Acta Phys. -Chim. Sin. ›› 1999, Vol. 15 ›› Issue (02): 162-166.doi: 10.3866/PKU.WHXB19990213

• ARTICLE • Previous Articles     Next Articles

Chemical Reactions of Transition-metals with CO

Cai Yong, Zhu Xi-Wen, Yan Min, Chen Yong-Tai, Gao Ke-Lin   

  1. Laboratory of Magnctic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physics and Mathematics,The Chinese Academy of Sciences,Wuhan 430071
  • Received:1998-04-24 Revised:1998-08-03 Published:1999-02-15
  • Contact: Zhu Xi-Wen

Abstract:

Chemical reactions of cluster ions of transition-metals (Fe2+ Co2+ Ni2+) with CO were studied by using an ion trap affixed with a laser ablation source. The experiments indicate that Co2+ is more reactive than Fe2+ and Ni2+ when they react with CO molecule, and the reaction rates are independent on CO pressure. The results are in agreement with the theoretical simulation and the previous data.

Key words: Ion trap, Chuster, Chemisorption