Acta Phys. -Chim. Sin. ›› 1999, Vol. 15 ›› Issue (06): 560-563.doi: 10.3866/PKU.WHXB19990615

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Study of the Reaction CH2(X 3B1)+N2O

Su Hong-Mei, Wu Cheng-Yin, Yang Ji-Xin, Zhong Jin-Xian, Kong Fan-Ao   

  1. The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080|Resarch Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085
  • Received:1998-07-03 Revised:1998-10-29 Published:1999-06-15
  • Contact: Kong Fan-Ao

Abstract:

The reaction dynamics of methylene radical CH2(X3B1) with N2O was investigated by Time-Resolved Fourier Transform Infrared Spectroscopy(TR-FTIRS). Pure CH2(X3B1) radicalwas produced via laser photolysis of ketene at 351 nm. Nascent viabrationally excited products CO, NO and HCN were observed. Some reaction pathways which may lead to these products were proposed and a possible reaction mechanism was outlined.

Key words: C2H, N2O, Reaction dynamics, TR-FTIRS