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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2008,Vol.24>> Issue(01)>> 13-19     doi: 10.1016/S1872-1508(08)60002-9         中文摘要
Carbon Electrode Material with High Densities of Energy and Power
YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua
Department of Chemistry, Tongji University, Shanghai 200092, P. R. China
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Activated carbon (AC) samples as electrode materials were prepared by means of simultaneous physical-chemical activation using walnut shells as precursors. The porosity and surface chemistry of the resultant AC samples were studied by the nitrogen adsorption at 77 K and FTIR spectrum. The testing supercapacitors were assembled with resultant carbon electrode and electrolyte of 6 mol·L-1 KOHsolution. Their electrochemical properties were investigated by charge-discharge of constant current, cyclic voltammogram, impedance spectrumand so on. The results showed that the capacitor had low inner resistance, low leakage current, high stability, and capacitance retainability. The specific capacitance of AC increased with increasing BET specific surface area. The specific capacitance of the AC sample with a specific area of 1197 m2·g-1 could be as high as 292 F·g-1. At a discharge current of 80 mA, the corresponding specific energy density, power density, and maximum power of the supercapacitor are 7.3 Wh·kg-1, 770 W·kg-1, and 5.1 W·g-1, respectively.

Keywords: Activated carbon   Activation   Functional group   Electrode material   Supercapacitor  
Received: 2007-07-05 Accepted: 2007-09-27 Publication Date (Web): 2007-10-24
Corresponding Authors: HU Zhong-Hua Email: huzh@mail.tongji.edu.cn


Cite this article: YANG Jing; LIU Ya-Fei; CHEN Xiao-Mei; HU Zhong-Hua; ZHAO Guo-Hua. Carbon Electrode Material with High Densities of Energy and Power[J]. Acta Phys. -Chim. Sin., 2008,24 (01): 13-19.    doi: 10.1016/S1872-1508(08)60002-9
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92. FU Qing-Bin, GAO Bo, SU Ling-Hao, YUAN Chang-Zhou, LU Xiang-Jun, ZHANG Xiao-Gang.Preparation of Polypyrrole/Benzenesulfonic Functionalized Multi-Walled Carbon Nanotubes Induced by Hydrogen Bonding and Their Electrochemical Behavior[J]. Acta Phys. -Chim. Sin., 2009,25(11): 2199-2204
93. SUN Zhe, LIU Kai-Yu, ZHANG Hai-Feng, LI Ao-Sheng, XU Xiao-Cun.Study on Meso-C/MnO2 Asymmetric Supercapacitors[J]. Acta Phys. -Chim. Sin., 2009,25(10): 1991-1997
94. CAI Wan-Fei, WANG Xiao-Hui, LI Lai-Cai, TIAN An-Min.Mechanism for the CuX-Catalyzed (X=I, Br) Intramolecular O-Arylation Reaction of N-(ortho-chlorophenyl)benzamide[J]. Acta Phys. -Chim. Sin., 2009,25(10): 2101-2106
95. WANG Xiao-Mei, HU Ji-Ming, ZHANG Jian-Qing, CAO Chu-Nan.Electrochemical Activity of IrO2 Electrodes in Aqueous Solutions Containing 4-Chlorophenol[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1725-1730
96. KONG De-Jin, ZOU Wei, ZHENG Jun-Lin, QI Xiao-Lan, FANG Ding-Ye.Crystallization Kinetics and Influencing Factors in the Syntheses of MFI/MFI Core-Shell Zeolites[J]. Acta Phys. -Chim. Sin., 2009,25(09): 1921-1927
97. JIANG Qi, ZHAO Xiao-Feng, HUANG Bin, DU Bing, ZHAO Yong.Effect of the Activated Carbon Reactivation on Its Electrochemical Capacitance[J]. Acta Phys. -Chim. Sin., 2009,25(04): 757-761
98. DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong.Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect[J]. Acta Phys. -Chim. Sin., 2009,25(03): 513-518
99. LIU Dao-Shing, HAN Chun-Yu, DUAN Lin-Hai, SONG Li-Juan, SUN Zhao-Lin.Activation Energy of Temperature Programmed Desorption Calculated Using Least-SquaresMethod for Benzene, Thiophene and Octane on NaY[J]. Acta Phys. -Chim. Sin., 2009,25(03): 470-476
100. CHEN Li; ZHANG Xiao-Gang; YUAN Chang-Zhou; CHEN Sheng-Yao.Electrochemical Properties of Poly(3,4-ethylenedioxythiophene)/Manganese Oxide Synthesized by Interfacial Polymerization[J]. Acta Phys. -Chim. Sin., 2009,25(02): 304-308
101. GAO Qiang; LIU Ya-Fei; HU Zhong-Hua; ZHENG Xiang-Wei; WEN Zu-Biao.Electrochemical Properties of Manganese Oxide Surface-Modified Activated Carbon Electrode Materials[J]. Acta Phys. -Chim. Sin., 2009,25(02): 229-236
102. JIANG Qi; ZHANG Qian; DU Bing; ZHAO Xiao-Feng; ZHAO Yong.Preparation and Electrochemical Properties of CNTs-PANI Composite Material via Finite Field Polymerization[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1719-1723
103. CHEN Yu-Juan; HU Zhong-Hua; WANG Xiao-Jing; ZHAO Guo-Hua; LIU Ya-Fei; LIU Wei.Influence of Pore Size and Surface Area of Activated Carbon on the Performance of TiO2/AC Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(09): 1589-1596
104. LIU Ya-Fei; HU Zhong-Hua; XU Kun; ZHENG Xiang-Wei; GAO Qiang.Surface Modification and Performance of Activated Carbon Electrode Material[J]. Acta Phys. -Chim. Sin., 2008,24(07): 1143-1148
105. GUO Liang; WU Zhan-Song.Mechanism of Methane’s Adsorption on Nanometer Active Carbon at Supercritical State[J]. Acta Phys. -Chim. Sin., 2008,24(05): 737-742
106. LIU Shou-Xin; CHEN Xiao-Yun.Effect of Pore Structure of Activated Carbon on the Photocatalytic Activity of TiO2/AC Composite Photocatalyst[J]. Acta Phys. -Chim. Sin., 2008,24(03): 533-538
107. ZENG Wen-Wen; HUANG Ke-Long; YANG You-Ping; LIU Su-Qin; LIU Ren-Sheng.Solvothermal Synthesis and Capacitance Performance of Co3O4 with Different Morphologies[J]. Acta Phys. -Chim. Sin., 2008,24(02): 263-268
108. YU Jun-Sheng; SUO Fan; LI Wei-Zhi; LIN Hui; LI Lu; JIANG Ya-Dong.Influence of Electrode Materials on the Performance of NPB/Alq3 Organic Electroluminescent Devices[J]. Acta Phys. -Chim. Sin., 2007,23(11): 1821-1826
109. YANG Jian-Jun; HUANG Jun-Jie; JIANG Zhi-Yu.Supercapacitance of MnO2 Thin Film Electrodes Prepared Using Jet Printing Method[J]. Acta Phys. -Chim. Sin., 2007,23(09): 1365-1369
110. WANG Jie; XU You-Long; SUN Xiao-Fei; XIAO Fang; MAO Sheng-Chun.Capacitance Properties of Porous Polypyrrole Thick Films Prepared Electrochemically by Multi-step Polymerization[J]. Acta Phys. -Chim. Sin., 2007,23(06): 877-882
111. WANG Jie;XU You-Long;CHEN Xi;DU Xian-Feng;LI Xi-Fei.Effect of Doping Ions on Electrochemical Capacitance Properties of Polypyrrole Films[J]. Acta Phys. -Chim. Sin., 2007,23(03): 299-304
112. QIU Kai-Dong;LI Wei-Bin.Adsorption of Hexavalent Chromium Ions on Multi-wall Carbon Nanotubes in Aqueous Solution[J]. Acta Phys. -Chim. Sin., 2006,22(12): 1542-1546
113. YANG Fang-Zu;YANG Bin;LU Bin-Bin;HUANG Ling;XU Shu-Kai;ZHOU Shao-Min .Electrochemical Study on Electroless Copper Plating Using Sodium Hypophosphite as Reductant[J]. Acta Phys. -Chim. Sin., 2006,22(11): 1317-1320
114. GE Su-Hong;DONG Guang-Xing;CHENG Xin-Lu;YANG Xiang-Dong.Reaction of H2 and N+ Ion under Titan′s Atmosphere[J]. Acta Phys. -Chim. Sin., 2006,22(10): 1217-1221
115. ZHANG Hua;CHEN Xiao-Hua;ZHANG Zhen-Hua;QIU Ming.Effect of Grafted Hydroxyl on the Electronic Structure of Finite-length Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(09): 1101-1105
116. WU Xin-Min;LIU Jian-Hua;LI Wei;QI Chuan-Song .Thermal Decomposition Kinetics of Complexes of Rare Earths (RE = Nd, Sm) with Amino Acid RE(Val)Cl3•6H2O[J]. Acta Phys. -Chim. Sin., 2006,22(08): 942-946
117. LIU Jun-Ling;SHANG Jing; WANG Pei-Yi; LI Lai-Cai1;TIAN An-Min.Theory of the Reaction Mechanismfor CH3CHF Radical and HNCO[J]. Acta Phys. -Chim. Sin., 2006,22(08): 921-925
118. CHEN Xiao-Yun;LIU Shou-Xin;CHEN Xi;SUN Cheng-Lin.Characterization and Activity of TiO2 /wAC Composite Photocatalyst Prepared by Acid Catalyzed Hydrolysis Method[J]. Acta Phys. -Chim. Sin., 2006,22(05): 517-522
119. ZHENG Yan; ZHA Dong; LI Lai-cai.Theoretical Study on the Mechanism of the Reaction of CF3O2 with NO[J]. Acta Phys. -Chim. Sin., 2006,22(02): 156-160
120. CHEN Xiao-xia; WANG Yong-cheng; Geng Zhiy-Yuan; GAO Li-guo; FANG Ran; ZHANG Xing-hui.Theoretical Study of Gas-phase Reaction of CrO2+ with H2[J]. Acta Phys. -Chim. Sin., 2006,22(01): 59-64
121. JIANG Qi; LU Xiao-ying; ZHAO Yong; ZHU Xiao-tong; CAI Yu-dong; QIAN Lan.Effects of Activation Conditions on the Specific Surface Area of Activated Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2006,22(01): 43-47
122. ZHAO Peng; FANG Hui-jue; XUE Teng; QI Xi-min; LU Jia-xing.Diffusion Coefficients and Rate Constants of NiCl2(bpy)3 in DMF Determined by Chronocoulometry[J]. Acta Phys. -Chim. Sin., 2005,21(11): 1235-1239
123. XUE Yong-qiang; DU Jian-ping; WANG Pei-dong; WANG Zhi-zhong.Effect of Particle Size on Kinetic Parameters of the Heterogeneous Reactions[J]. Acta Phys. -Chim. Sin., 2005,21(07): 758-762
124. LIU Chun-ling; WEN Yue-hua; CHENG Jie; GUO Quan-gui; CAO Gao-ping; LIU Lang; YANG Yu-sheng.Influence of Pore Structure of Phenolic Resin Based Activated Carbon Fibers on the Electrochemical Performance of Electrical Double-layer Capacitors[J]. Acta Phys. -Chim. Sin., 2005,21(07): 786-791
125. LANG; Xu-qing; MA Hong-qin; TAN Xin; ZHU Hui-ming.Surface Activation and Graft of the Ultrafine PTFE Particles[J]. Acta Phys. -Chim. Sin., 2005,21(07): 703-706
126. FENG Shao-bin; SHANG Shi-bo; BAO Xiang; FENG Li-ting; ZHANG Jing-wei; LI Zong-hui.Study of Potential Activation Phenomenon and Initial Process of the Metal Electrodeposition[J]. Acta Phys. -Chim. Sin., 2005,21(05): 463-467
127. LI Lai-Cai; ZHU Yuan-Qiang; ZHA Dong; TIAN An-Min.Theoretical Study on the Mechanism of the Reaction of CH3CF2O2 with HO2 Radical[J]. Acta Phys. -Chim. Sin., 2005,21(05): 490-493
128. XIAO Xue-Zhang; CHEN Chang-Pin; WANG Xin-Hua; CHEN Li-Xin; WANG Li; GAO Lin-Hui.Microstructure and Electrochemical Properties of Amorphous Mg-Fe-Ni Hydrogen Storage Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(05): 565-568
129. YANG Hong-Sheng; ZHOU Xiao; ZHANG Qing-Wu.Electrochemical Performances of Supercapacitor with Polyaniline Particles with Hierarchy as Active Electrode Material[J]. Acta Phys. -Chim. Sin., 2005,21(04): 414-418
130. QIAN Xin-Ming;LIU Li;FENG Chang-Gen.Calculating Apparent Activation Energy of Adiabatic Decomposition Process Using Pressure Data[J]. Acta Phys. -Chim. Sin., 2005,21(02): 134-138
131. WANG Xiao-Feng; WANG Da-Zhi; LIANG Ji.Pseudo-capacitance of Ultrafine Nickel Hydroxide Prepared by Sol-gel Method[J]. Acta Phys. -Chim. Sin., 2005,21(02): 117-122
132. Wu Wang-Ting;Yang Rui;Hu Ting;Peng Ke;He Shui-Yang;Hu Rong-Zu.Thermochemistry of Salicylaldehyde-1H-benzotriazol Acetyl Hydrazone Complexes with RE (III)[J]. Acta Phys. -Chim. Sin., 2004,20(09): 1144-1149
133. Hua Rui-Mao.Homogeneous Catalytic Activation of Hetero-Carbon Bond and Its Addition to Alkynes[J]. Acta Phys. -Chim. Sin., 2004,20(08S): 989-994
134. Yu Xue-Chun;Peng Hai-Lin;Zhang Ran;Zhang Ying-Ying;Liu Zhong-Fan.Influence of Decomposition Temperature on the Threshold Voltage for a Series of Charge Transfer Complexes[J]. Acta Phys. -Chim. Sin., 2004,20(06): 565-568
135. Su Yu-Zhi;Guo Shi-Heng;Xiao Yi-Zhi;Xiao Min;Yang Qi-Qin.Electrode Kinetics of 2,2’-diaminophenyloxydisulfide[J]. Acta Phys. -Chim. Sin., 2004,20(05): 518-523
136. Jiang Qi;Lu Xiao-Ying;Zhao Yong;Yu Zuo-Long.Effect of Microstructure’s Change on Electrochemical Capacitance of Carbon Nanotubes[J]. Acta Phys. -Chim. Sin., 2004,20(05): 546-549
137. Liu Xian-Ming;Zhang Yi-He;Zhang Xiao-Gang;Fu Shao-Yun.The Supercapacitive Properties of Ni-Ru Oxide Composites[J]. Acta Phys. -Chim. Sin., 2004,20(04): 417-420
138. Liu En-Hui;Li Xin-Hai;Hou Zhao-Hui;He Ze-Qiang;Deng Ling-Feng.Chemical Diffusion Behaviors of Lithium-ion in the LiV3O8 Prepared by Wet Method Reaction[J]. Acta Phys. -Chim. Sin., 2004,20(04): 377-381
139. Deng Mei-Gen;Zhang Zhi-An;Hu Yong-Da;Wang Bin-Hua;Yang Bang-Chao.Effect of Activation and Surface Modification on the Properties of Carbon Nanotubes Supercapacitors[J]. Acta Phys. -Chim. Sin., 2004,20(04): 432-435
140. Gu Xin;Hu Guang-Hui;Wang Zhou-Cheng;Lin Chang-Jian.In situ Investigation on the Behavior of Mixed Potential in Electroless Copper Plating[J]. Acta Phys. -Chim. Sin., 2004,20(02): 113-117
141. Zhuang Xin-Guo;Yang Yu-Sheng;Ji You-Ju;Yang Dong-Ping;Tang Zhi-Yuan.The Influence of Porous Structure of Activated Carbons Used as Supercapacitor Electrode Materials on Its Properties[J]. Acta Phys. -Chim. Sin., 2003,19(08): 689-694
142. Wang Xiao-Feng;Wang Da-Zhi;Liang Ji.Carbon Nanotube Capacitor Materials Loaded with Different Amounts of Ruthenium Oxide[J]. Acta Phys. -Chim. Sin., 2003,19(06): 509-513
143. Jiang Ling;Wang Gui-Chang;Guan Nai-Jia;Wu Yang;Cai Zun-Sheng;Pan Yin-Ming;Zhao Xue-Zhuang;Huang Wei;Li Yong-Wang;Sun Yu-Han;Zhong Bing.DFT Studies of CO Adsorption and Activation on Some Transition Metal Surfaces[J]. Acta Phys. -Chim. Sin., 2003,19(05): 393-397
144. Zhang Bao-Hong;Zhang Na.Research on Nanophase MnO2 for Electrochemical Supercapacitor[J]. Acta Phys. -Chim. Sin., 2003,19(03): 286-288
145. He Shui-Yang;Cao Wen-Kai;Hu Ting;Zhao Jian-She;Zhang Wei-Ping;Xue Gang-Lin;Hu Rong-Zu.Synthesis, Characterization and Thermochemical Properties of La(III) with Salicylaldehyde-1H- benzotriazol-1-aceylhydrazone[J]. Acta Phys. -Chim. Sin., 2002,18(10): 865-870
146. Chen Wen-Kai;Xu Jiao;Zhang Yong-Fan;Zhou Li-Xin;Li Jun-Qian.A Theoretical Study on the Proton Transfer in 2-hydroxy Pyridine[J]. Acta Phys. -Chim. Sin., 2002,18(09): 802-807
147. Xing Wei;Zhang Ming-Jie;Yan Zi-Feng.Synthesis and Activation Mechanism of Coke Based Super Activated Carbons[J]. Acta Phys. -Chim. Sin., 2002,18(04): 340-345
148. Liang Kui;Chen Ai;Feng Zhe-Sheng;Ye Zhi-Xiang.AC Impedance Analysis of Supercapacitors Utilizing Carbon Nanotube Electrodes[J]. Acta Phys. -Chim. Sin., 2002,18(04): 381-384
149. Xu Li-Na;Xu Hong-Fei;Zhou Kai-Chang;Xu Ai-Qun;Yue Zeng-Quan;Gu Ning;Zhang Hai-Qian;Liu Ju-Zheng;Chen Kun-Ji.Study on a New Activation Method for Initiating Electroless Plating on Alumina Powders Based on SAMs Bonded Palladium[J]. Acta Phys. -Chim. Sin., 2002,18(03): 284-288
150. Wang Yong-Cheng;Geng Zhi-Yuan;Chen Hong-Shan.A Density Functional Method(DFT) Study on the Cyclic Reaction Kinetics[J]. Acta Phys. -Chim. Sin., 2002,18(01): 45-49
151. Li Ying;Gong Jiang-Hong;Tang Zi-Long;Xie Yu-Sheng.Temperature-Independent Activation Energy for Ionic Conduction of Zirconia Based Solid Electrolytes[J]. Acta Phys. -Chim. Sin., 2001,17(09): 792-796
152. Yan Qian-Gu;Luo Chun-Rong;Weng Wei-Zheng;Yang Le-Fu;Wan Hui-Lin;Wu Ting-Hua.Activation of Methane over Ni/TiO2 Catalyst[J]. Acta Phys. -Chim. Sin., 2001,17(08): 733-738
153. Liu Han-Xing;Zhou Zheng-Ping;Zhao Shi-Xi;Hao Hua;Ouyang Shi-Xi.Chemical Synthesis in Microwave Field of Electrode Materials Li-Mn-O System[J]. Acta Phys. -Chim. Sin., 2001,17(08): 702-707
154. Liu Zhen-Yu;Zheng Jing-Tang;Wang Mao-Zhang;Zhang Bi-Jiang.Study for Nitrogen Adsorption of PAN-based Activated Carbon Fibers[J]. Acta Phys. -Chim. Sin., 2001,17(07): 594-599
155. Lu An-Hui;Li Wen-Cui;Zheng Jing-Tang.Preparation of PANbased Molecular Sieve ACF and Study of Surface Structure by XPS[J]. Acta Phys. -Chim. Sin., 2001,17(03): 216-221
156. Zhang Dong-Ju, Hu Hai-Quan, Liu Yong-Jun, Bu Yu-Xiang, Liu Cheng-Bu.Theoretical Study of Self-Exchange Electron Transfer Renctions for Co(H2O)62+/3+ System[J]. Acta Phys. -Chim. Sin., 2000,16(09): 855-859
157. Li Qing-Lian, Chen Shou-Tian, Yao Pu, Wei Guo, Qu Yong-He.Thermal Decomposation Mecharism of the Nano-BaTiO2 Formation[J]. Acta Phys. -Chim. Sin., 2000,16(02): 170-174
158. Li Zhen-Ya, Qin Xue, Yu Yuan-Bin, Chen Yan-Ying, Yi Ling, Yang Lin.The Electrochemical Behavior of Al Alloys Containing Tin and Gallium in Alkaline Electrolytes[J]. Acta Phys. -Chim. Sin., 1999,15(04): 381-384
159. Yang Yi-Yun, Sun Shi-Gang.Kinetics of Irreversible Reactions on Platinum Single Crystal Electrodes(III)[J]. Acta Phys. -Chim. Sin., 1998,14(10): 919-926
160. Wang Gui-Chang, Pan Yin-Ming, Cai Zun-Sheng, Zhao Xue-Zhuang.Theoretical Study of the Reactivity of the Addition of Radicals to Fluoro-ethylenes[J]. Acta Phys. -Chim. Sin., 1998,14(02): 127-130
161. Gong Xue-Dong, Xiao He-Ming.Theoreticl Studies on the Pyrolysis of Polynitric Esters[J]. Acta Phys. -Chim. Sin., 1998,14(01): 33-38
162. Liu Wei-,Xu Yi-De,Li Li-Yun,Hu Hong-Bing.Study Mo/HZSM-5 Catalysts by NMR[J]. Acta Phys. -Chim. Sin., 1997,13(08): 693-699
163. Zhang Jiao-Qiang,Zhu Chun-Hua,Gong Xue-Dong,Xiao He-Ming.AM1 Study on the Thermolyses Mechanism of TNAZ and Its Derivatives[J]. Acta Phys. -Chim. Sin., 1997,13(07): 612-616
164. Liu Tian-Qing,Guo Rong,Yu Wei-Li,Shen Ming.Diffusion Coefficient and Structure Properties of SDS/BA/H2O System[J]. Acta Phys. -Chim. Sin., 1997,13(05): 401-406
165. Kan Jin-Qing,Qiao Yue-Dong,Mu Shao-Lin,Li Yong-Fang.Inhibition of Bioelectrochemical Activities of Polyaniline Uricase Electrode by Theophylline[J]. Acta Phys. -Chim. Sin., 1997,13(03): 236-241
166. Guan Jian-Guo,Zhao Su-Ling,Xie Hong-Quan.The Temperature and Electric Field Dependence of Properties for Hydrous Electrorheological Fluid-Lithium Polymethacrylate[J]. Acta Phys. -Chim. Sin., 1997,13(03): 242-246
167. Chen Wei-Xiang,Tang Zhi-Yuan,Liu Zhao-Lin,Guo He-Tong.Chemical Activation of Metal Hydride Electrodes[J]. Acta Phys. -Chim. Sin., 1996,12(08): 704-708
168. Yin Zhou-Lan.Study on the Kinetics of the Thermal Decomposition of Ammonium Molybdates[J]. Acta Phys. -Chim. Sin., 1996,12(02): 181-184
169. Miao Rui-Ping,Dai Min-Ping.Study of Activatied Carbon on the Adsorption of Titan Yellow from Aqueous Solution[J]. Acta Phys. -Chim. Sin., 1996,12(02): 173-176
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172. Liu Wen-Bin,Wu Yan-Ping,Wang Jian-Ji,Lu Jin-Suo.Viscosity of NaCl and KCl in Aqueous Sucrose Solutions[J]. Acta Phys. -Chim. Sin., 1995,11(07): 590-595
173. Mu Guan-Nan, Yang Chun-Fen.Adsorption of Zinc(II) Ion and its Complexes from Solution by Activatied Charcoal[J]. Acta Phys. -Chim. Sin., 1995,11(02): 157-161
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180. Shao Shu-Min; Xi Guang-Kang; Wang Jun-Rong; Li Sheng-Lin; Yang Xue-Zhu; Wang Jin-He; Zhou Zhi-Qiang; He Tian-Xi; Yu Bao-Xia.Activated Chemisorption of CH4 On Ni Surface and La Film[J]. Acta Phys. -Chim. Sin., 1992,8(06): 767-771
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