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ISSN 1000-6818CN 11-1892/O6CODEN WHXUEU
Acta Phys Chim Sin >> 2000,Vol.16>> Issue(07)>> 613-620     doi: 10.3866/PKU.WHXB20000708         中文摘要
Active Components and Mechanism of Isobutane Alkylation with Butenes in the Catalytic System of HPAs+AcOH
Zhao Zhen-Bo, Sun Wen-Dong, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue
Changchun Institute of Applied Chemistry,The Chinese Academy of Sciences,Changchun 130022
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The catalytic active phase (CAP) of a novel liquid catalyst for isobutane alkylation with butenes was investigated, the composition of the CAP was analysized. The components of the catalytic active phase were separated and examined by the methods of FTIR,UV and NMR etc.. On the basis of these results, a reaction mechanism based on the formation of protonated heteropolyacid as an intial stage in the isobutane alkylation with butenes was postulated, which is in agreement with the experimental results.



Keywords: Concentrated heteropolyacid solution in acetic acid   Isobutane/butenes alkylation   Catalytic active phase   Reaction mechanism  
Received: 1999-11-01 Accepted: 2000-01-14 Publication Date (Web): 2000-07-15
Corresponding Authors: Wu Yue Email:


Cite this article: Zhao Zhen-Bo, Sun Wen-Dong, Yang Xiang-Guang, Ye Xing-Kai, Wu Yue. Active Components and Mechanism of Isobutane Alkylation with Butenes in the Catalytic System of HPAs+AcOH[J]. Acta Phys. -Chim. Sin., 2000,16 (07): 613-620.    doi: 10.3866/PKU.WHXB20000708
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108. Feng Hai-Xia, Zhu Zhi-Ang, Wang Chuan-Zhong, Ruan Wen-Juan, Li Ying, Chen Rong-Ti.Kinetics on the Axial Coordination Reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol[J]. Acta Phys. -Chim. Sin., 1999,15(02): 167-172
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110. Hu Hai-Quan, Liu Cheng-Bu.The Reaction Mechanism of the Biradical CF2 and O3[J]. Acta Phys. -Chim. Sin., 1998,14(12): 1104-1107
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