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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2007,Vol.23>> Issue(Supp)>> 46-50     doi: 10.3866/PKU.WHXB2007Supp11         中文摘要
Discharge Performances of C/LiNi1/3Co1/3Mn1/3O2

WANG Jian; QI Yu-Jun; LI Yong-Wei; QI Lu


CITIC Guoan Mengguli New Energy Technology Co. Ltd., Beijing 102200, P. R. China; New Energy Materials and Technology Laboratory, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
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18650 type Li ion secondary cells were developed using carbon as anode material and LiNi1/3Co1/3·Mn1/3O2 as cathode material. The discharge performance of the C/LiNi1/3Co1/3Mn1/3O2 cell was studied through such methods as charge and discharge cycle, hybrid pulse power characterization (HPPC) and area-specific impedance (ASI) test. Study was also performed on the impact of such factors as material particle and morphology, discharge temperature and electrolyte on the discharge performances of the C/LiNi1/3Co1/3Mn1/3O2 cell, especially on its discharge performance under big currents. The results show that the C/LiNi1/3Co1/3Mn1/3O2 cell presents more stable charge/discharge cycles as well as better discharge performance under big currents with smaller original particle of LiNi1/3Co1/3·Mn1/3O2. It is also demonstrated that elevated discharge temperature prominently improves the discharge performance of the C/LiNi1/3Co1/3Mn1/3O2 cell, with its output power density at late discharge period growing by a large margin. Electrolyte with high conductivity also improves the cell’s long-termcycle performance under big discharge currents.

Keywords: Lithiumion secondary battery   Cathode material   LiNi1/3Co1/3Mn1/3O2   Discharge performances  
Received: 1900-01-01 Accepted: 1900-01-01 Publication Date (Web): 2008-01-04
Corresponding Authors: QI Lu Email: qilu@pku.edu.cn


Cite this article:

WANG Jian; QI Yu-Jun; LI Yong-Wei; QI Lu

. Discharge Performances of C/LiNi1/3Co1/3Mn1/3O2[J]. Acta Phys. -Chim. Sin., 2007,23 (Supp): 46-50.    doi: 10.3866/PKU.WHXB2007Supp11
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