: 10.3866/PKU.WHXB2007Supp10
Article     
Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material
HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan
CITIC Guoan Mengguli New Engery Technology Co. Ltd., Beijing 102200, P. R. China; New Energy Material and Technology Laboratory, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
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Abstract  LiNi0.8Co0.2-xMgxO2 (x=0.02, 0.03, 0.04) cathode materials were synthesized by co-precipitation method. The materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), thermogravimetry (TG), and differential scanning calorimetry (DSC). The results showed that the spherical products, without impurities, had a typical α-NaFeO2 layered structure. In the range of 3.0-4.3 V, at 0.5 mA·cm-2 of the current density, the first specific capacity was 184.8 mAh·g-1. After 50 cycles, the capacity retention was 94.2%. The DSC result showed that after the doping with Mg2+, the phase transition of LiNi0.8Co0.2-xMgxO2 was inhibited without distinct capacity fall. At the same time, the stability and cycling character was improved obviously.

Key wordsLithiumion secondary battery      Cathode material      High capacity      Doping     
Received: 01 January 1900      Published: 04 January 2008
Corresponding Authors: QI Lu     E-mail: qilu@pku.edu.cn
Cite this article:

HOU Xian-Quan; JIANG Wei-Jun; QI Lu; HAN Li-Juan. Synthesis and Properties of Layered LiNi0.8Co0.2-xMgxO2 Cathode Material. Acta Physico-Chimica Sinica, 2007, 23(Supp): 40-45.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB2007Supp10     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2007/V23/ISupp/40

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