Please wait a minute...
Acta Physico-Chimica Sinica  2002, Vol. 18 Issue (03): 272-275    DOI: 10.3866/PKU.WHXB20020317
Note     
Research on Novel PMMAbased Gel Electrolyte for Lithium Ion Battery
Wang Zhan-Liang;Tang Zhi-Yuan;Geng Xin;Xue Jian-Jun
School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072
Download:   PDF(1615KB) Export: BibTeX | EndNote (RIS)      

Abstract  Novel PMMAbased electrolyte crosslinked by ethylene glycol dimethacrylate(EGD) for lithium ion battery is prepared. As the network structure, the mechanical property of the gelled electrolyte is improved. The content of methyl methacrylate(MMA) and EGD are optimized, and the temperature dependence of conductivity is investigated. The conductivity reaches 2×10-3 S•cm-1 in the polymer electrolyte containing 25%MMA, 2% EGD and 73% LiBF4 (mass fraction) in ethylene carbonate(EC)/dimethyl carbonate(DMC) at room temperature, and the electrochemical stability window is about 4.80 V versus lithium. The polymer lithium ion battery with gelled PMMAbased electrolyte exhibits good electrochemical property.

Key wordsLithium ion battery      Polymer electrolyte      PMMA      Ethylene carbonatedimethyl carbonate(EC-DMC)     
Received: 23 August 2001      Published: 15 March 2002
Corresponding Authors: Tang Zhi-Yuan     E-mail: zytang@tju.edu.cn
Cite this article:

Wang Zhan-Liang;Tang Zhi-Yuan;Geng Xin;Xue Jian-Jun. Research on Novel PMMAbased Gel Electrolyte for Lithium Ion Battery. Acta Physico-Chimica Sinica, 2002, 18(03): 272-275.

URL:

http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/10.3866/PKU.WHXB20020317     OR     http://www.whxb.pku.edu.cn/Jwk_wk/wlhx/Y2002/V18/I03/272

[1] MA Qiang, HU Yongsheng, LI Hong, CHEN Liquan, HUANG Xuejie, ZHOU Zhibin. An Sodium Bis (trifluoromethanesulfonyl) imide-based Polymer Electrolyte for Solid-State Sodium Batteries[J]. Acta Physico-Chimica Sinica, 2018, 34(2): 213-218.
[2] LI Wan-Long, LI Yue-Jiao, CAO Mei-Ling, QU Wei, QU Wen-Jie, CHEN Shi, CHEN Ren-Jie, WU Feng. Synthesis and Electrochemical Performance of Alginic Acid-Based Carbon-Coated Li3V2(PO4)3 Composite by Rheological Phase Method[J]. Acta Physico-Chimica Sinica, 2017, 33(11): 2261-2267.
[3] LI Ya-Dong, DENG Yu-Feng, PAN Zhi-Yi, WEI Yin-Ping, ZHAO Shi-Xi, GAN Lin. Dual Electron Energy Loss Spectrum Imaging of the Surfaces of LiNi0.5Mn1.5O4 Cathode Material[J]. Acta Physico-Chimica Sinica, 2017, 33(11): 2293-2300.
[4] HUANG Wei, WU Chun-Yang, ZENG Yue-Wu, JIN Chuan-Hong, ZHANG Ze. Surface Analysis of the Lithium-Rich Cathode Material Li1.2Mn0.54Co0.13Ni0.13NaxO2 by Advanced Electron Microscopy[J]. Acta Physico-Chimica Sinica, 2016, 32(9): 2287-2292.
[5] LI Ting, LONG Zhi-Hui, ZHANG Dao-Hong. Synthesis and Electrochemical Properties of Fe2O3/rGO Nanocomposites as Lithium and Sodium Storage Materials[J]. Acta Physico-Chimica Sinica, 2016, 32(2): 573-580.
[6] ZHU Shou-Pu, WU Tian, SU Hai-Ming, QU Shan-Shan, XIE Yong-Juan, CHEN Ming, DIAO Guo-Wang. Hydrothermal Synthesis of Fe3O4/rGO Nanocomposites as Anode Materials for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, 2016, 32(11): 2737-2744.
[7] WANG Qian-Wen, DU Xian-Feng, CHEN Xi-Zi, XU You-Long. TiO2 Nanotubes as an Anode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, 2015, 31(8): 1437-1451.
[8] ZENG Yu-Qun, GUO Yong-Sheng, WU Bing-Bin, HONG Xiang, WU Kai ZHONG, Kai-Fu. Synthesis and Electrochemical Performance of Plastic Crystal Compound-Based Ionic Liquid[J]. Acta Physico-Chimica Sinica, 2015, 31(7): 1351-1358.
[9] XUE Qing-Rui, LI Jian-Ling, XU Guo-Feng, HOU Peng-Fei, YAN Gang, DAI Yu, WANG Xin-Dong, GAO Fei. Effects of Surface Modification with Ag/C on Electrochemical Properties of Li[Li0.2Mn0.54Ni0.13Co0.13]O2[J]. Acta Physico-Chimica Sinica, 2014, 30(9): 1667-1673.
[10] HOU Hong-Ying. Recent Research Progress in Alkaline Polymer Electrolyte Membranes for Alkaline Solid Fuel Cells[J]. Acta Physico-Chimica Sinica, 2014, 30(8): 1393-1407.
[11] ZHU Zhi, QI Lu, LI Wei, LIAO Xi-Ying. Preparation and Electrochemical Performance of 5 V LiNi0.5Mn1.5O4 Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries[J]. Acta Physico-Chimica Sinica, 2014, 30(4): 669-676.
[12] WU Yue, LIU Xing-Quan, ZHANG Zheng, ZHAO Hong-Yuan. Preparation and Characterization of M(Ⅱ) and M(Ⅳ) Iso-Molar Co-Doped LiMn1.9Mg0.05Ti0.05O4 Cathode Materials for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, 2014, 30(12): 2283-2290.
[13] ZHONG Yan-Jun, LI Jun-Tao, WU Zhen-Guo, ZHONG Ben-He, GUO Xiao-Dong, HUANG Ling, SUN Shi-Gang. Synthesis of Na2MnPO4F/C with Different Carbon Sources and Their Performances as Cathode for Lithium Ion Battery[J]. Acta Physico-Chimica Sinica, 2013, 29(09): 1989-1997.
[14] LIU Nian-Ping, SHEN Jun, GUAN Da-Yong, LIU Dong, ZHOU Xiao-Wei, LI Ya-Jie. Effect of Carbon Aerogel Activation on Electrode Lithium Insertion Performance[J]. Acta Physico-Chimica Sinica, 2013, 29(05): 966-972.
[15] ZUO Xiang, CAI Feng, LIU Xiao-Min, YANG Hui, SHEN Xiao-Dong. Synthesis and Characterization of a Novel Physically Cross-Linked Gel Polymer Electrolyte[J]. Acta Physico-Chimica Sinica, 2013, 29(01): 64-72.